[Ir(dtbbpy)(ppy)2][PF6]

ChemicalBook > CAS DataBase List > [Ir(dtbbpy)(ppy)2][PF6]

[Ir(dtbbpy)(ppy)2][PF6]

Reaction

Product Name: [Ir(dtbbpy)(ppy)2][PF6]
CAS No.: 676525-77-2
Chemical Name: [Ir(dtbbpy)(ppy)2][PF6]
Synonyms: Ir(ppy)2(dtbbpy)PF6;[Ir(dtbbpy)(ppy);[Ir(dtbbpy)(ppy)2][PF6];-2,2'-bipyridine)bis[(2-pyridinyL;[Ir(dtbbpy)(ppy)2]PF6[[Ir(dtbbpy)(ppy)2]PF6];(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate;[4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate;(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
CBNumber: CB32750362
Molecular Formula: C40H40F6IrN4P
Formula Weight: 913.97
MOL File: 676525-77-2.mol

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[Ir(dtbbpy)(ppy)2][PF6] Property

storage temp.: 2-8°C
form: crystal
color: yellow
λmax: 380nm(CH2Cl2)(lit.)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26
WGK Germany: 3
TSCA: No
HS Code: 2843.90.0000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 747769
Product name: [Ir(dtbbpy)(ppy)2]PF6
Packaging: 50mg
Price: $108
Updated: 2024/03/01

Sigma-Aldrich

Product number: 747769
Product name: [Ir(dtbbpy)(ppy)
Packaging: 100mg
Price: $206
Updated: 2024/03/01

TCI Chemical

Product number: D4887
Product name: (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
Purity: >85.0%(HPLC)
Packaging: 200mg
Price: $324
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0410
Product name: (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 100mg
Price: $95
Updated: 2024/03/01

Strem Chemicals

Product number: 77-0410
Product name: (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging: 500mg
Price: $382
Updated: 2024/03/01

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[Ir(dtbbpy)(ppy)2][PF6] Chemical Properties,Usage,Production

Reaction

This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
Numerous uses of this photoredox catalyst are reported

Uses

[Ir(dtbbpy)(ppy)₂]PF₆ is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
Aryl-alkyl C?C reductive cross-coupling reactions.

reaction suitability

core: iridium
reaction type: Photocatalysis
reagent type: catalyst

[Ir(dtbbpy)(ppy)2][PF6] Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir(dtbbpy)(ppy)2][PF6] Suppliers

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View Lastest Price from [Ir(dtbbpy)(ppy)2][PF6] manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.

Product: [Ir(ppy)2(dtbbpy)] PF6 676525-77-2
Price: US $0.00/g
Min. Order: 1g
Purity: 99.90%
Supply Ability: 100kgs
Release date: 2021-09-16

Xian confluore Biological Technology Co., Ltd.

Product: Ir(ppy)2(dtbbpy)PF6 676525-77-2
Price: US $0.00/g
Min. Order: 5g
Purity: >95.00%
Supply Ability: 5g
Release date: 2024-03-30

Career Henan Chemical Co

Product: [Ir(dtbbpy)(ppy)2][PF6] 676525-77-2
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 10kg
Release date: 2018-12-18

676525-77-2, [Ir(dtbbpy)(ppy)2][PF6]Related Search:

Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6 Coumarin 30 COUMARIN 152 7-DIETHYLAMINO-4-(TRIFLUOROMETHYL)COUMARIN Exciton Coumarin 545 Coumarin 153 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate 2,6-bis(diphenylaMino)anthracene-9,10-dione Tris(2-phenylpyridine)iridium (Ir(ppy)3) Bis[2-(2-benzothiazoly)phenolato]zinc(II) N,N'- Dibutylquinacridone Coumarin 6 COUMARIN 7 Rhodamine B

[Ir(dtbbpy)(ppy)2][PF6]

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate

(4,4'-Di-<i>tert</i>-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate

[Ir(dtbbpy)(ppy)

Ir(ppy)2(dtbbpy)PF6

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%

[4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate

(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate

-2,2'-bipyridine)bis[(2-pyridinyL

[Ir(dtbbpy)(ppy)2]PF6[[Ir(dtbbpy)(ppy)2]PF6]

(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate

676525-77-2

C40H40F6IrN4P

C22H16IrN2C18H24N2F6P