Reaction
ChemicalBook > CAS DataBase List > [Ir(dtbbpy)(ppy)2][PF6]

[Ir(dtbbpy)(ppy)2][PF6]

Reaction
Product Name
[Ir(dtbbpy)(ppy)2][PF6]
CAS No.
676525-77-2
Chemical Name
[Ir(dtbbpy)(ppy)2][PF6]
Synonyms
Ir(ppy)2(dtbbpy)PF6;[Ir(dtbbpy)(ppy);[Ir(dtbbpy)(ppy)2][PF6];-2,2'-bipyridine)bis[(2-pyridinyL;[Ir(dtbbpy)(ppy)2]PF6[[Ir(dtbbpy)(ppy)2]PF6];(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate;[4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate;(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
CBNumber
CB32750362
Molecular Formula
C40H40F6IrN4P
Formula Weight
913.97
MOL File
676525-77-2.mol
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[Ir(dtbbpy)(ppy)2][PF6] Property

storage temp. 
2-8°C
form 
crystal
color 
yellow
λmax
380nm(CH2Cl2)(lit.)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
TSCA 
No
HS Code 
2843.90.0000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
747769
Product name
[Ir(dtbbpy)(ppy)2]PF6
Packaging
50mg
Price
$108
Updated
2024/03/01
Sigma-Aldrich
Product number
747769
Product name
[Ir(dtbbpy)(ppy)
Packaging
100mg
Price
$206
Updated
2024/03/01
TCI Chemical
Product number
D4887
Product name
(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
Purity
>85.0%(HPLC)
Packaging
200mg
Price
$324
Updated
2024/03/01
Strem Chemicals
Product number
77-0410
Product name
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging
100mg
Price
$95
Updated
2024/03/01
Strem Chemicals
Product number
77-0410
Product name
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging
500mg
Price
$382
Updated
2024/03/01
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[Ir(dtbbpy)(ppy)2][PF6] Chemical Properties,Usage,Production

Reaction

  1. This Iridium catalyst is used in the synthesis of β-amidovinyl sulfones via visible-light photoredox catalysis.
  2. Numerous uses of this photoredox catalyst are reported

Uses

[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

  • Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
  • Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
  • Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
  • Aryl-alkyl C?C reductive cross-coupling reactions.

[Ir(dtbbpy)(ppy)2][PF6] Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir(dtbbpy)(ppy)2][PF6] Suppliers

Americas 1 China 85 Europe 1 India 2 Japan 1 United Kingdom 1 United States 8 Global 99
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from [Ir(dtbbpy)(ppy)2][PF6] manufacturers

Zhejiang Free Trade Zone Violet Trade Co., Ltd.
Product
[Ir(ppy)2(dtbbpy)] PF6 676525-77-2
Price
US $0.00/g
Min. Order
1g
Purity
99.90%
Supply Ability
100kgs
Release date
2021-09-16
Xian confluore Biological Technology Co., Ltd.
Product
Ir(ppy)2(dtbbpy)PF6 676525-77-2
Price
US $0.00/g
Min. Order
5g
Purity
>95.00%
Supply Ability
5g
Release date
2024-03-30
Career Henan Chemical Co
Product
[Ir(dtbbpy)(ppy)2][PF6] 676525-77-2
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
10kg
Release date
2018-12-18

676525-77-2, [Ir(dtbbpy)(ppy)2][PF6]Related Search:

Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [1,10-phenanthroline] iridium hexafluorophosphate Ir[dFppy]2(dtbbpy)PF6 hexafluorophosphate Iridium(1+),[4,4'-bis(1,1-dimethylethyl)-2,2'-bipyridine-κN1,κN1']bis[5-(1,1-dimethylethyl)-2-[4-(1,1-dimethylethyl)-2-pyridinyl-κN]phenyl-κC]-,(OC-6-33)-,hexafluorophosphate(1-) Ir[p-F(Me)ppy]2(dtbbpy)PF6 Coumarin 30 COUMARIN 152 7-DIETHYLAMINO-4-(TRIFLUOROMETHYL)COUMARIN Exciton Coumarin 545 Coumarin 153 (2,2'-Bipyridine)bis[2-(2,4-difluorophenyl)pyridine]iridium(III) Hexafluorophosphate 2,6-bis(diphenylaMino)anthracene-9,10-dione Tris(2-phenylpyridine)iridium (Ir(ppy)3) Bis[2-(2-benzothiazoly)phenolato]zinc(II) N,N'- Dibutylquinacridone Coumarin 6 COUMARIN 7 Rhodamine B

  • [Ir(dtbbpy)(ppy)2][PF6]
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • (4,4'-Di-<i>tert</i>-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • [Ir(dtbbpy)(ppy)
  • Ir(ppy)2(dtbbpy)PF6
  • (4,4'-Di-t-butyl-2,2'-bipyridine)bis[2-(2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
  • [4,4'-Bis(tert-butyl)-2,2'-bipyridine]bis[2-(2-pyridinyl)phenyl]iridium(III) hexafluorophosphate
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)di[(2-pyridinyl-κN)phenyl-κC]iridium hexafluorophosphate
  • -2,2'-bipyridine)bis[(2-pyridinyL
  • [Ir(dtbbpy)(ppy)2]PF6[[Ir(dtbbpy)(ppy)2]PF6]
  • (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III) Hexafluorophosphate
  • 676525-77-2
  • C40H40F6IrN4P
  • C22H16IrN2C18H24N2F6P