ε-Caprolactone

Product Name: ε-Caprolactone
CAS No.: 502-44-3
Chemical Name: ε-Caprolactone
Synonyms: CAPROLACTONE;2-OXEPANONE;oxepan-2-one;EPSILON-CAPROLACTONE;E-CAPROLACTONE;Oxepanone;6-HEXANOLACTONE;Polycaprolactone Polyol;6-CAPROLACTONE;6-Hydroxyhexan-6-olide
CBNumber: CB1362738
Molecular Formula: C6H10O2
Formula Weight: 114.14
MOL File: 502-44-3.mol

More

Less

ε-Caprolactone Property

Melting point:: -1 °C
Boiling point:: 96-97.5 °C10 mm Hg(lit.)
Density: 1.03 g/mL at 25 °C(lit.)
vapor density: 3.9 (vs air)
vapor pressure: 0.01 mm Hg ( 20 °C)
refractive index: n20/D 1.463(lit.)
Flash point:: 229 °F
storage temp.: Store below +30°C.
solubility: Chloroform, Ethyl Acetate
form: Liquid
color: Clear colorless, yellowing on aging
explosive limit: 1.2-9%(V)
Water Solubility: >1000 MG/L (20 ºC)
BRN: 106919
InChIKey: PAPBSGBWRJIAAV-UHFFFAOYSA-N
LogP: 0.32 at 20℃
CAS DataBase Reference: 502-44-3(CAS DataBase Reference)
NIST Chemistry Reference: 2-Oxepanone(502-44-3)
EPA Substance Registry System: 2-Oxepanone (502-44-3)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 37/38-41-36/38
Safety Statements: 26-39-37/39
WGK Germany: 2
RTECS: MO8400000
Autoignition Temperature: 204 °C
TSCA: Yes
HS Code: 29322090
Hazardous Substances Data: 502-44-3(Hazardous Substances Data)
Toxicity: LD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rabbit 5990 mg/kg

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 704067
Product name: ω-Caprolactone
Purity: 97%
Packaging: 100g
Price: $42.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.02801
Product name: ε-Caprolactone
Purity: for synthesis
Packaging: 250ML
Price: $60.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 704067
Product name: ω-Caprolactone
Purity: 97%
Packaging: 500g
Price: $141
Updated: 2024/03/01

TCI Chemical

Product number: C0702
Product name: epsilon-Caprolactone
Purity: >99.0%(GC)
Packaging: 25mL
Price: $17
Updated: 2024/03/01

TCI Chemical

Product number: C0702
Product name: epsilon-Caprolactone
Purity: >99.0%(GC)
Packaging: 500mL
Price: $41
Updated: 2024/03/01

More

Less

ε-Caprolactone Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid, yellowing on ageing

Uses

Intermediate in adhesives, urethane coatings, and elastomers; solvent; diluent for epoxy resins; synthetic fibers; organic synthesis.

Uses

ε-Caprolactone is widely used as a monomer in the manufacturing of highly specialized polymers. It is mainly utilized as a precursor to caprolactam. It finds an application in the synthesis of polyglecaprone, which is used as a suture material in surgery.

Uses

ε-caprolactone is popularly used in the preparation of poly caprolactone (PCL).

Definition

ChEBI: A epsilon-lactone that is oxepane substituted by an oxo group at position 2.

Synthesis Reference(s)

Journal of the American Chemical Society, 80, p. 4079, 1958 DOI: 10.1021/ja01548a063
The Journal of Organic Chemistry, 61, p. 4560, 1996 DOI: 10.1021/jo952237x
Tetrahedron Letters, 17, p. 2455, 1976 DOI: 10.1016/0040-4039(76)90018-6

General Description

ε-caprolactone is a cyclic ester. Ring opening polymerization of ε-caprolactone initiated by, tributylin n butoxide, ethyl magnesium bromide, or samarium acetate or heteropolyacid, leads to the formation of poly caprolactone (PCL).

