[Ir{dFCF3ppy}2(bpy)]PF6

Reaction

Product Name: [Ir{dFCF3ppy}2(bpy)]PF6
CAS No.: 1092775-62-6
Chemical Name: [Ir{dFCF3ppy}2(bpy)]PF6
Synonyms: uoro-2-[5-trifL;[Ir{dFCF3ppy}2(bpy)]PF6;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE
CBNumber: CB33150909
Molecular Formula: C34H18F16IrN4P
Formula Weight: 1009.6987322
MOL File: 1092775-62-6.mol

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[Ir{dFCF3ppy}2(bpy)]PF6 Property

storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Powder
color: yellow
Sensitive: air sensitive

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 804215
Product name: [Ir{dFCF3ppy}2(bpy)]PF6
Packaging: 50mg
Price: $96.4
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0220
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging: 50mg
Price: $66
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0220
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging: 250mg
Price: $262
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0453
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 50mg
Price: $73
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0453
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 250mg
Price: $294
Updated: 2024/03/01

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[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties,Usage,Production

Reaction

Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
Photocatalyst used in the cross-coupling of trifluoroalkylboranes.

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp³ hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir{dFCF3ppy}2(bpy)]PF6 Suppliers

Americas 1 China 55 Europe 1 India 1 Japan 1 United States 4 Global 63

Tianjin Kailiqi Biotechnology Co., Ltd.

Tel: 15076683720
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Beijing HwrkChemical Technology Co., Ltd

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Email: Sales-JP@TCIchemicals.com
Country: Japan
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Suzhou Laing Biological Technology Co., LTD

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Sigma-Aldrich

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Alfa Chemistry

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Chengdu Xiaojia Technology Co., Ltd.

Tel: 15902830537
Email: zhanghao@happysyn.com
Country: China
ProdList: 2003
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View Lastest Price from [Ir{dFCF3ppy}2(bpy)]PF6 manufacturers

Xian confluore Biological Technology Co., Ltd.

Product: (Ir[dFCF3ppy]2(bpy))PF6 1092775-62-6
Price: US $0.00/g
Min. Order: 1g
Purity: >99.00%
Supply Ability: 1g
Release date: 2024-03-30

1092775-62-6, [Ir{dFCF3ppy}2(bpy)]PF6Related Search:

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6

[Ir{dFCF3ppy}2(bpy)]PF6

Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate

(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE

Ir[dF(CF3)2ppy]2(bpy)]PF6

(2,2'-Bipyridine)bis[3,5-difL

uoro-2-[5-trifL

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate

2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide

2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine

Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate,

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate

(2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate

1092775-62-6

C34H18F16IrN4P