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2-Bromo-4-fluoronitrobenzene

Product Name
2-Bromo-4-fluoronitrobenzene
CAS No.
700-36-7
Chemical Name
2-Bromo-4-fluoronitrobenzene
Synonyms
2-bromo-4-fluoro-1-nitrobenzene;2-Bromo-4-fluoronitrobenzene;1-Bromo-5-fluoro-2-nitrobenzene;2-Bromo-4-fluoronitrobenzene,>98%;Benzene, 2-bromo-4-fluoro-1-nitro-;2-BroMo-4-fluoronitrobenzene, 97+%;2-Bromo-4-fluoro-1-nitrobenzene >2-bromine-4-fluorine-1-Nitrobenzene;2-Bromo-4-fluoronitrobenzene ISO 9001:2015 REACH
CBNumber
CB1512322
Molecular Formula
C6H3BrFNO2
Formula Weight
220
MOL File
700-36-7.mol
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2-Bromo-4-fluoronitrobenzene Property

Melting point:
44 °C
Boiling point:
70-75 °C(Press: 0.4 Torr)
Density 
1.808±0.06 g/cm3(Predicted)
refractive index 
1.57
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
form 
Solid
color 
Pale yellow to green
InChI
InChI=1S/C6H3BrFNO2/c7-5-3-4(8)1-2-6(5)9(10)11/h1-3H
InChIKey
VGYVBEJDXIPSDL-UHFFFAOYSA-N
SMILES
C1([N+]([O-])=O)=CC=C(F)C=C1Br
CAS DataBase Reference
700-36-7
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Safety

Safety Statements 
24/25
HS Code 
29049090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3061
Product name
2-Bromo-4-fluoro-1-nitrobenzene
Purity
>98.0%(GC)
Packaging
5g
Price
$41
Updated
2025/07/31
TRC
Product number
B688678
Product name
2-Bromo-4-fluoro-1-nitrobenzene
Packaging
10g
Price
$55
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB105605
Product name
2-Bromo-4-fluoro-1-nitrobenzene
Packaging
10g
Price
$80
Updated
2021/12/16
SynQuest Laboratories
Product number
4654-B-02
Product name
2-Bromo-4-fluoronitrobenzene
Packaging
25g
Price
$82
Updated
2021/12/16
ChemScene
Product number
CS-D1760
Product name
2-Bromo-4-fluoronitrobenzene
Purity
99.81%
Packaging
100g
Price
$142
Updated
2021/12/16
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2-Bromo-4-fluoronitrobenzene Chemical Properties,Usage,Production

Chemical Properties

Yellow to pale green powder

Uses

2-Bromo-4-fluoro-1-nitrobenzene can be used as a valuable building block, mainly for the preparation of Benzimidazoles.

Synthesis

371-40-4

700-36-7

General procedure for the synthesis of 1-bromo-5-fluoro-2-nitrobenzene from 4-fluoroaniline: N-bromosuccinimide (34 g, 180 mmol) was dissolved in dichloromethane (60 mL) at 0 °C and slowly added dropwise to a solution of 4-fluoroaniline (20 g, 180 mmol) in dichloromethane (100 mL). The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, it was washed sequentially with saturated sodium sulfite solution, saturated sodium bicarbonate solution and brine, and then concentrated to give 1-bromo-5-fluoro-2-nitrobenzene (34 g, 154.5 mmol, 100% yield). The 1H NMR (400 MHz, CDCl3) data of the product were as follows: δ 7.12-7.21 (m, 1H), 7.47 (dd, J = 7.60, 2.40 Hz, 1H), (dd, J = 9.60, 6.40 Hz, 1H).

References

[1] Patent: US2008/300242, 2008, A1. Location in patent: Page/Page column 62

2-Bromo-4-fluoronitrobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-4-fluoronitrobenzene Suppliers

Ricci Chimica
Tel
--
Fax
--
Email
sales@riccichimica.com
Country
Italy
ProdList
2146
Advantage
46
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View Lastest Price from 2-Bromo-4-fluoronitrobenzene manufacturers

Henan Fengda Chemical Co., Ltd
Product
2-Bromo-4-fluoronitrobenzene 700-36-7
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-26
Shaanxi Dideu Medichem Co. Ltd
Product
1-Bromo-5-fluoro-2-nitrobenzene 700-36-7
Price
US $0.00-0.00/Kg
Min. Order
1KG
Purity
99.0%
Supply Ability
100 tons
Release date
2020-01-10
Career Henan Chemical Co
Product
2-Bromo-4-fluoronitrobenzene 700-36-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-12

700-36-7, 2-Bromo-4-fluoronitrobenzeneRelated Search:


  • 2-bromo-4-fluoro-1-nitrobenzene
  • 1-Bromo-5-fluoro-2-nitrobenzene
  • 2-Bromo-4-fluoronitrobenzene
  • 2-BroMo-4-fluoronitrobenzene, 97+%
  • 2-Bromo-4-fluoro-1-nitrobenzene &gt
  • 2-Bromo-4-fluoronitrobenzene,>98%
  • Benzene, 2-bromo-4-fluoro-1-nitro-
  • 2-Bromo-4-fluoronitrobenzene ISO 9001:2015 REACH
  • 2-bromine-4-fluorine-1-Nitrobenzene
  • 700-36-7
  • 70-36-7