Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Product Name
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- CAS No.
- 1149-23-1
- Chemical Name
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Synonyms
- diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate;DILUDINE;hantzschester;ethidine;1,4-DIHYDRO-2,6-DIMETHYL-3,5-PYRIDINEDICARBOXYLIC ACID DIETHYL ESTER;1,4-dihydro-2,6-dimethyL;rr116;etidin;diethone;DIETHANE
- CBNumber
- CB4757520
- Molecular Formula
- C13H19NO4
- Formula Weight
- 253.29
- MOL File
- 1149-23-1.mol
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Property
- Melting point:
- 178-183 °C(lit.)
- Boiling point:
- 351.8±42.0 °C(Predicted)
- Density
- 1.104±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Soluble in organic solvents.
- pka
- 3.50±0.70(Predicted)
- form
- Solid
- color
- Yellow
- λmax
- 374nm(EtOH)(lit.)
- InChI
- InChI=1S/C13H19NO4/c1-5-17-12(15)10-7-11(13(16)18-6-2)9(4)14-8(10)3/h14H,5-7H2,1-4H3
- InChIKey
- LJXTYJXBORAIHX-UHFFFAOYSA-N
- SMILES
- C1(C)NC(C)=C(C(OCC)=O)CC=1C(OCC)=O
- CAS DataBase Reference
- 1149-23-1(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 120227
- Product name
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Purity
- 95%
- Packaging
- 1G
- Price
- $73.8
- Updated
- 2024/03/01
- Product number
- 120227
- Product name
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Purity
- 95%
- Packaging
- 10G
- Price
- $455
- Updated
- 2024/03/01
- Product number
- 120227
- Product name
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Purity
- 95%
- Packaging
- 50G
- Price
- $1870
- Updated
- 2024/03/01
- Product number
- D3775
- Product name
- Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 5g
- Price
- $24
- Updated
- 2024/03/01
- Product number
- D3775
- Product name
- Diethyl 1,4-Dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate
- Purity
- >98.0%(HPLC)(N)
- Packaging
- 25g
- Price
- $59
- Updated
- 2024/03/01
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Chemical Properties,Usage,Production
Chemical Properties
Light green solid
Uses
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is a hydrogen source in conjugate reduction and organocatalytic reductive amination. It is used as a hydrogen source in organocatalytic reductive amination and conjugate reduction.
Uses
3,5-Dicarboethoxy-2,6-dimethyl-1,4-dihydropyridine is a dihydropyridine derivative that have been tested for antimicrobial activities.
Application
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate (DTP) was used to study the mechanism of electrochemical oxidation of DTP in ethanol/water solutions on a glassy carbon electrode.
Hazard
H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
Toxicology
rat LD50 intraperitoneal >16 gm/kg
mouse LD50 oral >32 gm/kg
mouse LD50 intraperitoneal >30 gm/kg
dog LD50 oral >12 gm/kg
Synthesis
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate is prepared by the reaction of formaldehyd and ethyl acetoacetate in the presence of an inert gas.
Purification Methods
recrystallization from EtOH or flash chromatography with petroleum/ethyl acetate (7:3)
Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate manufacturers
- Product
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate 1149-23-1
- Price
- US $0.00/kg
- Min. Order
- 25kg
- Purity
- 99.0%
- Supply Ability
- 1tons
- Release date
- 2024-04-26
- Product
- Dihydropyridine 1149-23-1
- Price
- US $180.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-06-03
- Product
- Diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate 1149-23-1
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-11-19