[Ir(dtbbpy)(ppy)2][PF6]

Reaction

Product Name: [Ir(dtbbpy)(ppy)2][PF6]
CAS No.: 676525-77-2
Chemical Name: [Ir(dtbbpy)(ppy)2][PF6]
Synonyms: Ir(ppy)2(dtbbpy)PF6;[Ir(dtbbpy)(ppy);[Ir(dtbbpy)(ppy)2][PF6];-2,2'-bipyridine)bis[(2-pyridinyL;[Ir(dtbbpy)(ppy)₂]PF₆;[Ir(dtbbpy)(ppy)2]PF6[[Ir(dtbbpy)(ppy)2]PF6];[Ir(dtbbpy)(ppy)2]PF6, high-purity crystalline;Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[2-(2-p...;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
CBNumber: CB32750362
Molecular Formula: C40H40F6IrN4P
Formula Weight: 913.97
MOL File: 676525-77-2.mol

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[Ir(dtbbpy)(ppy)2][PF6] Property

storage temp.: 2-8°C
form: crystal
color: yellow
λmax: 380nm(CH2Cl2)(lit.)
InChI: 1S/C18H24N2.2C11H8N.F6P.Ir/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6;2*1-2-6-10(7-3-1)11-8-4-5-9-12-11;1-7(2,3,4,5)6;/h7-12H,1-6H3;2*1-6,8-9H;;
InChIKey: VCIVELSSYHAWGC-UHFFFAOYSA-N
SMILES: [P+5]([F-])([F-])([F-])([F-])([F-])[F-].C(C1=CC=N2[Ir+3]34(N5=CC=CC=C5C5=CC=CC=[C-]35)(N3=CC=CC=C3C3=CC=CC=[C-]43)N3=CC=C(C(C)(C)C)C=C3C2=C1)(C)(C)C

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Safety

Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
TSCA: No
HS Code: 2843.90.0000
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 747769
Product name: [Ir(dtbbpy)(ppy)2]PF6
Packaging: 50mg
Price: $102.12
Updated: 2025/07/31

Sigma-Aldrich

Product number: 747769
Product name: [Ir(dtbbpy)(ppy)
Packaging: 100mg
Price: $212
Updated: 2025/07/31

TCI Chemical

Product number: D4887
Product name: (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
Purity: >85.0%(HPLC)
Packaging: 200mg
Price: $324
Updated: 2025/07/31

Strem Chemicals

Product number: 77-0410
Product name: (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 100mg
Price: $95
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0410
Product name: (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 500mg
Price: $382
Updated: 2024/03/01

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[Ir(dtbbpy)(ppy)2][PF6] Chemical Properties,Usage,Production

Reaction

This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
Numerous uses of this photoredox catalyst are reported

Uses

[Ir(dtbbpy)(ppy)₂]PF₆ is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
Aryl-alkyl CC reductive cross-coupling reactions.

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

Synthesis

Dichlorobridged dimer (0.1 mmol) was reacted with the appropriate neutral ligand (0.22 mmol) in ethylene glycol (5.0 mL) at reflux (150C) for 15 h with continuous stirring. After cooling to room temperature, the mixture was transferred to a dispensing funnel with water (3 x 30 mL) and washed (except in the case of C^N) dtbppy with ether (3 x 50 mL). The aqueous layer was heated to 70C for 5 min using a heat gun to remove residual organic solvent. The vessel was then placed on ice and 10 mL of aqueous ammonium hexafluorophosphate (1.0 g in 10 mL of deionized water) was slowly added to the reaction mixture to obtain a colored suspension. The precipitate was collected by suction filtration and allowed to air dry overnight. The product was recrystallized by acetonitrile:ether vapor diffusion (except for C^N) dtbppy, where hexane:acetone vapor diffusion was used) and dried under vacuum (100C) for 24 hr to give the pure product (4,4'-di-tert-butyl-2,2'-bipyridine)bis[(2-pyridyl)phenyl]iridium(III) hexafluorophosphate (yield: 68- 80%).

[Ir(dtbbpy)(ppy)2][PF6] Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir(dtbbpy)(ppy)2][PF6] Suppliers

Americas 1 China 107 Europe 1 India 2 Japan 1 United Kingdom 1 United States 7 Global 120

Yunnan Precious Metals Laboratory Co., Ltd

Tel: 871-15559856 15559856215
Fax: 0871-68329797
Email: yujuan@ipm.com.cn
Country: China
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Tel: 010-010-57302162 17611011830
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Guiyan Chemical Materials (Yunnan) Co., LTD

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Country: China
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Shanghai Jiahua Herong Biotechnology Co., Ltd

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Country: China
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TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
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Beijing HwrkChemical Technology Co., Ltd

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Email: sales.bj@hwrkchemical.com
Country: China
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Energy Chemical

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Email: sales8178@energy-chemical.com
Country: China
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Chengdu Forest Science and Technology Development Co., Ltd.

Tel: 18030648795 18030648795
Fax: 028-61777050
Email: sales@cdforestchem.com
Country: China
ProdList: 2000
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TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
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View Lastest Price from [Ir(dtbbpy)(ppy)2][PF6] manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.

Product: [Ir(ppy)2(dtbbpy)] PF6 676525-77-2
Price: US $0.00/g
Min. Order: 1g
Purity: 99.90%
Supply Ability: 100kgs
Release date: 2021-09-16

Xian confluore Biological Technology Co., Ltd.

Product: Ir(ppy)2(dtbbpy)PF6 676525-77-2
Price: US $0.00/g
Min. Order: 5g
Purity: >95.00%
Supply Ability: 5g
Release date: 2024-03-30

Career Henan Chemical Co

Product: [Ir(dtbbpy)(ppy)2][PF6] 676525-77-2
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 10kg
Release date: 2018-12-18

676525-77-2, [Ir(dtbbpy)(ppy)2][PF6]Related Search:

Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6 Coumarin 30 COUMARIN 152 7-DIETHYLAMINO-4-(TRIFLUOROMETHYL)COUMARIN Exciton Coumarin 545 Coumarin 153 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate 2,6-bis(diphenylaMino)anthracene-9,10-dione Tris(2-phenylpyridine)iridium (Ir(ppy)3) Bis[2-(2-benzothiazoly)phenolato]zinc(II) N,N'- Dibutylquinacridone Coumarin 6 COUMARIN 7 Rhodamine B

[Ir(dtbbpy)(ppy)2][PF6]

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate

[Ir(dtbbpy)(ppy)

Ir(ppy)2(dtbbpy)PF6

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%

[4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate

(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate

-2,2'-bipyridine)bis[(2-pyridinyL

[Ir(dtbbpy)(ppy)2]PF6[[Ir(dtbbpy)(ppy)2]PF6]

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

[Ir(dtbbpy)(ppy)2]PF6

4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine iridium(3+) 2-phenylpyridine hexafluorophosphate

[Ir(dtbbpy)(ppy)2]PF6, high-purity crystalline

Iridium(1+), [4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[2-(2-p...

676525-77-2

C40H40F6IrN4P

C22H16IrN2C18H24N2F6P