Reaction
ChemicalBook > CAS DataBase List > [Ir{dFCF3ppy}2(bpy)]PF6

[Ir{dFCF3ppy}2(bpy)]PF6

Reaction
Product Name
[Ir{dFCF3ppy}2(bpy)]PF6
CAS No.
1092775-62-6
Chemical Name
[Ir{dFCF3ppy}2(bpy)]PF6
Synonyms
uoro-2-[5-trifL;[Ir{dFCF3ppy}2(bpy)]PF6;Ir[dF(CF3)2ppy]2(bpy)]PF6;(2,2'-Bipyridine)bis[3,5-difL;2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine;Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate;(2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate;(2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE;(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
CBNumber
CB33150909
Molecular Formula
C34H18F16IrN4P
Formula Weight
1009.6987322
MOL File
1092775-62-6.mol
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[Ir{dFCF3ppy}2(bpy)]PF6 Property

storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Powder
color 
yellow
Sensitive 
air sensitive
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
804215
Product name
[Ir{dFCF3ppy}2(bpy)]PF6
Packaging
50mg
Price
$96.4
Updated
2024/03/01
Strem Chemicals
Product number
77-0220
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging
50mg
Price
$66
Updated
2024/03/01
Strem Chemicals
Product number
77-0220
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kN][phenyl-kC]iridium(III) hexafluorophosphate, 95%
Packaging
250mg
Price
$262
Updated
2024/03/01
Strem Chemicals
Product number
77-0453
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging
50mg
Price
$73
Updated
2024/03/01
Strem Chemicals
Product number
77-0453
Product name
(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate, 99%
Packaging
250mg
Price
$294
Updated
2024/03/01
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[Ir{dFCF3ppy}2(bpy)]PF6 Chemical Properties,Usage,Production

Reaction

  1. Catalyst used for the chemo-, regio, and stereoselective trifluoromethylation of styrene.
  2. Photoredox catalyst used in cross-coupling: Ir/Ni dual catalysts for the synthesis of benzylic ethers.
  3. Iridium complex used for catalytic olefin hydroamidation enabled by proton-coupled electron transfer.
  4. Catalyst used for visible light photoredox cross-coupling of acyl chlorides with potassium alkoxymethyltrifluoroborates.
  5. Iridium catalyst used in the photoredox/nickel dual catalytic cross-coupling of secondary alkyl β-trifluoroboratoketones and –esters with aryl bromides.
  6. Photocatalyst used in the cross-coupling of trifluoroalkylboranes.

Uses

When used in tandem with a nickel catalyst, the above photoredox catalyst effects the cross-coupling of C-sp3 hybridized trifluoroborates with aryl bromides under exceptionally mild conditions.

[Ir{dFCF3ppy}2(bpy)]PF6 Preparation Products And Raw materials

Raw materials

Preparation Products

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[Ir{dFCF3ppy}2(bpy)]PF6 Suppliers

TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from [Ir{dFCF3ppy}2(bpy)]PF6 manufacturers

Xian confluore Biological Technology Co., Ltd.
Product
(Ir[dFCF3ppy]2(bpy))PF6 1092775-62-6
Price
US $0.00/g
Min. Order
1g
Purity
>99.00%
Supply Ability
1g
Release date
2024-03-30

1092775-62-6, [Ir{dFCF3ppy}2(bpy)]PF6Related Search:


  • [Ir{dFCF3ppy}2(bpy)]PF6
  • Bis [2- (2,4-difluorophenyl) -5-trifluoromethylpyridine] [2-2'-bipyridyl] iridium hexafluorophosphate
  • (2,2'-BIPYRIDINE)BIS[3,5-DIFLUORO-2-[5-(TRIFLUOROMETHYL)-2-PYRIDINYL-KN][PHENYL-KC]IRIDIUM(III)HEXAFLUOROPHOSPHATE
  • Ir[dF(CF3)2ppy]2(bpy)]PF6
  • (2,2'-Bipyridine)bis[3,5-difL
  • uoro-2-[5-trifL
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-kappaN][phenyl-kappaC]iridium(III) Hexafluorophosphate
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]iridium(III) Hexafluorophosphate
  • 2,2'-bipyridine, bis({3,5-difluoro-2-[5-(trifluoromethyl)pyridin-2-yl]phenyl})iridiumylium, hexafluoro-lambda5-phosphanuide
  • 2-(2,4-difluorobenzene-6-id-1-yl)-5-(trifluoromethyl)pyridine
  • Ir{dFCF3ppy}2(bpy)]PF6,(2,2'-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate,
  • (2,2'-Bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN][phenyl-κC]iridium(III) Hexafluorophosphate
  • (2,2''-Bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
  • 1092775-62-6
  • C34H18F16IrN4P