N,N-Diethylhydroxylamine Property

Melting point:

−26-−25 °C(lit.)

Boiling point:

125-130 °C

Density 

0.902 g/mL at 25 °C

vapor density 

3.07 (vs air)

vapor pressure 

4 mm Hg ( 0 °C)

refractive index 

n20/D 1.420(lit.)

Flash point:

115 °F

storage temp. 

Store below +30°C.

form 

Liquid

pka

14.19±0.69(Predicted)

color 

Clear

Specific Gravity

0.867

explosive limit

1.9-10%(V)

Water Solubility 

soluble

Sensitive 

Hygroscopic

BRN 

1731349

Exposure limits

ACGIH: TWA 2 ppm

Stability:

Stable. Hygroscopic. Flammable. Incompatible with strong oxidizing agents, strong acids.

InChIKey

FVCOIAYSJZGECG-UHFFFAOYSA-N

LogP

0.5 at 23℃

CAS DataBase Reference

3710-84-7(CAS DataBase Reference)

NIST Chemistry Reference

Ethanamine, N-ethyl-N-hydroxy-(3710-84-7)

EPA Substance Registry System

Diethylhydroxylamine (3710-84-7)

Safety

Hazard Codes 

Xn

Risk Statements 

10-21-38-40-36/37/38-20/21-53-36/38

Safety Statements 

36/37-45-36/37/39-26-16

RIDADR 

UN 1993 3/PG 3

WGK Germany 

1

RTECS 

NC3500000

F 

3

TSCA 

Yes

HazardClass 

3

PackingGroup 

III

HS Code 

29280090

Hazardous Substances Data

3710-84-7(Hazardous Substances Data)

Toxicity

LD50 orally in Rabbit: 2190 mg/kg LD50 dermal Rabbit 1300 mg/kg

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

N,N-Diethylhydroxylamine Chemical Properties,Usage,Production

Description

N,N-Diethylhydroxylamine is a colorless and transparent liquid with a boiling point of 125-130 °C and an ammonia odor. It is easily soluble in water, soluble in ethanol, ether, chloroform and benzene.

Chemical Properties

liquid

Uses

N,N-Diethylhydroxylamine has the following various uses:
1.As a vinyl monomer, used in efficient inhibitor agent of conjugate olefins.
2.In liquid or gas phase, if end gather seed is existed,it can be used as inhibitors of end gather.
3.It's a excellent end agent in process of Emulsion-polymerized styrene butadiene rubber.
4.It's a antioxidants of the unsaturated oil and resin.
5.In the environmental protection,it’s good photochemical smoke inhibitors.
6.It's used as corrosion inhibitors in the equipment of the boiler feed water and steam heat exchange.
7.It's used as antioxidant in photography screens potions. 

Uses

N,N-Diethylhydroxylamine may be employed as a ligand in the preparation of unsymmetric mixed ligand oxadiazoline and/or imine platinum complexes. It may be used in the synthesis of organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc.

Uses

Diethylhydroxylamine has been suggested as a stabilizer for color forma­tion for monoalkylphenols and phenolic antioxidants. It has also been reported to stabilize emulsions used in the latex industry and for Spandex rubber, as well as a reducing agent for quinones and a monomer stabilizer or inhibitor.

General Description

The product is 85wt.% solution of N,N-diethylhydroxylamine. The reaction of N,N-diethylhydroxylamine with tert-butylhydroperoxide has been studied. It participates in the preparation of symmetrical and an isomeric mixture of unsymmetrical phthalocyanines. It undergoes degradation on exposure to radiation and affords light hydrocarbons. Qualitative and quantitative analyses of the produced hydrocarbons have been reported. It also participates in the conversion of quinones and quinonemonosulfonimide to the corresponding hydroquinones and sulfonylaminophenols, respectively.

Health effects

The effects of diethylhydroxylamine (DEHA), a potent free-radical scavenger, on lipid peroxidation of rat liver microsomes were investigated in vitro. DEHA strongly inhibited ascorbate-dependent nonenzymatic microsomal lipid peroxidation. It also completely inhibited nonenzymatic lipid peroxidation of heat-denatured microsomes, indicating that inhibition is protein-independent. DEHA only moderately inhibited NADPH-dependent enzymatic microsomal lipid peroxidation. 

reaction suitability

reagent type: reductant

Safety Profile

Poison by skin contact. Moderately toxic by ingestion and intraperitoneal routes. Experimental reproductive effects. Human mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also AMINES.