BISMUTH OXYCHLORIDE

Product Name: BISMUTH OXYCHLORIDE
CAS No.: 7787-59-9
Chemical Name: BISMUTH OXYCHLORIDE
Synonyms: biju;mearlite;CI 77163;BIRON MTU;PEARL WHITE;BIRON LF-2000;BISMUTHYL CHLORIDE;Chlorobismuth oxide;chlorooxo-bismuthin;BISMUTH OXYCHLORIDE
CBNumber: CB1489282
Molecular Formula: BiClO
Formula Weight: 260.43
MOL File: 7787-59-9.mol

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BISMUTH OXYCHLORIDE Property

Melting point:: melts at low red heat [MER06]
Density: 7.72 g/mL at 25 °C (lit.)
refractive index: 2.15
solubility: H2O: insoluble(lit.)
form: Powder
color: Very pale brown
Specific Gravity: 7.72
Odor: at 100.00?%. odorless
Water Solubility: Soluble in HCl, HNO3. Insoluble in water, alcohol.
Merck: 14,1263
Solubility Product Constant (Ksp): pKsp: 30.75
InChIKey: GLQBXSIPUULYOG-UHFFFAOYSA-M
CAS DataBase Reference: 7787-59-9(CAS DataBase Reference)
EPA Substance Registry System: Bismuthine, chlorooxo- (7787-59-9)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 2
RTECS: EB2700000
TSCA: Yes
HS Code: 28274990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 307610
Product name: Bismuth(III) oxychloride
Purity: 98%
Packaging: 50g
Price: $39
Updated: 2024/03/01

Sigma-Aldrich

Product number: 307610
Product name: Bismuth(III) oxychloride
Purity: 98%
Packaging: 250g
Price: $229
Updated: 2024/03/01

Alfa Aesar

Product number: 011843
Product name: Bismuth(III) chloride oxide, 99.999% (metals basis)
Packaging: 10g
Price: $69.65
Updated: 2024/03/01

Alfa Aesar

Product number: 011843
Product name: Bismuth(III) chloride oxide, 99.999% (metals basis)
Packaging: 50g
Price: $280
Updated: 2023/06/20

Alfa Aesar

Product number: 040396
Product name: Bismuth(III) chloride oxide, 98%
Packaging: 50g
Price: $56.1
Updated: 2024/03/01

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BISMUTH OXYCHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Bismuth oxychloride is a white Lustorus powder, It is an inorganic white pigment commonly used in foundations, blushes and other color cosmetics. Bismuth oxychloride usually comes in two forms: diamond and pearl finishes. The diamond is shimmery and the pearl is more matte.
Bismuth is the least toxic of its periodic table neighbors like lead, tin, antimony and polonium. Bismuth in itself is not safe for use in cosmetics, and must be refined and combined with other elements to produce bismuth oxychloride.

Bismuth occurs naturally, but in very small amounts. Most of the bismuth produced in the USA is as a by-product from refining lead, tin, copper, silver and gold ores.
Once the bismuth has been harvested, it is further refined through several processes to remove dangerous elements like lead. Then it is chlorinated, which gives us bismuth chloride (BiCl3). It still poses a severe risk at this point, smelling of hydrochloric acid. When bismuth chloride is combined with water, it starts to decompose and part of the chlorine is replaced by oxygen from the water. This process is called hydrolysis. The remaining compound is bismuth, chlorine and oxygen = Bismuth oxychloride.

Physical properties

White powder or tetragonal crystals; density 7.72 g/cm³; practically insoluble in water, alcohol and acetone; soluble in hydrochloric and nitric acids (with decomposition); Ksp 7.0 x 10-⁹.

Uses

It is used as skin protective's, thickeners, and absorbent agents. It act as a coloring agents in cosmetics.

Uses

In face powders; as pigment; manufacture of artificial pearls, dry-cell cathodes.

Uses

bismuth oxychloride is an inorganic color additive. It is used mostly in makeup manufacturing and rarely in skin care formulations. It may also be used for pearlization in cosmetics.

Preparation

Bismuth oxychloride is made by treating bismuth chloride with water and then drying the white precipitate so formed to expel a molecule of water:
BiCl₃ + 2H₂O → Bi(OH)₂Cl + 2HCl

Bi(OH)₂Cl → BiOCl + H₂O
Also, the compound is prepared by treating a dilute nitric acid solution of bismuth nitrate with sodium chloride.

General Description

Odorless white solid. Sinks in water.

Reactivity Profile

BISMUTH OXYCHLORIDE emits toxic fumes of chloride ion and bismuth when heated to decomposition [USCG, 1999].

Health Hazard

Contact with dust causes mild eye irritation and can cause skin rashes.

Flammability and Explosibility

Not classified

BISMUTH OXYCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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BISMUTH OXYCHLORIDE Suppliers

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View Lastest Price from BISMUTH OXYCHLORIDE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Bismuth subchloride 7787-59-9
Price: US $85.00-35.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-21

Shandong Deshang Chemical Co., Ltd.

Product: BISMUTH OXYCHLORIDE 7787-59-9
Price: US $15.50-10.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 tons
Release date: 2024-07-23

Hebei Weibang Biotechnology Co., Ltd

Product: BISMUTH OXYCHLORIDE 7787-59-9
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

7787-59-9, BISMUTH OXYCHLORIDERelated Search:

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BISMUTHYL CHLORIDE, 99.99%BISMUTHYL CHLORIDE, 99.99%BISMUTHYL CHLORIDE, 99.99%

bismuth(III) oxide chloride

PEARL WHITE

biju

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Chlorobismuth oxide

Bismuth oxychloride, (trace metal basis), 99.99%

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BisMuth oxychloride, 99.99%, (trace Metal basis)

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Bismuth(III) oxychloride 98%

chlorooxo-bismuthin

chlorooxo-Bismuthine

mearlite

BIRON LF-2000

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BISMUTHYL CHLORIDE

BISMUTH(III) OXYCHLORIDE

BISMUTH(III) CHLORIDE OXIDE

BISMUTH CHLORIDE, BASIC

BISMUTH CHLORIDE OXIDE

CI 77163

BISMUTHYL(III) CHLORIDE

BISMUTH(III) OXYCHLORIDE 99.99+%

Bismuth(III) chloride oxide, 99.99%

Bismuth(III) chloride oxide powder, 99%

Bismuth(III)chlorideoxide,99.95%(metalsbasis)

BISMUTHYL CHLORIDE, 99.99%

Bismuthine, chlorooxo-

BISMUTH OXYCHLORIDE Extra Pure

Bismuth Oxychloride 98% Extrapure

7787-59-9

7787-59-8

CO3BiO

BiC1O

BiOCl

BiClHO

Inorganics