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1-METHOXY-1,3-CYCLOHEXADIENE

Product Name
1-METHOXY-1,3-CYCLOHEXADIENE
CAS No.
2161-90-2
Chemical Name
1-METHOXY-1,3-CYCLOHEXADIENE
Synonyms
2,3-DIHYDROANISOLE;1-METHOXY-1,3-CYCLOHEXADIENE;1-methoxycyclohexa-1,3-diene;1,3-Cyclohexadiene, 1-methoxy-;1,3-Cyclohexadien-1-yl methyl ether;1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%;1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole;1-Methoxy-1,3-cyclohexadiene technical grade, 65%
CBNumber
CB1494725
Molecular Formula
C7H10O
Formula Weight
110.15
MOL File
2161-90-2.mol
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1-METHOXY-1,3-CYCLOHEXADIENE Property

Melting point:
96-97 °C
Boiling point:
40 °C/15 mmHg (lit.)
Density 
0.929 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.488(lit.)
Flash point:
80 °F
LogP
1.790 (est)
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Safety

Hazard Codes 
Xn
Risk Statements 
10-20/21/22
Safety Statements 
16-33-36/37/39
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
HazardClass 
3.2
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
CHM0114825
Product name
1-METHOXY-1,3-CYCLOHEXADIENE
Purity
95.00%
Packaging
1MG
Price
$632.21
Updated
2021/12/16
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1-METHOXY-1,3-CYCLOHEXADIENE Chemical Properties,Usage,Production

Uses

1-Methoxy-1,3-cyclohexadiene was used in the following studies:

  • Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
  • Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
  • Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.

Synthesis Reference(s)

Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X

General Description

1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.

1-METHOXY-1,3-CYCLOHEXADIENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-METHOXY-1,3-CYCLOHEXADIENE Suppliers

2161-90-2, 1-METHOXY-1,3-CYCLOHEXADIENERelated Search:


  • 1-METHOXY-1,3-CYCLOHEXADIENE
  • 2,3-DIHYDROANISOLE
  • 1,3-Cyclohexadien-1-yl methyl ether
  • 1,3-Cyclohexadiene, 1-methoxy-
  • 1-methoxycyclohexa-1,3-diene
  • 1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%
  • 1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole
  • 1-Methoxy-1,3-cyclohexadiene technical grade, 65%
  • 2161-90-2
  • Building Blocks
  • Enol Ethers
  • Oxygen Compounds
  • Organic Building Blocks