(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine

Product Name: (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
CAS No.: 127184-05-8
Chemical Name: (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Synonyms: (+)-8;8AR)-8;8-Dichlorocamphorylsulfonyl)oxaziri dine;(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE;(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine;(+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%;(+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T);(1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione;(4aS,7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
CBNumber: CB1690604
Molecular Formula: C10H13Cl2NO3S
Formula Weight: 298.19
MOL File: 127184-05-8.mol

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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Property

Melting point:: 181-186 °C
Boiling point:: 390.5±52.0 °C(Predicted)
Density: 1.68±0.1 g/cm3(Predicted)
storage temp.: 2-8°C
solubility: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form: Solid
pka: -15.63±0.60(Predicted)
color: White to Off-White
optical activity: [α]20/D +89±3°, c = 0.5% in chloroform
BRN: 3653352
InChI: InChI=1/C10H13Cl2NO3S/c1-7(2)6-3-4-8(7)5-17(14,15)13-10(8,16-13)9(6,11)12/h6H,3-5H2,1-2H3/t6-,8-,10+,13?/s3
InChIKey: HAMBQYFZDBYWHU-XCDSEQPNNA-N
SMILES: [C@@]123ON1S(=O)(=O)C[C@@]12CC[C@@]([H])(C1(C)C)C3(Cl)Cl |&1:0,7,10,r|

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Safety

Safety Statements: 22-24/25
RIDADR: 1479
WGK Germany: 3
F: 8-10
HazardClass: 5.1
PackingGroup: III

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H271May cause fire or explosion; strong oxidiser

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 35603
Product name: (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Purity: ≥97.0% (T)
Packaging: 5G
Price: $282
Updated: 2024/03/01

Sigma-Aldrich

Product number: 35603
Product name: (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Purity: ≥97.0% (T)
Packaging: 25g
Price: $1210
Updated: 2024/03/01

TRC

Product number: D433990
Product name: (+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine
Packaging: 1g
Price: $165
Updated: 2021/12/16

TRC

Product number: D433990
Product name: (+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: D433990
Product name: (+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine
Packaging: 5g
Price: $385
Updated: 2021/12/16

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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

Chiral oxidizing agent.

Purification Methods

Recrystallise the enantiomers from EtOH [Davis & Weismiller J Org Chem 55 3715 1990].

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Suppliers

Canada 1 China 65 France 1 Germany 1 India 2 Switzerland 2 United Kingdom 3 United States 13 Global 88

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Sigma-Aldrich

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View Lastest Price from (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine >=97.0% (T) 127184-05-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE 127184-05-8
Price: US $1.00/kg
Min. Order: 1kg
Purity: 95%-99%
Supply Ability: 10kg
Release date: 2018-12-18

127184-05-8, (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridineRelated Search:

(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE 2-CHLOROCYCLOHEXANOL (-)-MENTHYL CHLORIDE Borneol oil Aminomethylcyclopentane hydrochloride 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-AMINE HYDROCHLORIDE BORNYLAMINE DL-Isoborneol (2R)-Bornane-10,2-sultam 1,1-DICHLORO-3,3-DIMETHYLBUTANE N-CYCLOHEXYLHYDROXYLAMINE HYDROCHLORIDE (1S)-(-)-10-MERCAPTOBORNEOL EXO-(1R)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-AMINE HYDROCHLORIDE CYCLOPENTYMETHYL HYDROXYAMINE HYDROCHLORIDE ISOTHIAZOLINE 1,1-DIOXIDE N-CYCLOHEXYLHYDROXYLAMINE 1-CHLORO-3,3-DIMETHYLPENTANE 5-CHLOROPENTYLAMINE

(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE

(+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM

4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, 8,8-dichlorotetrahydro-9,9-dimethyl-, 3,3-dioxide, (2R,4aS,7S,8aR)-

(+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%

[2R-(2α,4aα,7α,8aR*)]-8,8-Dichlorotetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide

(+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T)

(4aS,7S,8aR)-8,8-dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide

(1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione

8AR)-8

8-Dichlorocamphorylsulfonyl)oxaziri dine

(+)-8

(4aS,7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine

127184-05-8

C10H13Cl2NO3S

Hydroxylation

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Heterocycles

Miscellaneous Reagents