Glycyrrhizic acid ammonium salt

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Glycyrrhizic acid ammonium salt

Product Name: Glycyrrhizic acid ammonium salt
CAS No.: 53956-04-0
Chemical Name: Glycyrrhizic acid ammonium salt
Synonyms: MONOAMMONIUM GLYCYRRHIZINATE;Magnasweet;monoammoniumglycyrrhizate;glycyrrhizin monoammonium salt;Monoammonium Glycyrrhizinate S;GLYCYRRHIZINATE MONOAMMONIUM SALT;GLYCYRRHIZIC ACID MONOAMMONIUM SALT;GLYCAMIL;icorice);t from g
CBNumber: CB1492372
Molecular Formula: C42H65NO16
Formula Weight: 839.97
MOL File: 53956-04-0.mol

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Glycyrrhizic acid ammonium salt Property

Melting point:: >200°C (dec.)
Boiling point:: 768.56°C (rough estimate)
Density: 1.1846 (rough estimate)
FEMA: 2528 | GLYCYRRHIZIN, AMMONIATED (GLYCYRRHIZA SPP.)
refractive index: 49 ° (C=1.5, EtOH)
storage temp.: 2-8°C
solubility: Slightly soluble in water, very slightly soluble in anhydrous ethanol, practically insoluble in acetone. It dissolves in dilute solutions of acids and of alkali hydroxides.
form: Powder or Crystals
color: Yellow to yellow-green
Odor: bland
optical activity: [α]20/D +48±4°, c = 1% in ethanol: water (1:1)
BRN: 3897076
Stability:: Hygroscopic
InChIKey: ILRKKHJEINIICQ-YDYGGSECSA-N
LogP: -0.9
CAS DataBase Reference: 53956-04-0
EPA Substance Registry System: .alpha.-D-Glucopyranosiduronic acid, (3.beta.,20.beta.)-20-carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-.beta.-D-glucopyranuronosyl-, monoammonium salt (53956-04-0)

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Safety

RIDADR: UN 3077 9 / PGIII
WGK Germany: 2
RTECS: LZ6500000
F: 3-10
HS Code: 29389090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: PHL82467
Product name: Glycyrrhizin ammonium salt
Purity: phyproof? Reference Substance
Packaging: 100MG
Price: $262
Updated: 2024/03/01

Sigma-Aldrich

Product number: 1029929
Product name: Ammonium glycyrrhizate
Purity: United States Pharmacopeia (USP) Reference Standard
Packaging: 100mg
Price: $474
Updated: 2024/03/01

Sigma-Aldrich

Product number: 356780
Product name: Glycyrrhizin, Ammonium Salt - CAS 53956-04-0 - Calbiochem
Packaging: 5G
Price: $111
Updated: 2022/05/15

TCI Chemical

Product number: G0151
Product name: Monoammonium Glycyrrhizinate Hydrate
Purity: >75.0%(HPLC)
Packaging: 1g
Price: $20
Updated: 2024/03/01

TCI Chemical

Product number: G0151
Product name: Monoammonium Glycyrrhizinate Hydrate
Purity: >75.0%(HPLC)
Packaging: 25g
Price: $65
Updated: 2024/03/01

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Glycyrrhizic acid ammonium salt Chemical Properties,Usage,Production

Description

§ 184.1408(a)(1) Licorice (glycyrrhiza) root is the dried and ground rhizome and root portions of Glycyrrhiza glabra or other species of glycyrrhiza. Licorice extract is that portion of the licorice root that is, after maceration, extracted by boiling water. The extract can be further purified by filtration and by treatment with acids and ethyl alcohol. Licorice extract is sold as a liquid paste ("block"), or spraydried powder. (2) Ammoniated glycyrrhizin is prepared from the water extract of licorice root by acid precipitation followed by neutralization with dilute ammonia. Monoammonium glycyrrhizinate (C42H61016NH45H2O ) is prepared from ammoniated glycyrrhizin by solvent extraction and separation techniques.

Chemical Properties

Licorice (glycyrrhiza) root is the dried and ground rhizome and root portions of Glycyrrhiza glabra or other species of glycyrrhiza Ammoniated glycyrrhizin is prepared from the water extract of licorice root by acid precipitation, followed by neutral- ization with dilute ammonia Monoammonium glycyrrhizinate (C42H62O16NH45H2O) is prepared from ammoniated glycyrrhizin by solvent extraction and separation techniques.

