ChemicalBook > CAS DataBase List > METHYL 2-CHLORO-3-NITROBENZOATE

METHYL 2-CHLORO-3-NITROBENZOATE

Product Name: METHYL 2-CHLORO-3-NITROBENZOATE
CAS No.: 53553-14-3
Chemical Name: METHYL 2-CHLORO-3-NITROBENZOATE
Synonyms: METHYL 2-CHLORO-3-NITROBENZOATE;Benzoic acid, 2-chloro-3-nitro-, methyl ester
CBNumber: CB1382976
Molecular Formula: C8H6ClNO4
Formula Weight: 215.59
MOL File: 53553-14-3.mol

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METHYL 2-CHLORO-3-NITROBENZOATE Property

Melting point:: 70 °C
Boiling point:: 319.5±22.0 °C(Predicted)
Density: 1.426±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
Appearance: Light yellow to yellow Solid

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TRC

Product number: B499288
Product name: methyl2-chloro-3-nitrobenzoate
Packaging: 100mg
Price: $90
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC55358
Product name: 2-Chloro-3-nitrobenzoic acid methyl ester
Packaging: 1g
Price: $95
Updated: 2021/12/16

AK Scientific

Product number: 7382AH
Product name: Methyl2-chloro-3-nitrobenzoate
Packaging: 250mg
Price: $99
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FC55358
Product name: 2-Chloro-3-nitrobenzoic acid methyl ester
Packaging: 2g
Price: $150
Updated: 2021/12/16

AK Scientific

Product number: 7382AH
Product name: Methyl2-chloro-3-nitrobenzoate
Packaging: 1g
Price: $163
Updated: 2021/12/16

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METHYL 2-CHLORO-3-NITROBENZOATE Chemical Properties,Usage,Production

Uses

Methyl 2-Chloro-3-nitrobenzoate is a useful research chemical used in the preparation of benzothiadiazole derivatives as agrochemical microbicides.

Synthesis

67-56-1

3970-35-2

53553-14-3

General procedure for the synthesis of methyl 2-chloro-3-nitrobenzoate from methanol and 2-chloro-3-nitrobenzoic acid: 1. to a solution of 2-chloro-3-nitrobenzoic acid (10.0 g, 49.6 mmol) in methanol (80 mL) was added concentrated sulfuric acid (2.0 mL). 2. The reaction mixture was stirred overnight under reflux conditions. 3. Upon completion of the reaction, the methanol was removed by vacuum concentration. 4. Water was added to the residue and extracted with ethyl acetate. 5. The organic phase was washed sequentially with water, saturated sodium bicarbonate solution and saturated brine. 6. 6. The organic phase was dried with magnesium sulfate. 7. The target compound, methyl 2-chloro-3-nitrobenzoate (10.6 g, 99% yield), was obtained as a white solid by vacuum concentration. 8. The product was characterized by 1H NMR (CDCl3) and HPLC: 1H NMR (CDCl3) δ (ppm): 7.95 (dd, 1H), 7.84 (dd, 1H), 7.48 (t, 1H), 3.98 (s, 3H). HPLC Rt = 11.88 min. 150 × 6.0 mm); mobile phase: 0-20 min, acetonitrile/water = 10/90 to 100/0 (gradient), 20-30 min, acetonitrile/water = 100/0 (isocratic); flow rate: 1 mL/min.

References

[1] Patent: WO2008/51533, 2008, A2. Location in patent: Page/Page column 95
[2] Pesticide Science, 1997, vol. 50, # 4, p. 275 - 282
[3] Patent: EP1982982, 2008, A1. Location in patent: Page/Page column 197
[4] Patent: EP2141150, 2010, A1. Location in patent: Page/Page column 109-110
[5] Patent: KR101511396, 2015, B1. Location in patent: Paragraph 2881-2885

METHYL 2-CHLORO-3-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 2-CHLORO-3-NITROBENZOATE manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: METHYL 2-CHLORO-3-NITROBENZOATE 53553-14-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 97.0%
Supply Ability: 10000KGS
Release date: 2025-05-12

53553-14-3, METHYL 2-CHLORO-3-NITROBENZOATERelated Search:

4-Nitrobenzoic acid 2-HYDROXY-CYCLOPENTANECARBOXYLIC ACID METHYL ESTER RARECHEM AL BF 0981 METHYL 2-CHLORO-3,5-DINITROBENZOATE ETHYL 2-CHLORO-3-NITROBENZOATE methyl 2,5-dichloro-3-nitrobenzoate RARECHEM AL BI 0981 METHYL 2-CHLORO-3-NITROBENZOATE

METHYL 2-CHLORO-3-NITROBENZOATE

Benzoic acid, 2-chloro-3-nitro-, methyl ester

53553-14-3

Aromatic Esters