Reaction
ChemicalBook > CAS DataBase List > [Ir{dFCF3ppy}2(bpy)]PF6

[Ir{dFCF3ppy}2(bpy)]PF6

Reaction
Product Name
[Ir{dFCF3ppy}2(bpy)]PF6
CAS No.
1092775-62-6
Chemical Name
[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms
uoro-2-[5-trifL;[Ir{dFCF3ppy}2(bpy)]PF6;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
CBNumber
CB33150909
Molecular Formula
C34H18F16IrN4P
Formula Weight
1009.6987322
MOL File
1092775-62-6.mol
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[Ir{dFCF3ppy}2(bpy)]PF6 Property

storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
yellow
Sensitive 
air sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
804215
Product name
[Ir{dFCF3ppy}2(bpy)]PF6
Packaging
50mg
Price
$96.4
Updated
2024/03/01
Strem Chemicals
Product number
77-0220
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging
50mg
Price
$66
Updated
2024/03/01
Strem Chemicals
Product number
77-0220
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging
250mg
Price
$262
Updated
2024/03/01
Strem Chemicals
Product number
77-0453
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging
50mg
Price
$73
Updated
2024/03/01
Strem Chemicals
Product number
77-0453
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging
250mg
Price
$294
Updated
2024/03/01
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[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties,Usage,Production

Reaction

  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir{dFCF3ppy}2(bpy)]PF6 Suppliers

Americas 1 China 50 Europe 1 India 1 Japan 1 United States 4 Global 58
BeiJing Hwrk Chemicals Limted
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0757-86329057 18501085097
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Daicel Chiral Technologies (China)CO.,LTD
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021-50460086-9 15921403865
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+86-21-50462321
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TOKYO CHEMICAL INDUSTRY CO., LTD.
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03-36680489
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03-3668-0520
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Sales-JP@TCIchemicals.com
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Japan
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TCI Europe
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320-37350700
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+32 (0)37350701
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sales@tcieurope.eu
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Europe
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TCI AMERICA
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+1-888-520-1075 / +1-503-283-1987
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Bide Pharmatech Ltd.
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400-1647117 15221909166
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+86-21-61629029
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product02@bidepharm.com
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Suzhou Laing Biological Technology Co., LTD
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Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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Alfa Chemistry
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1-516-6625404
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1-516-927-0118
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support@alfa-chemistry.com
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United States
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Chengdu Xiaojia Technology Co., Ltd.
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15902830537
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3644356552@qq.com
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China
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View Lastest Price from [Ir{dFCF3ppy}2(bpy)]PF6 manufacturers

Xian confluore Biological Technology Co., Ltd.
Product
(Ir[dFCF3ppy]2(bpy))PF6 1092775-62-6
Price
US $0.00/g
Min. Order
1g
Purity
>99.00%
Supply Ability
1g
Release date
2024-03-30

1092775-62-6, [Ir{dFCF3ppy}2(bpy)]PF6Related Search:

Tris[2-(2-pyridinyl-κN)-5-(trifluoromethyl)phenyl-κC]iridium(III) Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III) Ir[dF(t-Bu)-ppy]3 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate Iridium [2,2'-bis (4-tert-butylpyridine)] bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate (2,2'-bipyridyl) bis [2- (4-fluorophenyl) pyridine] iridium (III) hexafluorophosphate Tris (2- (4-tert-butylphenyl) pyridine) iridium Ir[dF(Me)ppy]2(dtbbpy)PF6 Ir(dFppy)3 (2,2'-Bipyridine)bis(2-phenylpyridinato)iridium(III) Hexafluorophosphate Ir[p-F(t-Bu)-ppy]3 [Ir(dtbbpy)(ppy)2][PF6] Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6

  • [Ir{dFCF3ppy}2(bpy)]PF6
  • Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate
  • (2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE
  • Ir[dF(CF3)2ppy]2(bpy)]PF6
  • (2,2'-Bipyridine)bis[3,5-difL
  • uoro-2-[5-trifL
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate
  • 2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide
  • 2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine
  • Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate,
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
  • (2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
  • 1092775-62-6
  • C34H18F16IrN4P