ε-Caprolactone
- Product Name
- ε-Caprolactone
- CAS No.
- 502-44-3
- Chemical Name
- ε-Caprolactone
- Synonyms
- CAPROLACTONE;2-OXEPANONE;oxepan-2-one;EPSILON-CAPROLACTONE;E-CAPROLACTONE;Oxepanone;6-HEXANOLACTONE;Polycaprolactone Polyol;6-CAPROLACTONE;6-Hydroxyhexan-6-olide
- CBNumber
- CB1362738
- Molecular Formula
- C6H10O2
- Formula Weight
- 114.14
- MOL File
- 502-44-3.mol
ε-Caprolactone Property
- Melting point:
- -1 °C
- Boiling point:
- 96-97.5 °C10 mm Hg(lit.)
- Density
- 1.03 g/mL at 25 °C(lit.)
- vapor density
- 3.9 (vs air)
- vapor pressure
- 0.01 mm Hg ( 20 °C)
- refractive index
- n20/D 1.463(lit.)
- Flash point:
- 229 °F
- storage temp.
- Store below +30°C.
- solubility
- Chloroform, Ethyl Acetate
- form
- Liquid
- color
- Clear colorless, yellowing on aging
- explosive limit
- 1.2-9%(V)
- Water Solubility
- >1000 MG/L (20 ºC)
- BRN
- 106919
- InChIKey
- PAPBSGBWRJIAAV-UHFFFAOYSA-N
- LogP
- 0.32 at 20℃
- CAS DataBase Reference
- 502-44-3(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Oxepanone(502-44-3)
- EPA Substance Registry System
- 2-Oxepanone (502-44-3)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 37/38-41-36/38
- Safety Statements
- 26-39-37/39
- WGK Germany
- 2
- RTECS
- MO8400000
- Autoignition Temperature
- 204 °C
- TSCA
- Yes
- HS Code
- 29322090
- Hazardous Substances Data
- 502-44-3(Hazardous Substances Data)
- Toxicity
- LD50 orally in Rabbit: > 2000 mg/kg LD50 dermal Rabbit 5990 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 704067
- Product name
- ω-Caprolactone
- Purity
- 97%
- Packaging
- 100g
- Price
- $42.8
- Updated
- 2024/03/01
- Product number
- 8.02801
- Product name
- ε-Caprolactone
- Purity
- for synthesis
- Packaging
- 250ML
- Price
- $60.3
- Updated
- 2024/03/01
- Product number
- 704067
- Product name
- ω-Caprolactone
- Purity
- 97%
- Packaging
- 500g
- Price
- $141
- Updated
- 2024/03/01
- Product number
- C0702
- Product name
- epsilon-Caprolactone
- Purity
- >99.0%(GC)
- Packaging
- 25mL
- Price
- $17
- Updated
- 2024/03/01
- Product number
- C0702
- Product name
- epsilon-Caprolactone
- Purity
- >99.0%(GC)
- Packaging
- 500mL
- Price
- $41
- Updated
- 2024/03/01
ε-Caprolactone Chemical Properties,Usage,Production
Chemical Properties
Clear colorless liquid, yellowing on ageing
Uses
Intermediate in adhesives, urethane coatings, and elastomers; solvent; diluent for epoxy resins; synthetic fibers; organic synthesis.
Uses
ε-Caprolactone is widely used as a monomer in the manufacturing of highly specialized polymers. It is mainly utilized as a precursor to caprolactam. It finds an application in the synthesis of polyglecaprone, which is used as a suture material in surgery.
Uses
ε-caprolactone is popularly used in the preparation of poly caprolactone (PCL).
Definition
ChEBI: A epsilon-lactone that is oxepane substituted by an oxo group at position 2.
Synthesis Reference(s)
Journal of the American Chemical Society, 80, p. 4079, 1958 DOI: 10.1021/ja01548a063
The Journal of Organic Chemistry, 61, p. 4560, 1996 DOI: 10.1021/jo952237x
Tetrahedron Letters, 17, p. 2455, 1976 DOI: 10.1016/0040-4039(76)90018-6
General Description
ε-caprolactone is a cyclic ester. Ring opening polymerization of ε-caprolactone initiated by, tributylin n butoxide, ethyl magnesium bromide, or samarium acetate or heteropolyacid, leads to the formation of poly caprolactone (PCL).
Flammability and Explosibility
Not classified
ε-Caprolactone Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from ε-Caprolactone manufacturers
- Product
- 6-Hexanolactone 502-44-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99.91%
- Supply Ability
- 200000
- Release date
- 2024-04-25
- Product
- ε-Caprolactone 502-44-3
- Price
- US $35.00-1.40/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-03-27
- Product
- ε-Caprolactone 502-44-3
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 200000
- Release date
- 2024-03-21