Chemical Properties

white to slightly yellow powder

Uses

anti-cancer agent

Uses

pharmaceutical excipient, GRAS, sweetener

Uses

Glycyrrhizic acid ammonium salt is a flavoring and sweetening agent obtained from licorice flavonoids. It has a slight licorice flavor and an intense and rounded sweetness. It is soluble in water, glycerin, and propylene glycol and has good thermal stability but can degrade under prolonged heating. It is stable over a ph of 3.5–9 but could precipitate below ph of 3.5. It can be used in beverages, desserts, confectionary products, soups, and dressings.

Uses

Ammonium Glycyrrhizinate is used in the synthesis of polyion complex nanocarriers which may act as a template for the design of other negatively charged water-soluble drugs. Particularly for anti-infl ammatory drugs with which Ammonium Glycyrrhizinate is associated.

Definition

ChEBI: Monoammonium glycyrrhizinate is an organic molecular entity.

General Description

Produced and qualified by HWI pharma services GmbH.
Exact content by quantitative NMR can be found on the certificate.

Biochem/physiol Actions

Biologically active constituent in the sweet root of Glycyrrhiza species (licorice). Antiviral.

Anticancer Research

Glycyrrhizin (GL) is a saponin-like compound that provides the main sweet flavourfor G. glabra (licorice), and it is commonly used in clinical treatment for itsoutstanding pharmacological action such as antitumour, anti-inflammatory andanti-oxidativeactions (Rebhun et al. 2015; Wu et al. 2015). Cai et al. (2017) triedto evaluate the anticancer properties of GA and GL against TNBC in combinationwith etoposide.

Safety Profile

Moderately toxic by intravenous route. An experimental teratogen. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NH3.

target

ROS

Purification Methods

Crystallise the ammonium salt from glacial acetic acid, then dissolve it in ethanolic ammonia and evaporate. The pentahydrate forms needles from 75% aqueous EtOH, m 212-217o. The free acid crystallises from glacial acetic acid. [Karrer et al. Helv Chim Acta 4 100 1921, Lithgoe & Tripett J Chem Soc 1983, 1987 1950, Beilstein 18 IV 5156.]

Glycyrrhizic acid ammonium salt Preparation Products And Raw materials

Raw materials

Glycyrrhizic acid LACQUER THINNER Ammonium hydroxide Triammonium glycyrrhizinate DGL

Preparation Products

Ammonium Glycyrrhizinate

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View Lastest Price from Glycyrrhizic acid ammonium salt manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Glycyrrhizic Acid Ammonium Salt 53956-04-0
Price: US $99.00-35.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-16

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Glycyrrhizic acid ammonium salt 53956-04-0
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.0%
Supply Ability: 1000kg/month
Release date: 2021-12-16

Hebei Weibang Biotechnology Co., Ltd

Product: Glycyrrhizic acid ammonium salt 53956-04-0
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-11

53956-04-0, Glycyrrhizic acid ammonium saltRelated Search:

Ammonium hydroxide Ammonium chloride Ammonium acetate Glycyrrhizic acid Ammonium sulfate Diammonium glycyrrhizinate Shikonin DGL Sodium hyaluronate GLYCYRRHIZIC ACID, MONOAMMONIUM SALT HYDRATE, CA. 75 Ammonium nitrate AMMONIUM GLYCYRRHIZIC ACID, AMMONIUM SALT, TRIHYDRATE(RG) Ammonium Glycyrrhizinate Glycyrrhizic acid ammonium salt GLYCYRRHIZIC ACID AMMONIUM SALT TRIHYDRATE BETA MAX?

monoammoniumglycyrrhetat

Monoammoniumglycyrrhetate

monoammoniumglycyrrhizate

(2S,3S,4S,5R,6S)-6-[[(3S,4aS,6aR,6bS,8aR,11S,12aR,14aS,14bS)-11-carboxy-4,4,6a,6b,8a,11,14b-heptamethyl-14-oxo-2,3,4a,5,6,7,8,9,10,12,12a,14a-dodecahydro-1H-picen-3-yl]oxy]-5-[(2R,3R,4S,5S,6S)-6-carboxy-3,4,5-trihydroxy-oxan-2-yl]oxy-3,4-dihydroxyoxane-2-carboxylic acid azane

alpha-D-Glucopyranosiduronic acid, (3-beta,20-beta)-20-carboxy-11-oxo-30-norolean-12-en- 3-yl 2-O-beta-D-glucopyranuronosyl-, ammoniate

20β-Carboxy-11-oxo-30-noroleana-12-ene-3β-yl 2-O-(β-D-glucopyranuronosyl)-α-D-glucopyranosiduronic acid/ammonia,(1:x)

