ChemicalBook > CAS DataBase List > (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE

(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE

Product Name
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
CAS No.
34257-63-1
Chemical Name
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
Synonyms
MurahashiReagent;murahashi's reagent;(N-Methylphenylamino)T;(N-METHYLPHENYLAMINO)TRIPHENYL- &;(N-METHYL-N-PHENYLAMINO)-TRIPHENYLPHOSPH;N-METHYLANILINOTRIPHENYLPHOSPHONIUM IODIDE;(Methyl(phenyl)amino)triphenylphosphonium iodide;(N-Methylphenylamino)triphenylphosphonium iodide;(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE;Murahashi reagent, N-Methylanilinotriphenylphosphonium iodide
CBNumber
CB1418244
Molecular Formula
C25H23INP
Formula Weight
495.34
MOL File
34257-63-1.mol
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(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Property

Melting point:
238-239°C
solubility 
sol DMF, EtOAc. Behaves as a Wittig-type reagent in terms of solubility.
form 
powder to crystal
color 
White to Yellow to Orange
CAS DataBase Reference
34257-63-1(CAS DataBase Reference)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36-24/25-22
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M1151
Product name
(N-Methyl-N-phenylamino)triphenylphosphonium Iodide
Packaging
10g
Price
$222
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0008339
Product name
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
Purity
95.00%
Packaging
25G
Price
$598
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0008339
Product name
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
Purity
95.00%
Packaging
125G
Price
$1117.5
Updated
2021/12/16
AK Scientific
Product number
4115AL
Product name
(N-Methyl-N-phenylamino)triphenylphosphonium Iodide
Packaging
10g
Price
$371
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0008339
Product name
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
Purity
95.00%
Packaging
5G
Price
$457.6
Updated
2021/12/16
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(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Chemical Properties,Usage,Production

Uses

(N-Methyl-N-phenylamino)triphenylphosphonium Iodide is used to synthesis of amines from alcohols; synthesis of unsymmetrical sulfides; synthesis of alkenes from allyl alcohols; synthesis of 1,3-dienes.

Preparation

Preparative Method of (N-Methyl-N-phenylamino)triphenylphosphonium Iodide: phenyliminotriphenylphosphorane is reacted with excess Iodomethane at reflux for 2 h. Removal of MeI followed by recrystallization gives a quantitative yield.[1]

storage

(N-Methyl-N-phenylamino)triphenylphosphonium Iodide stores in sealed bottle on bench. Do not breathe dust, fumes, or vapor. Avoid contact with skin and eyes. Use in a fume hood.

References

1. Tanigawa, Y.; Kanamaru, H.; Sonoda, A.; Murahashi, S-I. JACS 1977, 99, 2361.

(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Suppliers

Americas 1 China 20 Europe 1 Germany 3 India 2 Japan 1 Switzerland 1 United Kingdom 6 United States 6 Global 41
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
(N-Methyl-N-phenylaMino)triphenylphosphoniuM Iodide 34257-63-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-08-27

34257-63-1, (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDERelated Search:

Benzotriazole-1-yl-oxytripyrrolidinophosphonium hexafluorophosphate PHOSPHONIUM IODIDE TRIPHENYLPHOSPHINE HYDROIODIDE (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Diphenyl(2,4,6-trimethylbenzoyl)phosphine oxide

  • N-METHYLANILINOTRIPHENYLPHOSPHONIUM IODIDE
  • (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
  • (N-METHYLPHENYLAMINO)TRIPHENYL- &
  • Phosphorus(1+), (N-methylbenzenaminato)triphenyl-, iodide, (T-4)-
  • murahashi's reagent
  • (N-Methylphenylamino)T
  • (N-METHYL-N-PHENYLAMINO)-TRIPHENYLPHOSPH
  • (N-Methylphenylamino)triphenylphosphonium iodide
  • Murahashi reagent, N-Methylanilinotriphenylphosphonium iodide
  • MurahashiReagent
  • (Methyl(phenyl)amino)triphenylphosphonium iodide
  • 34257-63-1
  • C25H23INP
  • C25H23NPI
  • Phosphonium Compounds
  • Phosphonium Compounds