hexafluorophosphate

Reaction

Product Name: hexafluorophosphate
CAS No.: 870987-63-6
Chemical Name: hexafluorophosphate
Synonyms: Ir[dF(CF3)ppy]2(dtbbpy)PF6;4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine;[Ir(dtbbpy)[dF(CF3)ppy]2]PF6;4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate;(4,4'-Di-t-butyL;Ir[dF(CF3)ppy]2(dtbbpy)PF6 Chembeads (0.003μmol/mg);(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆;bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+);(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) hexafluorophosphate;(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
CBNumber: CB13303666
Molecular Formula: C42H34F10IrN4.PF6
Formula Weight: 1121.91
MOL File: 870987-63-6.mol

More

Less

hexafluorophosphate Property

Melting point:: >300 °C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Chloroform (Slightly)
form: crystal
color: yellow
InChI: InChI=1S/F6P/c1-7(2,3,4,5)6/q-1
InChIKey: LJQLCJWAZJINEB-UHFFFAOYSA-N
SMILES: [P-](F)(F)(F)(F)(F)F
CAS DataBase Reference: 870987-63-6

More

Less

Safety

Risk Statements: 36/37/38
Safety Statements: 26
TSCA: No
HS Code: 2843909000

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 747793
Product name: (Ir[dF(CF3)ppy]2(dtbpy))PF6
Packaging: 100mg
Price: $156
Updated: 2025/07/31

Sigma-Aldrich

Product number: 747793
Product name: (Ir[dF(CF3)ppy]2(dtbpy))PF6
Packaging: 1g
Price: $1030
Updated: 2025/07/31

TCI Chemical

Product number: D5817
Product name: (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate
Packaging: 200MG
Price: $192
Updated: 2025/07/31

TCI Chemical

Product number: D5817
Product name: (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate
Packaging: 1G
Price: $575
Updated: 2025/07/31

Strem Chemicals

Product number: 77-0425
Product name: (4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 50mg
Price: $59
Updated: 2024/03/01

More

Less

hexafluorophosphate Chemical Properties,Usage,Production

Reaction

Visible light photoredox-catalyzed cascade cyclizations of α-bromochalcones or α-bromocinnamates with heteroarenes.
Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.

Uses

(Ir[dF(CF₃)ppy]₂(dtbpy))PF₆ is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.

Uses

[4,?4''-?Bis(tert-butyl)?-?2,?2''-?bipyridine]?bis[3,?5-?difluoro-?2-?[5-?(trifluoromethyl)?-?2-?pyridinyl]?phenyl]?iridium(III) hexafluorophosphate is commonly used as a catalyst in the synthesis of various compounds such as saturated N-?heterocycles from aldehydes, fosmidomycin analogue, and many more.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

hexafluorophosphate Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

hexafluorophosphate Suppliers

Americas 1 China 83 Europe 1 India 1 Japan 1 United States 4 Global 91

Yunnan Precious Metals Laboratory Co., Ltd

Tel: 871-15559856 15559856215
Fax: 0871-68329797
Email: yujuan@ipm.com.cn
Country: China
ProdList: 225
Advantage: 58

Panjin Infinity Scientific CO. LTD

Tel: 400-1062016 18612996721
Fax: QQ25788917
Email: hao@infsci.com
Country: China
ProdList: 327
Advantage: 58

Changzhou Carman Chemical Co., ltd

Tel: 0519-0519-83534936 18151214939
Email: 1521178147@qq.com
Country: China
ProdList: 497
Advantage: 58

Jiangsu aikang biomedical research and development co., LTD

Tel: 025-58859352 13155353615
Email: qzhang@aikonchem.com
Country: China
ProdList: 15525
Advantage: 58

Shanghai Chemilab Biotechnology CO.,Ltd

Tel: 18116465878
Email: kmlb@kaimilaibo.com
Country: China
ProdList: 2627
Advantage: 58

Beijing HwrkChemical Technology Co., Ltd

Tel: 18515581800 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 9400
Advantage: 55

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 15883
Advantage: 64

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
Advantage: 75

More

Less

View Lastest Price from hexafluorophosphate manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: hexafluorophosphate 870987-63-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 10000KGS
Release date: 2025-05-21

Zhejiang Free Trade Zone Violet Trade Co., Ltd.

Product: [Ir (dF (CF3) ppy)2(dtbpy)]PF6 870987-63-6
Price: US $0.00/g
Min. Order: 1g
Purity: 99.90%
Supply Ability: 100kgs
Release date: 2021-09-16

Xian confluore Biological Technology Co., Ltd.

Product: (Ir[dF(CF3)ppy]2(dtbpy))PF6 870987-63-6
Price: US $0.00/g
Min. Order: 1g
Purity: >99.00%
Supply Ability: 1g
Release date: 2024-03-30

870987-63-6, hexafluorophosphateRelated Search:

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir{dFCF3ppy}2(bpy)]PF6 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6

bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+)

4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine

Ir[dF(CF3)ppy]2(dtbbpy)PF6

(4,4'-DI-T-BUTYL-2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-TRIFLUOROMETHYL-2-PYRIDINYL-KN)PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE,99%

[Ir(dtbbpy)[dF(CF3)ppy]2]PF6

4,4-Bis(tert-butyl)-2,2-bipyridine]bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium(III)hexafluorophosphate

(4,4'-Di-t-butyL

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kappaN)phenyl-kappaC]iridium(III) Hexafluorophosphate

Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-, (OC-6-33)-, hexafluorophosphate(1-) (1:1)

(OC-6-33)-[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]-Iridium(1+) hexafluorophosphate(1-) (1:1)

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-κN)phenyl-κC]iridium(III) Hexafluorophosphate

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) hexafluorophosphate

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Ir[dF(CF3)ppy]2(dtbbpy)PF6 Chembeads (0.003μmol/mg)

(OC-6-33)-[4,4'-Bis(tert-butyl)-2,2'-bipyridin-kappaN1,kappaN1']bis[3,5-difluoro-2-[5-(trifluoromethyl)-pyridin-2-yl-kappan]phenyl-kappac]-iridium(I) hexafluorophosphate(I)

870987-63-6

C42H34F16IrN4P