Glycyrrhizine ammonium salt

AMMONIUM 10-[6-CARBOXY-3-(6-CARBOXY-3,4,5-TRIHYDROXY-OXAN-2-YL)OXY-4,5-DIHYDROXY-OXAN-2-YL]OXY-2,4A,6A,6B,9,9,12A-HEPTAMETHYL-13-OXO-3,4,5,6,6A,7,8,8A,10,11,12,14B-DODECAHYDRO-1H-PICENE-2-CARBOXYLATE

AMMONIATED GLYCYRRHIZIN

3-O-(2-O-BETA-D-GLUCOPYRANURONOSYL-ALPHA-D-GLUCOPYRANURONOSYL)-18BETA-GLYCYRRHETINIC ACID AMMONIUM SALT

GLYCAMIL

GLYCYRRHIZIC ACID AMMONIUM SALT

GLYCYRRHIZIC ACID, NH4

GLYCYRRHIZIC ACID, NH4+

GLYCYRRHIZIN AMMONIACAL

GLYCYRRHIZIN, AMMONIATED

GLYCYRRHIZIN AMMONIUM SALT

GLYCYRRHIZIC ACID MONOAMMONIUM SALT

GLYCYRRHIZINATE MONOAMMONIUM SALT

Glycyrrhizic acid monoammonium salt trihydrate,98%

GLYCYRRHIZIC ACID, AMMONIUM SALT(RG)

Glycyrrhiz

Glycyrrhizic acid, aMMoniuM salt, trihydrate / Glycyrrihizin

Glycyrrhizic acid MonoaMMoniuM salt, 98+%

Glycyrrhizic acid MonoaMMoniuM salt trihydrate, 98% 25GR

aMMoniuM (2S,3S,4S,5R,6S)-5-((2R,3R,4S,5S,6S)-6-carboxy-3,4,5-trihydroxytetrahydro-2H-pyran-2-yloxy)-6-((3S,6aR,6bS,8aS,11S,12aR,14aR,14bS)-11-carboxy-4,4,6a,6b,8a,11,14b-heptaMethyl-14-oxo-1,2,3,4,4a,5,6,6a,6b,7,8,8a,9,10,11,12,12a,14,14a,14b-icosahydrop

Glycyrrhizic Acid Monoammonium Salt Glycyrrhizin Monoammonium Salt

Magnasweet

MonoaMMoniuM 18β-glycyrrhizinate

Monoammonium glycyrrhizinate Glycyrrhizic acid ammonium

monoammonium glycyrrhizlnate

Monoammonium Glycyrrhizinate EP

Glycyrrhizic acid ammonium salt from glycyrrhiza

Glycyrrhizic acid ammonium salt 53956-04-0

MONOAMMONIATED GLYCYRRHIZINATE

MONOAMMONIUM GLYCRRHIZINATE

MONOAMMONIUM GLYCYRRHIZINATE

.alpha.-D-Glucopyranosiduronicacid,(3.beta.,20.beta.)-20-carboxy-11-oxo-30-norolean-12-en-3-yl2-O-.beta.-D-glucopyranuronosyl-,monoammoniumsalt

ammoniate

Ammoniumglycynhizinato

ammoniumglycyrrhizate

glycyrram

.alpha.-D-Glucopyranosiduronic acid, (3.beta.,20.beta.)-20-carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-.beta.-D-glucopyranuronosyl-, monoammonium salt

glycyrrhizin monoammonium salt

GLYCYRRHIZINICACIDAMMONIUMSALT

GLYCERRHIZICACIDMONOAMMONIUMSALT

GLYCYRRHIZICAMMONIUM

AMMONIUMGLYCYRRHIZIN

AMMONIATEDGLYCERRHIZIN

MONOAMMONIUM GLYCYRRHIZINATE 95% SODIUM GLYCYRRHIZINTE 95%

α-D-Glucopyranosiduronic acid, (3,20)-20-carboxy- 11-oxo-30-norolean-12-en-3-yl 2-O--D-glucopyranuronosyl-, monoammonium salt

3-O-(2-O-β-D-Glucopyranuronosyl-α-D-glucopyranuronosyl)-18β-glycyrrhetinic acid ammonium salt

GLYCYRRHIZIN, AMMONIATED [GLYCYRRHIZINIC ACID, MONOAMMONIUM SALT]

GLYCYRRHIZIC ACID AMMONIUM

GlycyrrhizinicAcidAmmoniumSalt,>95%

3-O-(2-O-beta-D-Glucopyranuronosyl-alpha-D-glucopyranuronosyl)-18beta-g lycyrrhetinic acid ammonium salt

AMMONIATED GLYCYRRHIZIN, NATURAL