(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
- Product Name
- (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
- CAS No.
- 34257-63-1
- Chemical Name
- (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
- Synonyms
- MurahashiReagent;murahashi's reagent;(N-Methylphenylamino)T;(N-METHYLPHENYLAMINO)TRIPHENYL- &;(N-METHYL-N-PHENYLAMINO)-TRIPHENYLPHOSPH;N-METHYLANILINOTRIPHENYLPHOSPHONIUM IODIDE;(Methyl(phenyl)amino)triphenylphosphonium iodide;(N-Methylphenylamino)triphenylphosphonium iodide;(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE;Murahashi reagent, N-Methylanilinotriphenylphosphonium iodide
- CBNumber
- CB1418244
- Molecular Formula
- C25H23INP
- Formula Weight
- 495.34
- MOL File
- 34257-63-1.mol
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Property
- Melting point:
- 238-239°C
- solubility
- sol DMF, EtOAc. Behaves as a Wittig-type reagent in terms of solubility.
- form
- powder to crystal
- color
- White to Yellow to Orange
- CAS DataBase Reference
- 34257-63-1(CAS DataBase Reference)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25-22
- HS Code
- 2931.90.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- M1151
- Product name
- (N-Methyl-N-phenylamino)triphenylphosphonium Iodide
- Packaging
- 10g
- Price
- $200
- Updated
- 2025/07/31
- Product number
- ING0008339
- Product name
- (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
- Purity
- 95.00%
- Packaging
- 25G
- Price
- $598
- Updated
- 2021/12/16
- Product number
- ING0008339
- Product name
- (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
- Purity
- 95.00%
- Packaging
- 125G
- Price
- $1117.5
- Updated
- 2021/12/16
- Product number
- 4115AL
- Product name
- (N-Methyl-N-phenylamino)triphenylphosphonium Iodide
- Packaging
- 10g
- Price
- $371
- Updated
- 2021/12/16
- Product number
- ING0008339
- Product name
- (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $457.6
- Updated
- 2021/12/16
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Chemical Properties,Usage,Production
Uses
(N-Methyl-N-phenylamino)triphenylphosphonium Iodide is used to synthesis of amines from alcohols; synthesis of unsymmetrical sulfides; synthesis of alkenes from allyl alcohols; synthesis of 1,3-dienes.
Preparation
Preparative Method of (N-Methyl-N-phenylamino)triphenylphosphonium Iodide: phenyliminotriphenylphosphorane is reacted with excess Iodomethane at reflux for 2 h. Removal of MeI followed by recrystallization gives a quantitative yield.[1]
storage
(N-Methyl-N-phenylamino)triphenylphosphonium Iodide stores in sealed bottle on bench. Do not breathe dust, fumes, or vapor. Avoid contact with skin and eyes. Use in a fume hood.
References
1. Tanigawa, Y.; Kanamaru, H.; Sonoda, A.; Murahashi, S-I. JACS 1977, 99, 2361.
(N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (N-METHYL-N-PHENYLAMINO)TRIPHENYLPHOSPHONIUM IODIDE manufacturers
- Product
- (N-Methyl-N-phenylaMino)triphenylphosphoniuM Iodide 34257-63-1
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-08-27