ChemicalBook > CAS DataBase List > 4,4'-Bipyridine

4,4'-Bipyridine

Product Name
4,4'-Bipyridine
CAS No.
553-26-4
Chemical Name
4,4'-Bipyridine
Synonyms
4,4-BIPYRIDINE;4,4-DIPYRIDYL;4,4'-BIPYRIDYL;4,4'-DIPYRIDYL;GAMMA,GAMMA-DIPYRIDYL;'LGC' (1608);γ,γ'-Dipyridy;g,g'-Dipyridyl;4,4'-Bipyridyl;4,4'-Dipyridyl
CBNumber
CB1671180
Molecular Formula
C10H8N2
Formula Weight
156.18
MOL File
553-26-4.mol
More
Less

4,4'-Bipyridine Property

Melting point:
109-112 °C(lit.)
Boiling point:
305 °C(lit.)
Density 
1.2814 (rough estimate)
refractive index 
1.6057 (estimate)
Flash point:
304-305°C
storage temp. 
Store below +30°C.
solubility 
4.5g/l
form 
Powder
pka
pK1:3.17(+2);pK2:4.82(+1) (25°C)
color 
Off-white to beige
Water Solubility 
slightly soluble
Sensitive 
Hygroscopic
λmax
300nm(CH3CN)(lit.)
Merck 
14,3348
BRN 
113176
Stability:
Stable. Incompatible with strong oxidizing agents, strong acids.
InChIKey
MWVTWFVJZLCBMC-UHFFFAOYSA-N
CAS DataBase Reference
553-26-4(CAS DataBase Reference)
NIST Chemistry Reference
4,4'-Bipyridine(553-26-4)
EPA Substance Registry System
4,4'-Bipyridine (553-26-4)
More
Less

Safety

Hazard Codes 
T,Xi
Risk Statements 
25-36/37/38-20/21-23/24/25
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
RTECS 
DW1760000
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
29333999
Toxicity
LD50 orally in Rabbit: 172 mg/kg
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
289426
Product name
4,4′?Dipyridyl
Purity
98%
Packaging
5g
Price
$38.3
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20158
Product name
4,4′-Bipyridine
Purity
for synthesis
Packaging
10g
Price
$75.7
Updated
2024/03/01
Sigma-Aldrich
Product number
289426
Product name
4,4′?Dipyridyl
Purity
98%
Packaging
25g
Price
$126
Updated
2024/03/01
TCI Chemical
Product number
B0469
Product name
4,4'-Bipyridyl
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$83
Updated
2024/03/01
TCI Chemical
Product number
B0469
Product name
4,4'-Bipyridyl
Purity
>98.0%(GC)(T)
Packaging
100g
Price
$252
Updated
2024/03/01
More
Less

4,4'-Bipyridine Chemical Properties,Usage,Production

Chemical Properties

off-white to tan powder

Uses

4,4'-Bipyridine is used in transition-metal complex catalyst chemistry for uniform polymerization, in luminescence chemistry and in spectrophotometric analysis. It plays an important role as a photosensitizer and luminescent material. It is also used as a precursor to paraquat viz. N,N'-dimethyl-4,4'-bipyridinium.

Definition

ChEBI: A bipyridine in which the two pyridine moieties are linked by a bond between positions C-4 and C-4'.

Synthesis Reference(s)

Tetrahedron Letters, 26, p. 1655, 1985 DOI: 10.1016/S0040-4039(00)98576-9

General Description

4,4′-Dipyridyl (BPY) is an organic linker mainly used in the preparation of coordination polymers. It is a pyridine derivative in which pyridyl groups can rotate along the carbon-carbon structure. It can be used as a catalyst for photoelectrochemical reduction.

Safety Profile

Poison by ingestion. When heatedto decomposition it emits toxic vapors of NOx.

Purification Methods

It crystallises from water, *benzene/pet ether, ethyl acetate and sublimes in vacuo at 70o. Also purify it by dissolving in 0.1M H2SO4 and twice precipitating by addition of 1M NaOH to pH 8. Then recrystallise it from EtOH. For the dihydrochloride see Viologen below. [Collman et al. J Am Chem Soc 109 4606 1987, Beilstein 23 H 800, 23 III/IV 1371, 23/8 V 28.]

