Tetrabutylammonium tetrafluoroborate
- Product Name
- Tetrabutylammonium tetrafluoroborate
- CAS No.
- 429-42-5
- Chemical Name
- Tetrabutylammonium tetrafluoroborate
- Synonyms
- tetrabutylammonium tetrafluoborate;TETRA-N-BUTYLAMMONIUM TETRAFLUOROBORATE;SKL1461;SKL1624;N4,4,4,4BF4;ammonium TetrafL;Tetrabutylammonium fluoborate;TETRABUTYLAMMONIUM FLUOROBORATE;TETRA-N-BUTYLAMMONIUM FLUOROBORATE;Tetrabutylazanium tetrafluoroborate
- CBNumber
- CB1273128
- Molecular Formula
- C16H36BF4N
- Formula Weight
- 329.27
- MOL File
- 429-42-5.mol
Tetrabutylammonium tetrafluoroborate Property
- Melting point:
- 155-161 °C(lit.)
- Flash point:
- >93℃
- storage temp.
- −20°C
- solubility
- methanol: 0.1 g/mL, clear, colorless
- form
- Crystalline Powder
- color
- White
- Water Solubility
- Slightly soluble
- Sensitive
- Hygroscopic
- BRN
- 3577508
- InChIKey
- DWWRDPSMLREDKW-UHFFFAOYSA-M
- CAS DataBase Reference
- 429-42-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Tetrabutylammonium tetrafluoroborate(429-42-5)
- EPA Substance Registry System
- 1-Butanaminium, N,N,N-tributyl-, tetrafluoroborate(1-) (429-42-5)
Safety
- Hazard Codes
- Xi,T,Xn
- Risk Statements
- 36/37/38-41-37/38-22
- Safety Statements
- 26-36-37/39-39
- RIDADR
- UN 1759 8/PG III
- WGK Germany
- 3
- Hazard Note
- Irritant/Hygroscopic
- TSCA
- Yes
- HazardClass
- TOXIC, HYGROSCOPIC
- PackingGroup
- III
- HS Code
- 29239000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H318Causes serious eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 217964
- Product name
- Tetrabutylammonium tetrafluoroborate
- Purity
- 99%
- Packaging
- 5g
- Price
- $41.1
- Updated
- 2024/03/01
- Product number
- 217964
- Product name
- Tetrabutylammonium tetrafluoroborate
- Purity
- 99%
- Packaging
- 25g
- Price
- $189
- Updated
- 2024/03/01
- Product number
- T0914
- Product name
- Tetrabutylammonium Tetrafluoroborate
- Purity
- >98.0%(N)
- Packaging
- 25g
- Price
- $29
- Updated
- 2024/03/01
- Product number
- T0914
- Product name
- Tetrabutylammonium Tetrafluoroborate
- Purity
- >98.0%(N)
- Packaging
- 100g
- Price
- $73
- Updated
- 2024/03/01
- Product number
- A16688
- Product name
- Tetra-n-butylammonium tetrafluoroborate
- Purity
- 99%
- Packaging
- 5g
- Price
- $33.65
- Updated
- 2024/03/01
Tetrabutylammonium tetrafluoroborate Chemical Properties,Usage,Production
Chemical Properties
WHITE FINE CRYSTALLINE POWDER
Uses
Tetrabutylammonium tetrafluoroborate may be used in the following studies:
- As supporting electrolyte in the voltammetric determination of Δ(9)-tetrahydrocannabinol (Δ(9)-THC).
- Synthesis of biologically relevant macrolactones, Sansalvamide A.
- As supporting electrolyte in the determination of the oxidation and reduction potentials of 5,10,15,20-tetra[3-(3-trifluoromethyl)phenoxy]porphyrin by cyclic voltammetry.
- Preparation of 1:1 adduct with 1,10-phenanthroline.
- Used to prepare other tetrabutylammonium salts in aqueous solutions.
- As electrolyte additive in the synthesis of conducting poly(thiophenes).
Uses
TBATFB has been used as an electrolyte to understand the paraffin graphite powder modified with sweet potato tissue (PCPET) electrode response.
General Description
Tetrabutylammonium tetrafluoroborate (TBATFB) is a phase transfer catalyst. It can be synthesized by the reaction between 30% aqueous solution of tetrafluoroboric acid and 40% aqueous solution of tetrabutylamonium hydroxide. Tetrabutylammonium tetrafluoroborate acts as an electrolyte and inhibits the self-assembly of alkylthiosulfate on gold.
Purification Methods
Recrystallise it from H2O, aqueous EtOH or from EtOAc by cooling in Dry-ice. Also recrystallise it from ethyl acetate/pentane or dry acetonitrile. Dry it at 80o under vacuum. [Detty & Jones J Am Chem Soc 109 5666 1987, Hartley & Faulkner J Am Chem Soc 107 3436 1985.] The acetate has m 118±2o (from BuCl), the bromide has m 118o (from EtOAc) and the nitrate has m 120o (from *C6H6). [Witschonka & Kraus J Am Chem Soc 69 2472 1947, Wheeler & Sandstedt J Am Chem Soc 77 2024 1955, Beilstein 4 IV 558.]
Tetrabutylammonium tetrafluoroborate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Tetrabutylammonium tetrafluoroborate manufacturers
- Product
- Tetrabutylammonium tetrafluoroborate 429-42-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-12
- Product
- Tetrabutylammonium tetrafluoroborate 429-42-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2023-03-08
- Product
- Tetrabutylammonium tetrafluoroborate 429-42-5
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2023-02-13