4-(bromomethyl)benzaldehyde
- Product Name
- 4-(bromomethyl)benzaldehyde
- CAS No.
- 51359-78-5
- Chemical Name
- 4-(bromomethyl)benzaldehyde
- Synonyms
- α-Bromo-p-Tolualdehyde;4-(BROMOMETHYL)BENZALDEHYDE;Benzaldehyde,4-(broMoMethyl)-;4-(Bromomethyl)benzaldehyde97%;4-(Bromomethyl)benzaldehyde 97%;4-Formylbenzyl bromide, alpha-Bromo-4-formyltoluene
- CBNumber
- CB1708152
- Molecular Formula
- C8H7BrO
- Formula Weight
- 199.04
- MOL File
- 51359-78-5.mol
4-(bromomethyl)benzaldehyde Property
- Melting point:
- 99 °C
- Boiling point:
- 277.9±15.0 °C(Predicted)
- Density
- 1.524±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystalline powder
- color
- Pale lemon
- CAS DataBase Reference
- 51359-78-5
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- B694635
- Product name
- 4-(Bromomethyl)benzaldehyde
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FB10749
- Product name
- 4-(Bromomethyl)benzaldehyde
- Packaging
- 100mg
- Price
- $50
- Updated
- 2021/12/16
- Product number
- FB10749
- Product name
- 4-(Bromomethyl)benzaldehyde
- Packaging
- 250mg
- Price
- $80
- Updated
- 2021/12/16
- Product number
- OR9193
- Product name
- 4-(Bromomethyl)benzaldehyde
- Purity
- 97%
- Packaging
- 1g
- Price
- $87
- Updated
- 2021/12/16
- Product number
- FB10749
- Product name
- 4-(Bromomethyl)benzaldehyde
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
4-(bromomethyl)benzaldehyde Chemical Properties,Usage,Production
Synthesis
4-(bromomethyl) benzonitrile (1 g, 5.1 mmol) was dissolved in 10 mL of dry toluene and cooled at 0 oC and a portion of 1.08 M DIBALH in hexane (2 equiv.) was added dropwise under nitrogen atmosphere. The solution was stirred for 1 h at 0 oC. The reaction mixture was first diluted with chloroform (15 mL) followed by 34 mL of 10% HCl, and the solution was stirred at room temperature for another 1 h. The organic layer separated was washed with distilled water and dried over anhydrous Na2SO4. The solvent was almost completely removed from the filtrate under reduced pressure, and the residue was washed with ice-cold n-hexane and dried at 50 oC under vacuum to afford 4-(bromomethyl)benzaldehyde. Yield: 70%; 1 H NMR (300 MHz, CDCl3, TMS): δ = 10.02 (s, 1H), 7.86 (m, 2H), 7.57 (m, 2H), 4.52 (s, 2H) ppm[1].
References
[1] Sandeep, Anjamkudy et al. “Supercoiled fibres of self-sorted donor–acceptor stacks: a turn-off/turn-on platform for sensing volatile aromatic compounds?.” Chemical Science 7 (2016): 4460–4467.
4-(bromomethyl)benzaldehyde Preparation Products And Raw materials
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View Lastest Price from 4-(bromomethyl)benzaldehyde manufacturers
- Product
- 4-bromomethylbenzaldehyde 51359-78-5
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-19
- Product
- 4-(BROMOMETHYL)BENZALDEHYDE 51359-78-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-26