1-METHOXY-1,3-CYCLOHEXADIENE

Product Name: 1-METHOXY-1,3-CYCLOHEXADIENE
CAS No.: 2161-90-2
Chemical Name: 1-METHOXY-1,3-CYCLOHEXADIENE
Synonyms: 2,3-DIHYDROANISOLE;1-METHOXY-1,3-CYCLOHEXADIENE;1-methoxycyclohexa-1,3-diene;1,3-Cyclohexadiene, 1-methoxy-;1,3-Cyclohexadien-1-yl methyl ether;1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%;1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole;1-Methoxy-1,3-cyclohexadiene technical grade, 65%
CBNumber: CB1494725
Molecular Formula: C7H10O
Formula Weight: 110.15
MOL File: 2161-90-2.mol

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1-METHOXY-1,3-CYCLOHEXADIENE Property

Melting point:: 96-97 °C
Boiling point:: 40 °C/15 mmHg (lit.)
Density: 0.929 g/mL at 25 °C (lit.)
refractive index: n20/D 1.488(lit.)
Flash point:: 80 °F
LogP: 1.790 (est)

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Safety

Hazard Codes: Xn
Risk Statements: 10-20/21/22
Safety Statements: 16-33-36/37/39
RIDADR: UN 1993 3/PG 3
WGK Germany: 3
HazardClass: 3.2
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation

Product number: CHM0114825
Product name: 1-METHOXY-1,3-CYCLOHEXADIENE
Purity: 95.00%
Packaging: 1MG
Price: $632.21
Updated: 2021/12/16

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1-METHOXY-1,3-CYCLOHEXADIENE Chemical Properties,Usage,Production

Uses

1-Methoxy-1,3-cyclohexadiene was used in the following studies:

Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X

General Description

1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.

1-METHOXY-1,3-CYCLOHEXADIENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-METHOXY-1,3-CYCLOHEXADIENE Suppliers

China 9 Switzerland 1 United States 3 USA 1 Global 14

3B Pharmachem (Wuhan) International Co.,Ltd.

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2161-90-2, 1-METHOXY-1,3-CYCLOHEXADIENERelated Search:

THEBAINE 1-METHOXY-1,3-CYCLOHEXADIENE 1,3-CYCLOHEXADIENE saframycin D 2,4,6-TRIMETHOXYBENZALDEHYDE OXIME NATALOE-EMODIN 8-METHYL ETHER 2,3-DIBROMO-7,8-DIHYDRODIOXINO-DIBENZODIOXIN HERNANDEZINE THIOTOMOXETINE 2-BUTENOIC ACID, 2-METHYL-, (5S,6S,7S,13AS)-5,6,7,13A-TETRAHYDRO-6-HYDROXY-1,2,3,13-TETRAMETHOXY-6,7-DIMETHYLBENZO[3,4]CYCLOOCTA[1,2-F][1,3]BENZODIOXOL-5-YL ESTER, (2Z)- SOMNIFERINE AKOS 90802 AKOS 90823 D,L-TETRAHYDROPALMATINE SULFATE AKOS 90846 2-(AMINOMETHYL)-5-METHOXYCYCLOHEXA-2,4-DIEN-1-AMINE AKOS 220-81 AKOS 90818

1-METHOXY-1,3-CYCLOHEXADIENE

2,3-DIHYDROANISOLE

1,3-Cyclohexadien-1-yl methyl ether

1,3-Cyclohexadiene, 1-methoxy-

1-methoxycyclohexa-1,3-diene

1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%

1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole

1-Methoxy-1,3-cyclohexadiene technical grade, 65%

2161-90-2

Building Blocks

Enol Ethers

Oxygen Compounds

Organic Building Blocks