METHYL 3-NITROPROPIONATE 97
- Product Name
- METHYL 3-NITROPROPIONATE 97
- CAS No.
- 20497-95-4
- Chemical Name
- METHYL 3-NITROPROPIONATE 97
- Synonyms
- Methyl 3-Nitropropanoate;Methyl 3-nitropropionate;METHYL 3-NITROPROPIONATE 97;METHYL 3-NITROPROPIONATE 97%;2,4,7-Tribromo methyl benzoate;Propanoic acid, 3-nitro-, methyl ester
- CBNumber
- CB1503689
- Molecular Formula
- C4H7NO4
- Formula Weight
- 133.1
- MOL File
- 20497-95-4.mol
METHYL 3-NITROPROPIONATE 97 Property
- Boiling point:
- 68 °C/1 mmHg(lit.)
- Density
- 1.249 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.4350(lit.)
- Flash point:
- 110 °C
- pka
- 7.67±0.29(Predicted)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 5011CC
- Product name
- Methyl3-nitropropanoate
- Packaging
- 5g
- Price
- $1680
- Updated
- 2021/12/16
METHYL 3-NITROPROPIONATE 97 Chemical Properties,Usage,Production
Uses
Methyl 3-Nitropropanoate is used to nitroaldol additions, condensation reactions, and Michael additions involving the NO2-substituted carbon; the α-carbonyl carbon in dilithionitronate enolates of the esters undergoes alkylations, double alkylations, and aldol and Michael additions; elimination of HNO2 from the products gives α,β- unsaturated esters with substituents in either the β- or the α-position, thus making the reagent a synthetic equivalent of acrylate anions with d3 or d2 reactivity; precursor to nitrile oxide for [3 + 2] cycloadditions; 3-nitropropanoyl chloride can be used for enolate acylation and five-membered ring annulation.
METHYL 3-NITROPROPIONATE 97 Preparation Products And Raw materials
Raw materials
Preparation Products
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