4,4'-Bipyridine Preparation Products And Raw materials

Raw materials

Preparation Products

1-METHYL-[4,4']BIPIPERIDINYL
More
Less

4,4'-Bipyridine Suppliers

Americas 1 Austria 1 Belgium 2 Canada 2 China 391 Europe 3 Germany 8 India 20 Japan 6 Slovakia 1 South Korea 1 Sweden 1 Switzerland 5 The Netherlands 1 Ukraine 1 United Kingdom 18 United States 47 Global 509
Changzhou Zhongji Chemical Co.,Ltd
Tel
0519-85156279-811,812
Fax
0519-85156279-816
Email
sales@czzjchem.com
Country
China
ProdList
20
Advantage
58
Shanghai yongzeng technology co., LTD
Tel
021-021-021-65281118 15921781258
Fax
021-6528 2963
Email
sales@yongzchem.com
Country
China
ProdList
66
Advantage
58
JinJin Le Chemical Co., Ltd
Tel
10106090
Email
jjlchem2@163.com
Country
China
ProdList
9981
Advantage
58
Zhangjiagang Free Trade Zone Kailite Chemical Co., Ltd.
Tel
18606289633 15862625988
Fax
0512-58813106
Email
sales@clentchem.com
Country
China
ProdList
172
Advantage
60
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18207
Advantage
66
Zhangjiagang BoMan Chemical Co., Ltd.
Tel
15601563028
Fax
4006648400-2
Country
China
ProdList
29
Advantage
60
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Jia Xing Isenchem Co.,Ltd
Tel
0573-85285100 18627885956
Fax
0573-85285100
Email
isenchem@163.com
Country
China
ProdList
9513
Advantage
66
Nanjing Chemlin Chemical Co., Ltd
Tel
025-83697070
Fax
+86-25-83453306
Email
info@chemlin.com.cn
Country
China
ProdList
19179
Advantage
64
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
XiaoGan ShenYuan ChemPharm co,ltd
Tel
15527768850
Email
1791901229@qq.com
Country
China
ProdList
8837
Advantage
52
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Sichuan Kulinan Technology Co., Ltd
Tel
400-1166-196 18981987031
Fax
028-84555506 800101999
Email
cdhxsj@163.com
Country
China
ProdList
11707
Advantage
57
RYSS TECH LTD
Tel
400-188-0725 +86 21 34310725 13611771617
Fax
+86 21 34311076
Country
China
ProdList
2002
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Sinopharm Chemical Reagent Co,Ltd.
Tel
86-21-63210123
Fax
86-21-63290778 86-21-63218885
Email
sj_scrc@sinopharm.com
Country
China
ProdList
9815
Advantage
79
Shanghai Sunway Pharmaceutical Technology Co., Ltd
Tel
021-51613915-820 13611835272
Fax
021 51613951
Email
mmwang@sunwaypharm.cn
Country
China
ProdList
9734
Advantage
57
Maya High Purity Chemicals
Tel
+86 (573) 82222445 (0)18006601000 452520369
Fax
+86 (573) 82222643
Email
sales@maya-r.com
Country
China
ProdList
11707
Advantage
57
Springchem New Material Technology Co.,Limited
Tel
+86-021-62885108 +8613917661608
Email
info@spring-chem.com
Country
China
ProdList
2068
Advantage
57
Beijing Taiya Jie Technology Development Co., Ltd.
Tel
021-33690831-8001 13552411790
Fax
021-33690831
Email
postmaster@tyjchem.cn
Country
China
ProdList
1541
Advantage
55
ShangHai YuanYe Biotechnology Co., Ltd.
Tel
021-61312847 13636370518
Fax
021-55068248
Email
shyysw007@163.com
Country
China
ProdList
4940
Advantage
60
AILY INTL CHEMICAL CORP LTD
Tel
025-83208295 18913388297
Fax
+86-2583208202
Email
ben@ailychem.com
Country
China
ProdList
132
Advantage
50
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing innoChem Science & Technology Co.,Ltd.
Tel
400-810-7969 010-59572699
Fax
010-59572688
Email
ningzi.li@inno-chem.com.cn
Country
China
ProdList
6134
Advantage
55
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.
Tel
025-66099280 17798518460
Fax
(1)02557626880
Email
cfzhang@aikonchem.com
Country
China
ProdList
19915
Advantage
55
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
18209
Advantage
56
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
The future of Shanghai Industrial Co., Ltd.
Tel
021-61552785
Fax
021-55660885
Email
sales@shshiji.com
Country
China
ProdList
9545
Advantage
55
Shanghai Ruji Biology Technology Co., Ltd.
Tel
+86-21-65211385-8001 36031160
Fax
+86-21-65211385-8004
Email
sales@shruji.com
Country
China
ProdList
3224
Advantage
55
Cantotech Chemicals, Ltd.
Tel
86-0755-86635001
Fax
86-0755-22642228
Email
cantotech@126.com
Country
China
ProdList
4566
Advantage
55
Shanghai Yolne Chemical Co., Ltd.
Tel
021-62960152
Fax
021-52212593
Email
934678158@qq.com
Country
China
ProdList
9899
Advantage
55
Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.
Tel
+86-28-85122536 85324413
Fax
+86-28-85326443
Email
market@astatech.cn
Country
China
ProdList
8026
Advantage
55
Zouping Mingxing Chemical Co.,Ltd.
Tel
86-13605431940 13605431940
Fax
0086-0543-2240079
Email
zpmxchemical@126.com
Country
China
ProdList
1999
Advantage
62
Quzhou Juhua Friendship Co., Ltd
Tel
0570-3066667
Fax
0570-3063388
Country
China
ProdList
3930
Advantage
58
Beijing Universal Century Technology Co., Ltd.
Tel
400-8706899
Fax
400-8706899
Email
hysj_bj.com
Country
China
ProdList
3583
Advantage
55
Shanghai Meishui Chemical Technology Co., Ltd
Tel
021-60549325 18616193163
Fax
021-33250306
Country
China
ProdList
4526
Advantage
56
Shanghai JONLN Reagent Co., Ltd.
Tel
400-0066400 13621662912
Fax
021-55660885
Email
422131432@qq.com
Country
China
ProdList
9978
Advantage
55
Huainan Kedi Chemical Factory
Tel
0554-2106669
Fax
0554-2666215
Email
sales1@kedichem.com
Country
China
ProdList
4924
Advantage
55
More
Less

