ChemicalBook > CAS DataBase List > (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine

Product Name
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
CAS No.
127184-05-8
Chemical Name
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Synonyms
(+)-8;8AR)-8;8-Dichlorocamphorylsulfonyl)oxaziri dine;(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE;(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine;(+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%;(+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T);(1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione;(4aS,7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
CBNumber
CB1690604
Molecular Formula
C10H13Cl2NO3S
Formula Weight
298.19
MOL File
127184-05-8.mol
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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Property

Melting point:
181-186 °C
Boiling point:
390.5±52.0 °C(Predicted)
Density 
1.68±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
-15.63±0.60(Predicted)
color 
White to Off-White
optical activity
[α]20/D +89±3°, c = 0.5% in chloroform
BRN 
3653352
InChI
InChI=1/C10H13Cl2NO3S/c1-7(2)6-3-4-8(7)5-17(14,15)13-10(8,16-13)9(6,11)12/h6H,3-5H2,1-2H3/t6-,8-,10+,13?/s3
InChIKey
HAMBQYFZDBYWHU-XCDSEQPNNA-N
SMILES
[C@@]123ON1S(=O)(=O)C[C@@]12CC[C@@]([H])(C1(C)C)C3(Cl)Cl |&1:0,7,10,r|
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Safety

Safety Statements 
22-24/25
RIDADR 
1479
WGK Germany 
3
F 
8-10
HazardClass 
5.1
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H271May cause fire or explosion; strong oxidiser

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
35603
Product name
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Purity
≥97.0% (T)
Packaging
5G
Price
$282
Updated
2024/03/01
Sigma-Aldrich
Product number
35603
Product name
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
Purity
≥97.0% (T)
Packaging
25g
Price
$1210
Updated
2024/03/01
TRC
Product number
D433990
Product name
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine
Packaging
1g
Price
$165
Updated
2021/12/16
TRC
Product number
D433990
Product name
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine
Packaging
100mg
Price
$60
Updated
2021/12/16
TRC
Product number
D433990
Product name
(+)-[(8,8-Dichlorocamphoryl)sulfonyl]oxaziridine
Packaging
5g
Price
$385
Updated
2021/12/16
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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

Chiral oxidizing agent.

Purification Methods

Recrystallise the enantiomers from EtOH [Davis & Weismiller J Org Chem 55 3715 1990].

(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine Suppliers

Canada 1 China 65 France 1 Germany 1 India 2 Switzerland 2 United Kingdom 3 United States 13 Global 88
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
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View Lastest Price from (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine >=97.0% (T) 127184-05-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE 127184-05-8
Price
US $1.00/kg
Min. Order
1kg
Purity
95%-99%
Supply Ability
10kg
Release date
2018-12-18

127184-05-8, (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridineRelated Search:

(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE 2-CHLOROCYCLOHEXANOL (-)-MENTHYL CHLORIDE Borneol oil Aminomethylcyclopentane hydrochloride 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-AMINE HYDROCHLORIDE BORNYLAMINE DL-Isoborneol (2R)-Bornane-10,2-sultam 1,1-DICHLORO-3,3-DIMETHYLBUTANE N-CYCLOHEXYLHYDROXYLAMINE HYDROCHLORIDE (1S)-(-)-10-MERCAPTOBORNEOL EXO-(1R)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-AMINE HYDROCHLORIDE CYCLOPENTYMETHYL HYDROXYAMINE HYDROCHLORIDE ISOTHIAZOLINE 1,1-DIOXIDE N-CYCLOHEXYLHYDROXYLAMINE 1-CHLORO-3,3-DIMETHYLPENTANE 5-CHLOROPENTYLAMINE

  • (+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE
  • (+)-3,3-DICHLORO-2,N-EPOXY-EXO-10,2-BORNANESULTAM
  • 4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, 8,8-dichlorotetrahydro-9,9-dimethyl-, 3,3-dioxide, (2R,4aS,7S,8aR)-
  • (+)-[(8,8-DICHLOROCAMPHORYL)-SULFONYL]-OXAZIRIDINE 97+%
  • [2R-(2α,4aα,7α,8aR*)]-8,8-Dichlorotetrahydro-9,9-diMethyl-4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-Dioxide
  • (+)-(8,8-DichlorocaMphorylsulfonyl)oxaziridine >=97.0% (T)
  • (4aS,7S,8aR)-8,8-dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
  • (1S,6R,8S)-7,7-dichloro-11,11-dimethyl-5-oxa-3λ?-thia-4-azatetracyclo[6.2.1.01,?.0?,?]undecane-3,3-dione
  • 8AR)-8
  • 8-Dichlorocamphorylsulfonyl)oxaziri dine
  • (+)-8
  • (4aS,7S)-8,8-Dichloro-9,9-dimethyltetrahydro-4H-4a,7-methanobenzo[c][1,2]oxazireno[2,3-b]isothiazole 3,3-dioxide
  • (+)-(8,8-Dichlorocamphorylsulfonyl)oxaziridine
  • 127184-05-8
  • C10H13Cl2NO3S
  • Hydroxylation
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Heterocycles
  • Miscellaneous Reagents