Dibenzofuran-4-boronic acid

Product Name: Dibenzofuran-4-boronic acid
CAS No.: 100124-06-9
Chemical Name: Dibenzofuran-4-boronic acid
Synonyms: DIBENZO[B,D]FURAN-4-YLBORONIC ACID;4-DIBENZOFURANBORONIC ACID;dibenzofuran-4-ylboronic acid;FRBA;DBF-B;D2420G1;AKOS BRN-0085;4-(DibenzofuranyL;TIMTEC-BB SBB003426;RARECHEM AH PB 0052
CBNumber: CB1671054
Molecular Formula: C12H9BO3
Formula Weight: 212.01
MOL File: 100124-06-9.mol

More

Less

Dibenzofuran-4-boronic acid Property

Melting point:: 286-291 °C (lit.)
Boiling point:: 438.5±37.0 °C(Predicted)
Density: 1.34±0.1 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
pka: 8.04±0.30(Predicted)
form: powder
color: white to off-white
BRN: 1645426
InChI: InChI=1S/C12H9BO3/c14-13(15)10-6-3-5-9-8-4-1-2-7-11(8)16-12(9)10/h1-7,14-15H
InChIKey: ZXHUJRZYLRVVNP-UHFFFAOYSA-N
SMILES: B(C1=C2C(=CC=C1)C1=CC=CC=C1O2)(O)O
CAS DataBase Reference: 100124-06-9(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26-24/25
WGK Germany: 3
TSCA: No
HazardClass: IRRITANT
HS Code: 29321900

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 499951
Product name: 4-(Dibenzofuranyl)boronic acid
Purity: ≥95.0%
Packaging: 5g
Price: $40.6
Updated: 2023/06/20

TCI Chemical

Product number: D4567
Product name: Dibenzofuran-4-boronic Acid (contains varying amounts of Anhydride)
Packaging: 1g
Price: $23
Updated: 2025/07/31

TCI Chemical

Product number: D4567
Product name: Dibenzofuran-4-boronic Acid (contains varying amounts of Anhydride)
Packaging: 5g
Price: $65
Updated: 2025/07/31

TRC

Product number: D417208
Product name: Dibenzofuran-4-boronicacid
Packaging: 500mg
Price: $65
Updated: 2021/12/16

Apolloscientific

Product number: OR6444
Product name: Dibenzo[b,d]furan-4-boronicacid
Packaging: 1g
Price: $15
Updated: 2021/12/16

More

Less

Dibenzofuran-4-boronic acid Chemical Properties,Usage,Production

Description

Dibenzofuran-4-boronic acid (DBFBA) is a boronic acid that has been used as a cross-coupling agent in the Suzuki coupling reaction. It has been shown to have low efficiency, but advances in this area have been made through the use of methanol extraction and photophysical properties. DBFBA is often coupled with imidazole derivatives to form anti-inflammatory compounds. The bond cleavage and hydrogen bonding properties of DBFBA make it a good target for drug synthesis.

Chemical Properties

off-white to beige powder

Uses

Dibenzofuran-4-boronic acid is a water-soluble boronic acid, and the boronic acid molecule is a very useful functional group for the preparation of glycosensors. Water-soluble boronic acids that change their fluorescence properties upon binding to sugars are particularly useful as reporter units for carbohydrate fluorescence sensors. Dibenzofuran-4-boronic acid displays distinctive fluorescence changes at three wavelengths when bound to sugars under near-physiological conditions^[1].

Synthesis

In a 300 ml three-necked flask, 7.2 g of 4-bromodibenzofuran was dissolved in -78° C. anhydrous tetrahydrofuran (THF) under an argon atmosphere. Then, 20 ml of an n-butyl lithium-n-hexane solution (1.6 M, 1.1 eq) was added and stirred for 1 hour. 4.23 ml (1.3 eq) of trimethoxyborane (B(OMe)3) was added and stirred for 2 hours, and the temperature of the reaction system was increased to room temperature. 200 ml of 1 N hydrochloric acid was added into the reactant and stirred for 3 hours. An organic layer was separated, and solvents were distilled off. In the crude product thus obtained, hexane was added. Precipitated product was filtered to obtain 4.94 g of dibenzofuran-4-boronic acid as a white solid (yield 80%).

References

[1] JUNFENG WANG Binghe W Shan Jin. A new boronic acid fluorescent reporter that changes emission intensities at three wavelengths upon sugar binding[J]. Tetrahedron Letters, 2005. DOI:10.1016/j.tetlet.2005.08.053.

Dibenzofuran-4-boronic acid Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Dibenzofuran-4-boronic acid Suppliers

Americas 1 Belgium 4 China 341 Europe 1 France 5 Germany 12 India 5 Italy 1 Japan 6 Jordan 1 Russia 1 South Korea 2 Switzerland 2 The Netherlands 1 United Kingdom 13 United States 54 Global 450

INTATRADE GmbH

Tel: +49 3493/605464
Fax: +49 3493/605470
Email: sales@intatrade.de
Country: Germany
ProdList: 3572
Advantage: 66

Alfa Aesar, Thermo Fisher Scientific

Tel: --
Fax: --
Email: es@alfa.com
Country: Germany
ProdList: 5123
Advantage: 58

Archimica Germany

Tel: --
Fax: --
Country: Germany
ProdList: 190
Advantage: 58

CHEMOS GmbH & Co. KG

Tel: --
Fax: --
Email: chemos@chemos.de
Country: Germany
ProdList: 6727
Advantage: 58

SYNTHON Chemicals GmbH & Co. KG

Tel: --
Fax: --
Email: synthon@synthon-chemicals.com
Country: Germany
ProdList: 2000
Advantage: 65

ChemPur GmbH

Tel: --
Fax: --
Email: info@ChemPur.de
Country: Germany
ProdList: 2737
Advantage: 50

ABCR GmbH & CO. KG

Tel: --
Fax: --
Email: info@abcr.de
Country: Germany
ProdList: 6831
Advantage: 75

Archimica

Tel: --
Fax: --
Email: juergen.brockmann@clariant.com
Country: Germany
ProdList: 526
Advantage: 68

Service Chemical Inc.