View Lastest Price from 4,4'-Bipyridine manufacturers

Hebei Longbang Technology Co., Ltd
Product
4,4'-Bipyridine 553-26-4
Price
US $5.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20TONS
Release date
2024-05-11
Hebei Weibang Biotechnology Co., Ltd
Product
4,4'-Bipyridine 553-26-4
Price
US $8.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-28
Hebei Jingbo New Material Technology Co., Ltd
Product
4,4'-Bipyridine 553-26-4
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000000
Release date
2024-01-05

553-26-4, 4,4'-BipyridineRelated Search:

Pyridine 4-Aminobutyric acid DIPIPERIDINOMETHANE Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Sulfasalazine Chromium picolinate 2,2'-Bipyridine Morfamquat(dichloride((content>65%) Paraquat methosulfate 2,2':6',2''-TERPYRIDINE !2,2'-bipyridine! !dihydrochloride! 2,2'-DIPYRIDYL N,N'-DIOXIDE tris[2,2'-bipyridine]ruthenium dichloride ,tris(2,2’-bipyridine-n,n’)-,dichloride,(oc-6-11)-ruthenium(2+ 4,4'-Dinonyl-2,2'-bipyridine 4,4’-diphenyl-2’-bipyridin Paraquat dichloride 4,4'-Dipyridyl hydrate ETHYL VIOLOGEN DIPERCHLORATE

  • 'LGC' (1608)
  • GAMMA,GAMMA'-DIPYRIDYL
  • GAMMA,GAMMA-DIPYRIDYL
  • 4, 4'-DIPYRIDINE
  • 4,4'-DIPYRIDYL
  • 4,4-DIPYRIDYL
  • 4,4'-BIPYRIDINE
  • 4,4-BIPYRIDINE
  • 4,4'-BIPYRIDYL
  • 4,4'-BIPYRIDYL HYDRATE
  • 4,4,4'-DIPYRIDYL
  • 4-PYRIDIN-4-YLPYRIDINE
  • 4-(4-Pyridyl)pyridine
  • 4,4’-Bipyridine,dihydrate
  • Bipyridine, 4,4'-
  • gamma,gamma’-bipyridyl
  • gamma,gamma'-Bipyridyl
  • 4,4'Bipyridinyl
  • 4,4'-BIPYRIDINE ANHYDROUS PESTANAL
  • 4,4'-Bipyridyl,98%
  • 4,4'-Bipyridine,98%
  • 4,4'-BIPYRIDINE ANHYDROUS
  • 4,4'-Dipyridyl, anhydrous, 98%
  • 4,4-DIPYRIDYL, 4,4-BIPYRIDINE
  • 4,4''-DIPYRIDINE / 4,4''-DIPYRIDYL
  • 4,4''-DIPYRIDYL, 98%, ANHYDROUS
  • 4,4μ-Bipyridine, 4,4μ-Bipyridyl
  • 4,4'-Dipyridyl ,99%
  • g,g'-Dipyridyl
  • 4,4′-Bipyridyl,4,4′-Bipyridine
  • 4,4'-Bipyridyl dihydrate
  • 4,4'-Dipyridyl 98%
  • 4, 4 - al pyridine
  • 4,4'-Bipyridine SynonyMs 4,4'-Dipyridyl
  • γ,γ'-Dipyridy
  • 4,4'-Dipyridyl≥ 99% (Assay)
  • 4,4'-Bipyridine for synthesis
  • 4,4'-Dipyridyl, 99%, for synthesis
  • 4,4'-Bipyridyl &gt
  • 4, 4 '- pyridine
  • 4,4,-Bipyridyl, GR 98%
  • 4,4'-Bipyridine (8CI, 9CI, ACI)
  • Metamitron Impurity 7
  • 4,4'-Bipyridine
  • 4,4'-Bipyridyl
  • 4,4'-Dipyridine
  • 4,4'-Dipyridyl
  • 553-26-4
  • 53-26-4
  • -C5H4N22H2O
  • Photochromic Compounds
  • Viologens (Photochromic, Related Compounds)
  • C9
  • C9 to C46
  • Carbonyl Compounds
  • Building Blocks
  • Pyridines
  • Ketones