[Ir{dFCF3ppy}2(bpy)]PF6

Reaction

Product Name: [Ir{dFCF3ppy}2(bpy)]PF6
CAS No.: 1092775-62-6
Chemical Name: [Ir{dFCF3ppy}2(bpy)]PF6
Synonyms: uoro-2-[5-trifL;[Ir{dFCF3ppy}2(bpy)]PF6;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;[Ir{dFCF₃ppy}₂(bpy)]PF₆;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
CBNumber: CB33150909
Molecular Formula: C34H18F16IrN4P
Formula Weight: 1009.6987322
MOL File: 1092775-62-6.mol

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[Ir{dFCF3ppy}2(bpy)]PF6 Property

storage temp.: Keep in dark place,Inert atmosphere,Room temperature
form: Powder
color: yellow
Sensitive: air sensitive
InChIKey: ZCNUFCYLERNPGN-UHFFFAOYSA-N

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 804215
Product name: [Ir{dFCF3ppy}2(bpy)]PF6
Packaging: 50mg
Price: $99.4
Updated: 2025/07/31

TCI Chemical

Product number: B6161
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
Packaging: 200MG
Price: $170
Updated: 2025/07/31

TCI Chemical

Product number: B6161
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
Packaging: 1G
Price: $510
Updated: 2025/07/31

Strem Chemicals

Product number: 77-0220
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging: 50mg
Price: $66
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0220
Product name: (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging: 250mg
Price: $262
Updated: 2024/03/01

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[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties,Usage,Production

Reaction

Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
Photocatalyst used in the cross-coupling of trifluoroalkylboranes.

Chemical Properties

The presence of fluorine atoms in the molecule of bis[2-(2,4-difluorophenyl)-5-trifluoromethylpyridine][2-2'-bipyridyl]iridium bis(hexafluorophosphate) salts gives them high thermal and chemical stability. Secondly, the introduction of iridium(III) ions endows it with unique luminescent properties, which makes it potentially applicable in the field of organic electroluminescence. In addition, the compound has good redox properties and photoelectric conversion efficiency, which provides the possibility of its application in solar cells, photovoltaic devices and other fields.

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp³ hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

reaction suitability

core: iridium
reagent type: catalyst
reaction type: Photocatalysis

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir{dFCF3ppy}2(bpy)]PF6 Suppliers

Americas 1 China 57 Europe 1 India 1 Japan 1 United States 3 Global 64

Tianjin Kailiqi Biotechnology Co., Ltd.

Tel: 15076683720
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Email: Sales-JP@TCIchemicals.com
Country: Japan
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Sigma-Aldrich

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Alfa Chemistry

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Shanghai Haozhixiang Biotechnology Co., Ltd

Tel: 526763801 13301653310
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ProdList: 9274
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View Lastest Price from [Ir{dFCF3ppy}2(bpy)]PF6 manufacturers

Xian confluore Biological Technology Co., Ltd.

Product: (Ir[dFCF3ppy]2(bpy))PF6 1092775-62-6
Price: US $0.00/g
Min. Order: 1g
Purity: >99.00%
Supply Ability: 1g
Release date: 2024-03-30

1092775-62-6, [Ir{dFCF3ppy}2(bpy)]PF6Related Search:

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6

[Ir{dFCF3ppy}2(bpy)]PF6

Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate

(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE

Ir[dF(CF3)2ppy]2(bpy)]PF6

(2,2'-Bipyridine)bis[3,5-difL

uoro-2-[5-trifL

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate

2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide

2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine

Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate,

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate

(2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

[Ir{dFCF3ppy}2(bpy)]PF6

(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

1092775-62-6

C34H18F16IrN4P