Tel: --
Fax: --
Email: sales@chemos-group.com
Country: Germany
ProdList: 6350
Advantage: 71

AKos Consulting & Solutions GmbH

Tel: --
Fax: --
Email: akos@akosgmbh.de
Country: Germany
ProdList: 6717
Advantage: 72

ACTIVATE SCIENTIFIC GmbH

Tel: --
Fax: --
Email: info@activate-scientific.com
Country: Germany
ProdList: 2856
Advantage: 61

Rare Chemicals GmbH

Tel: --
Fax: --
Email: sales@rarechem.de
Country: Germany
ProdList: 6297
Advantage: 38

More

Less

View Lastest Price from Dibenzofuran-4-boronic acid manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: DIBENZOFURAN-4-BORONIC ACID 100124-06-9
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-27

Shanghai Daken Advanced Materials Co.,Ltd

Product: Boronic acid,B-4-dibenzofuranyl- 100124-06-9
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.00%
Supply Ability: 150KG /month
Release date: 2021-11-17

Hebei Yanxi Chemical Co., Ltd.

Product: DIBENZOFURAN-4-BORONIC ACID 100124-06-9
Price: US $50.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10000
Release date: 2023-10-30

100124-06-9, Dibenzofuran-4-boronic acidRelated Search:

4-AMINO-N,N-DIMETHYLBENZYLAMINE 4-(DIMETHOXYMETHYL)-2-METHYLPYRIMIDINE 4-Chlorobiphenyl 4-DIBENZOTHIOPHENEBORONIC ACID 4-Bromodiphenylamine 4-BROMO-P-TERPHENYL 4-Bromophenoxybenzene DIBENZOFURAN-4-CARBOXALDEHYDE 97 Dibenzo[b,d]furan-2-ylboronic acid dibenzo[b,d]furan-3-ylboronic acid DIBENZOFURAN-2-CARBOXALDEHYDE 2-Fluoro-3-pyridylboronic acid 2-Chloro-3-pyridylboronic acid 5-Chloro-2-fluoropyridin-3-ylboronic acid Phenylboronic acid Methylboronic acid Dibenzofuran DIBENZOFURAN-4-BORONIC ACID

RARECHEM AH PB 0052

TIMTEC-BB SBB003426

DIBENZO[B,D]FURAN-4-YLBORONIC ACID

DIBENZOFURAN-4-BORONIC ACID

4-DIBENZOFURANBORONIC ACID

AKOS BRN-0085

Dibenzofuran-4-boronic acid, 98+%

dibenzofuran-4-ylboronic acid

4-(Dibenzofuranyl)boronic acid

nzofuran-4-Boronic acid

4-dibenzofuran boronic

Dibenzofuran-4-boronic acid,97%

FRBA

Dibenzo[d,b]furan-4-ylboronic acid

Boronic acid, 4-dibenzofuranyl-

DIBENZOFURAN-4-BORONIC ACID In stock Factory

4-(DibenzofuranyL

4-Boronodibenzo[b,d]furan

Dibenzo[b,d]furan-4-boronic acid

Boronic acid,B-4-dibenzofuranyl-

4-(Dibenzofuranyl)boronic Acid, 97+%

4-Dibenzofuranboronic acid SynonyMs 4-(Dibenzofuranyl)boronic acid

4-(Dibenzofuranyl)boronic acid >=95.0%

D2420G1

Dibenzofuran-4-boronic Acid (contains varying amounts of Anhydride)

Dibenxofuran-4-boronic acid

4-(Dibenzofuranyl)boronic acid, 98%, contains varying amounts of anhydride

4-Dibenzofuranboronic acid/ 4-(Dibenzofuranyl)boronic acid

4-diphenylenzofuranic acid

Dibenzofuran-4-BoronicAci

DBF-B

Boronic acid, B-4-dibenzofurany-

TIANFU-CHEM 100124-06-9 DIBENZOFURAN-4-BORONIC ACID

2-Methyl-82-nitrobenzyl&chloride

4-Dibenzofuranboronic acid (6CI)

4-dibenzofurylboronic acid

4-(Dibenzofuranyl)boronic acid (contains varying amounts of Anhydride)

4-oxfluorene boric acid

4-Dibenzofuranboronic acid 99%

Dibenzofuran-4-boronic acid - [D2420]

100124-06-9

C12H9BO3

BORONIC ACID

Boronic Acids

Boronic Acids and Derivatives

Heteroaryl

Organometallic Reagents

Heterocyclic Compounds

Boronic acid

Dibenzofuran

Organoborons

Boronic Acids

Boronic Acids and Derivatives

Heteroaryl

OLED materials,pharm chemical,electronic

100124-06-9

OLED