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Naloxone hydrochloride

Product Name
Naloxone hydrochloride
CAS No.
357-08-4
Chemical Name
Naloxone hydrochloride
Synonyms
NALOXONE HCL;narcan;en1530;Nalone;nalonee;nih7890;EN-15304;Narcanti;Naloxone hydrochlori;NALOXONE HYDROCHLORIDE
CBNumber
CB1409273
Molecular Formula
C19H22ClNO4
Formula Weight
363.84
MOL File
357-08-4.mol
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Naloxone hydrochloride Property

Melting point:
200-2050C
RTECS 
QD2275000
storage temp. 
2-8°C
solubility 
ethanol: 3.3 mg/mL stable for several months refrigerated if protected from light.
form 
powder
color 
white to off-white
Water Solubility 
Soluble in water (73 mg/ml), ethanol (3.3 mg/ml), methanol (50 mg/ml) and dimethyl sulfoxide (73 mg/ml). Insoluble in ether
Stability:
Stable for 1 year from date of purchase as supplied. Solutions in DMSO or distilled water may be stored at -20°C for up to 2 months.
CAS DataBase Reference
357-08-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-26-36/37/39-36
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
BP548
Product name
Naloxone hydrochloride
Purity
British Pharmacopoeia (BP) Reference Standard
Packaging
100MG
Price
$257
Updated
2024/03/01
Alfa Aesar
Product number
J60013
Product name
Naloxone hydrochloride, 98%
Packaging
100mg
Price
$82
Updated
2023/06/20
Alfa Aesar
Product number
J60013
Product name
Naloxone hydrochloride, 98%
Packaging
1g
Price
$490
Updated
2023/06/20
Cayman Chemical
Product number
15594
Product name
Naloxone (hydrochloride)
Purity
≥95%
Packaging
50mg
Price
$81
Updated
2024/03/01
Cayman Chemical
Product number
15594
Product name
Naloxone (hydrochloride)
Purity
≥95%
Packaging
100mg
Price
$120
Updated
2024/03/01
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Naloxone hydrochloride Chemical Properties,Usage,Production

Description

Naloxone (hydrochloride) (CRM) (Item No. ISO60191) is a certified reference material categorized as an opioid antagonist. Formulations containing naloxone have been used as antidotes for opioid overdose and the prevention of overdose. They have also been used in combination with buprenorphine (Item Nos. ISO60178 | 14025) in the treatment of opiate addiction and in pain management. This product is intended for research and forensic applications.

Chemical Properties

Crystalline Solid

Originator

Narcan,Du Pont,US,1971

Uses

Opioate antidote;

Uses

A nonspecific opiate receptor antagonist that displays anitnociceptive effects

Uses

Naloxone Hydrochloride is a specific opioid antagonist. Narcotic antagonist.

Definition

ChEBI: A hydrochloride resulting from the formal reaction of equimolar amounts of naloxone and hydrogen chloride. A specific opioid antagonist, it is used to reverse the effects of opioids, both following their use of opioids during surgery and in cases of known r suspected opioid overdose.

Manufacturing Process

10 grams of 14-hydroxydihydromorphinone (oxymorphone) was converted into its diacetate by warming it on the steam bath with 80 cc of acetic anhydride for about 2 hours. The acetic anhydride was removed on the water bath under a vacuum of about 30 mm absolute pressure. The melting point of the residue was 220°C. The residue was taken up in 100 cc of chloroform. An equal amount by weight of cyanogen bromide was added and the mixture was refluxed at about 60°C for about 5 hours. After refluxing, the mixture was washed with 100 cc of a 5% aqueous hydrochloric acid solution, dried over sodium sulfate and the chloroform removed by evaporation under a vacuum of about 30 mm. The residue had a melting point of 240°C.
The residue was then heated at about 90°C for 16 hours on a steam bath with 300 cc of 20% aqueous hydrochloric acid solution, and treated with a small amount, e.g., 1 gram of charcoal. The hydrochloric acid was then removed under a vacuum of 15 mm, the residue dissolved in 30 cc of water and precipitated by the addition of 2.4 cc of concentrated aqueous ammonia. The precipitate was filtered off and dried. It consists of 14- hydroxydihydronormorphinone. It is soluble in ethanol.
The 14-hydroxydihydronormorphinone was suspended in 200 cc of pure ethyl alcohol, half its weight of sodium bicarbonate and half its weight of allyl bromide added and the resulting mixture was refluxed at about 75°C for 48 hours. The solution was cooled, e.g., to 10°C and filtered and the alcohol removed under a vacuum of 30 mm. The residue was dissolved in chloroform and filtered. The chloroform was removed under a vacuum of 30 mm and the residue was crystallized from ethylacetate. The crystallized product, N-allyl- 1,4-hydroxydihydronormorphinone, has a melting point of 184°C, is soluble in chloroform and insoluble in petroleum ether. The yield amounts to 20% based on the weight of the reacted 14-hydroxydihydromorphinone.