Flammability and Explosibility

Not classified

ε-Caprolactone Preparation Products And Raw materials

Raw materials

Peroxyacetic acid Ozone Cyclohexanone

Preparation Products

More

Less

ε-Caprolactone Suppliers

Americas 1 Australia 1 Belgium 3 Canada 2 China 309 Europe 4 France 1 Germany 9 India 11 Japan 8 Slovakia 1 South Africa 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 11 United States 32 Global 398

Acros Organics (Part of Thermo Fisher Scientific )

Tel: --
Fax: --
Email: fo@acros.com
Country: Belgium
ProdList: 3824
Advantage: 58

Alkemi BVBA

Tel: --
Fax: --
Email: nfo@alkemi.be
Country: Belgium
ProdList: 2201
Advantage: 58

Acros Organics

Tel: --
Fax: --
Email: info@acros.com
Country: Belgium
ProdList: 6772
Advantage: 81

More

Less

View Lastest Price from ε-Caprolactone manufacturers

Shandong Deshang Chemical Co., Ltd.

Product: ε-Caprolactone 502-44-3
Price: US $10.00-5.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 tons
Release date: 2024-08-15

Hebei Weibang Biotechnology Co., Ltd

Product: 6-Hexanalactone 502-44-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-30

Hebei Weibang Biotechnology Co., Ltd

Product: 6-Hexanolactone 502-44-3
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-10-25

502-44-3, ε-CaprolactoneRelated Search:

Spironolactone Dodecyl acrylate Styrene D-(+)-Glucono-1,5-lactone γ-Valerolactone Gibberellin A4 PICROTOXIN DL-CAMPHORIC ANHYDRIDE PICROTOXININ Polycaprolactone (1R,3S)-(-)-CAMPHORIC ANHYDRIDE Cyclobutane-1,2,3,4-tetracarboxylic dianhydride Nomilin 22(S),23(S)-HOMOBRASSINOLIDE Brassinolide POLYCAPROLACTONE-BLOCK-POLYTETRAHYDROFURAN-BLOCK-POLYCAPROLACTONE 7-BUTYL-2-OXEPANONE heteratisine

2-oxo-hexamethyleneoxid

5-Caprolactone

6-Caprolactone monomer

6-Hexanalactone

6-Hexanolacetone

6-Hydroxyhexan-6-olide

6-Hydroxyhexanoic acid lactone

6-hydroxyhexanoicacidlactone

6-hydroxy-hexanoicaciepsilon-lactone

6-hydroxy-hexanoicacilactone

caprolactonemonomer

epsilon-Kaprolakton

Polycaprolactone Polyol

24,25-Dihydroxy Fusidic Acid &epsilon

epsilon-Hexalactone epsilon-Hexanolactone

Epsilon-CaprolaCLone MonoMer

E-CAPROLACTONE FOR SYNTHESIS

epsilon-Caprolactone 97%

1,6-Hexanolide

1-Oxa-2-oxocycloheptane

2-Oxacycloheptanone

Hexanoic acid, epsilon-lactone

hexanoicacid,epsilon-lactone

oxepan-2-one

Placcel M

placcelm

epsilon-Caprolactone MonoMer, 99% 1KG

epsilon-Caprolactone MonoMer, 99% 250GR

epsilon-kaprolakton(czech)

Hexamethylene oxide, 2-oxo-

Hexan-6-olide

Hexanoic acid, 6-hydroxy-, epsilon-lactone

Hexanoic acid, 6-hydroxy-, lactone

&epsi:-Caprolactone monomer

hexano-6-lactone

ε-Caprolactone 〔6-Hexanolide〕

ε-CaproL

2-OXEPANONE

6-Hexanolactone~2-Oxepanone

6-CAPROLACTONE

6-HEXANOLACTONE

6-HEXANOLIDE

6-HYDROXYCAPROIC ACID LACTONE

CAPROLACTONE

E-CAPROLACTONE

EPSILON-CAPROLACTONE

EPSILON-HEXALACTONE

EPSILON-HEXANOLACTONE

EPSILON-CAPROLACTONE MONOMER

gama-Caprolactone

gama-Hexalactone

EPSILON-CAPROLACTONE, 99+%

E-CAPROLACTONE MONOMER

epsilon-Caprolactone monomer, 99+%

EPSILON-HEXANOICLACTONE

1-isocyanato-4-[(4-isocyanatocyclohexyl)methyl]cyclohexane

2-Oxepanone, 6-Caprolactone monomer, 6-Hexanolactone

Oxepanone