ChemicalBook > CAS DataBase List > BISMUTH OXYCHLORIDE

BISMUTH OXYCHLORIDE

Product Name
BISMUTH OXYCHLORIDE
CAS No.
7787-59-9
Chemical Name
BISMUTH OXYCHLORIDE
Synonyms
biju;mearlite;CI 77163;BIRON MTU;PEARL WHITE;BIRON LF-2000;BISMUTHYL CHLORIDE;Chlorobismuth oxide;chlorooxo-bismuthin;BISMUTH OXYCHLORIDE
CBNumber
CB1489282
Molecular Formula
BiClO
Formula Weight
260.43
MOL File
7787-59-9.mol
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BISMUTH OXYCHLORIDE Property

Melting point:
melts at low red heat [MER06]
Density 
7.72 g/mL at 25 °C (lit.)
refractive index 
2.15
solubility 
H2O: insoluble(lit.)
form 
Powder
color 
Very pale brown
Specific Gravity
7.72
Odor
at 100.00?%. odorless
Water Solubility 
Soluble in HCl, HNO3. Insoluble in water, alcohol.
Merck 
14,1263
Solubility Product Constant (Ksp)
pKsp: 30.75
InChIKey
GLQBXSIPUULYOG-UHFFFAOYSA-M
CAS DataBase Reference
7787-59-9(CAS DataBase Reference)
EPA Substance Registry System
Bismuthine, chlorooxo- (7787-59-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
EB2700000
TSCA 
Yes
HS Code 
28274990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
307610
Product name
Bismuth(III) oxychloride
Purity
98%
Packaging
50g
Price
$39
Updated
2024/03/01
Sigma-Aldrich
Product number
307610
Product name
Bismuth(III) oxychloride
Purity
98%
Packaging
250g
Price
$229
Updated
2024/03/01
Alfa Aesar
Product number
011843
Product name
Bismuth(III) chloride oxide, 99.999% (metals basis)
Packaging
10g
Price
$69.65
Updated
2024/03/01
Alfa Aesar
Product number
011843
Product name
Bismuth(III) chloride oxide, 99.999% (metals basis)
Packaging
50g
Price
$280
Updated
2023/06/20
Alfa Aesar
Product number
040396
Product name
Bismuth(III) chloride oxide, 98%
Packaging
50g
Price
$56.1
Updated
2024/03/01
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BISMUTH OXYCHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Bismuth oxychloride is a white Lustorus powder, It is an inorganic white pigment commonly used in foundations, blushes and other color cosmetics. Bismuth oxychloride usually comes in two forms: diamond and pearl finishes. The diamond is shimmery and the pearl is more matte.
Bismuth is the least toxic of its periodic table neighbors like lead, tin, antimony and polonium. Bismuth in itself is not safe for use in cosmetics, and must be refined and combined with other elements to produce bismuth oxychloride.

Bismuth occurs naturally, but in very small amounts. Most of the bismuth produced in the USA is as a by-product from refining lead, tin, copper, silver and gold ores.
Once the bismuth has been harvested, it is further refined through several processes to remove dangerous elements like lead. Then it is chlorinated, which gives us bismuth chloride (BiCl3). It still poses a severe risk at this point, smelling of hydrochloric acid. When bismuth chloride is combined with water, it starts to decompose and part of the chlorine is replaced by oxygen from the water. This process is called hydrolysis. The remaining compound is bismuth, chlorine and oxygen = Bismuth oxychloride.

Physical properties

White powder or tetragonal crystals; density 7.72 g/cm3; practically insoluble in water, alcohol and acetone; soluble in hydrochloric and nitric acids (with decomposition); Ksp 7.0 x 10-9.

Uses

It is used as skin protective's, thickeners, and absorbent agents. It act as a coloring agents in cosmetics.

Uses

In face powders; as pigment; manufacture of artificial pearls, dry-cell cathodes.

Uses

bismuth oxychloride is an inorganic color additive. It is used mostly in makeup manufacturing and rarely in skin care formulations. It may also be used for pearlization in cosmetics.

Preparation

Bismuth oxychloride is made by treating bismuth chloride with water and then drying the white precipitate so formed to expel a molecule of water:
BiCl3 + 2H2O → Bi(OH)2Cl + 2HCl

Bi(OH)2Cl BiOCl + H2O
Also, the compound is prepared by treating a dilute nitric acid solution of bismuth nitrate with sodium chloride.

General Description

Odorless white solid. Sinks in water.

Reactivity Profile

BISMUTH OXYCHLORIDE emits toxic fumes of chloride ion and bismuth when heated to decomposition [USCG, 1999].

Health Hazard

Contact with dust causes mild eye irritation and can cause skin rashes.

Flammability and Explosibility

Not classified

BISMUTH OXYCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from BISMUTH OXYCHLORIDE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Bismuth subchloride 7787-59-9
Price
US $85.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-21
Shandong Deshang Chemical Co., Ltd.
Product
BISMUTH OXYCHLORIDE 7787-59-9
Price
US $15.50-10.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-07-23
Hebei Weibang Biotechnology Co., Ltd
Product
BISMUTH OXYCHLORIDE 7787-59-9
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24

7787-59-9, BISMUTH OXYCHLORIDERelated Search:


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  • bismuth(III) oxide chloride
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  • BISMUTH (LLL) OXYCHLORIDE
  • Bismuth(III) chloride oxide, 99.999% (metals basis)
  • Bismuth(III) chloride oxide, Bismuthyl(III) chloride
  • Bismuth oxidechloride
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  • BisMuth oxychloride, (trace Metal basis)
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  • chlorooxo-bismuthin
  • chlorooxo-Bismuthine
  • mearlite
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  • BISMUTH OXYCHLORIDE Extra Pure
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  • 7787-59-9
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  • CO3BiO
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  • Inorganics