brand name

Narcan (Bristol-Myers Squibb); Narcan (Endo).

Therapeutic Function

Narcotic antagonist

Biological Activity

Opioid antagonist.

Veterinary Drugs and Treatments

Naloxone is used in veterinary medicine almost exclusively for its opiate reversal effects, but the drug is being investigated for treating other conditions (e.g., septic, hypovolemic or cardiogenic shock). Naloxone may also be employed as a test drug to see if endogenous opiate blockade will result in diminished tail chasing or other self-mutilating behaviors. It, potentially, could be useful for treating overdoses of clonidine or the CNS effects of benzodiazepines (ivermectin?), but more research is necessary before recommending its use.

Metabolism

Naloxone hydrochloride is rapidly metabolised in the liver, mainly by conjugation with glucuronic acid to naloxone-3-glucuronide, which is excreted in the urine

storage

Room temperature

References

1) Le Bourdonnec?et al., (2008),?Novel trans-3,4-dimethyl-4-(3-hydroxyphenyl)piperidines as mu opioid receptor antagonists with improved opioid receptor selectivity profiles: Bioorg. Med. Chem. Lett..?18?2006 2) Boyer?et al.?(2012),?Management of opioid analgesic overdose; New Engl. J. Med.?367?146 3) Wang?et al.?(2017),?Opioids and opioid receptors orchestrate wound repair;?Transl. Res.?185?13 4) Wright and Rodgers (2013),?Low dose naloxone attenuates the pruritic but not anorectic response to rimonabant in male rats; Psychopharmacology (Berl.)?226?415

Naloxone hydrochloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Naloxone hydrochloride Suppliers

Shanghai Boyle Chemical Co., Ltd.
Tel
Fax
86-21-57758967
Email
sales@boylechem.com
Country
China
ProdList
2922
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Chembest Research Laboratories Limited
Tel
+86-21-20908456
Fax
021-58180499
Email
sales@BioChemBest.com
Country
China
ProdList
6005
Advantage
61
Ascent Scientific
Tel
4401179829988
Fax
4402030 700 369
Email
customerservice@ascentscientific.co.uk
Country
United Kingdom
ProdList
279
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9513
Advantage
66
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32321
Advantage
50
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8836
Advantage
52
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View Lastest Price from Naloxone hydrochloride manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Naloxone hydrochloride 357-08-4
Price
US $1.10/g
Min. Order
1g
Purity
99.0% min
Supply Ability
100 tons min
Release date
2021-05-25
Nantong Guangyuan Chemicl Co,Ltd
Product
Naloxone hydrochloride 357-08-4
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2023-11-02
Wuhan Han Sheng New Material Technology Co.,Ltd
Product
Naloxone hydrochloride 357-08-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99.34%
Supply Ability
20tons
Release date
2023-04-20

357-08-4, Naloxone hydrochloride Related Search:


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  • Naloxone (hydrochloride) (CRM)
  • Naloxone hydrochloride USP/EP/BP
  • Naloxone hydrochlori
  • Naloxone Hydrochloride hydrate
  • Naloxone hydrochloride in methanol
  • 357-08-4
  • C19H21NO4HClH2O
  • C19H21NO4HCl
  • C19H22ClNO4
  • C19H21NO4HClC19H22ClNO4
  • API
  • Chiral Reagents
  • Drug Analogues
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Opioid receptor and opioid-like receptor
  • Opioids