METHYL 1-BROMOCYCLOHEXANECARBOXYLATE
- Product Name
- METHYL 1-BROMOCYCLOHEXANECARBOXYLATE
- CAS No.
- 3196-23-4
- Chemical Name
- METHYL 1-BROMOCYCLOHEXANECARBOXYLATE
- Synonyms
- LABOTEST-BB LT00160081;METHYL 1-BROMOCYCLOHEXANECARBOXYLATE;methyl 1-bromocyclohexane-1-carboxylate;Methyl 1-broMocyclohexanecarboxylate 97%;METHYL 1-BROMOCYCLOHEXANECARBOXYLATE, 97 %;1-Bromocyclohexanecarboxylic acid methyl ester;Cyclohexanecarboxylic acid, 1-bromo-, methyl ester
- CBNumber
- CB1457931
- Molecular Formula
- C8H13BrO2
- Formula Weight
- 221.09
- MOL File
- 3196-23-4.mol
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE Property
- Boiling point:
- 115-116 °C/19 mmHg (lit.)
- Density
- 1.39 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.493(lit.)
- Flash point:
- 222 °F
- storage temp.
- 2-8°C
Safety
- Hazard Codes
- C
- Risk Statements
- 34-36/37
- Safety Statements
- 26-27-28-36/37/39-45
- RIDADR
- UN 3265 8/PG 2
- WGK Germany
- 3
- HazardClass
- 8
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 361976
- Product name
- Methyl 1-bromocyclohexanecarboxylate
- Purity
- 97%
- Packaging
- 25g
- Price
- $249
- Updated
- 2023/06/20
- Product number
- M296573
- Product name
- Methyl 1-bromocyclohexanecarboxylate
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 3511AB
- Product name
- Methyl 1-bromocyclohexanecarboxylate
- Packaging
- 1g
- Price
- $77
- Updated
- 2021/12/16
- Product number
- HCH0067456
- Product name
- METHYL 1-BROMOCYCLOHEXANECARBOXYLATE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $273
- Updated
- 2021/12/16
- Product number
- HCH0067456
- Product name
- METHYL 1-BROMOCYCLOHEXANECARBOXYLATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $832.43
- Updated
- 2021/12/16
METHYL 1-BROMOCYCLOHEXANECARBOXYLATE Chemical Properties,Usage,Production
Uses
Methyl 1-bromocyclohexanecarboxylate may be used in the improved method of preparation of methyl 3-oxo-1-cyclohexene-1-carboxylate. It may be used in the Reformatsky synthesis of 16-aryl-15-oxadispiro[5.1.5.3]hexadecane-7,14-diones.
General Description
Methyl 1-bromocyclohexanecarboxylate reacts with zinc and substituted chalcones to yield the corresponding spiro-3,4-dihydropyran-2-one derivatives, 3-aryl-5-aryl-2-oxaspiro[5.5]undec-3-en-1-ones. Reformatsky reaction of methyl 1-bromocyclohexanecarboxylate with 2-aryl-2-oxoacetaldehyde is reported. Methyl 1-bromocyclohexanecarboxylate reacts with zinc and amides or methylamides of 3-aryl-2-cyanopropenoic acids to yield 5-aryl-1,3-dioxo-2-azaspiro[5.5]undecane-4-carbonitriles or 5-aryl-2-methyl-1,3-dioxo-2-azaspiro[5.5]undecane-4-carbonitriles.