METHYL-2-BROMO-4-BROMOMETHYLBENZOATE
- Product Name
- METHYL-2-BROMO-4-BROMOMETHYLBENZOATE
- CAS No.
- 128577-48-0
- Chemical Name
- METHYL-2-BROMO-4-BROMOMETHYLBENZOATE
- Synonyms
- CAS:128577-48-0;Methyl 2-bromo-4-(bromomethyl);METHYL-2-BROMO-4-BROMOMETHYLBENZOATE;Benzoic acid, 2-bromo-4-(bromomethyl)-, methyl ester
- CBNumber
- CB3491995
- Molecular Formula
- C9H8Br2O2
- Formula Weight
- 307.97
- MOL File
- 128577-48-0.mol
METHYL-2-BROMO-4-BROMOMETHYLBENZOATE Property
- Melting point:
- 53 - 56°C
- Boiling point:
- 340.3±32.0 °C(Predicted)
- Density
- 1.780±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Chloroform (Slightly), Ethyl Acetate (Soluble)
- form
- Solid
- color
- White to Off-White
- Stability:
- Hygroscopic, Moisture Sensitive
- InChI
- InChI=1S/C9H8Br2O2/c1-13-9(12)7-3-2-6(5-10)4-8(7)11/h2-4H,5H2,1H3
- InChIKey
- ZTDXOVAPGGNGSD-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C(CBr)C=C1Br
Safety
- HS Code
- 2916399090
N-Bromosuccinimide Price
- Product number
- M296273
- Product name
- Methyl-2-bromo-4-bromomethylbenzoate
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M296273
- Product name
- Methyl-2-bromo-4-bromomethylbenzoate
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- M296273
- Product name
- Methyl-2-bromo-4-bromomethylbenzoate
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 456025
- Product name
- Methyl-2-bromo-4-bromomethylbenzoate
- Packaging
- 100mg
- Price
- $305
- Updated
- 2021/12/16
- Product number
- 119646
- Product name
- Methyl 2-bromo-4-(bromomethyl)benzoate
- Purity
- 95+%
- Packaging
- 5g
- Price
- $390
- Updated
- 2021/12/16
METHYL-2-BROMO-4-BROMOMETHYLBENZOATE Chemical Properties,Usage,Production
Synthesis
87808-49-9
128577-48-0
General procedure for the synthesis of methyl 2-bromo-4-bromomethylbenzoate from methyl 2-bromo-4-methylbenzoate: the reaction mixture was placed in a controlled microwave synthesizer of the model Biotage Initiator + SP Wave (power range 0-200 W, frequency 2.45 GHz, 60 W capped at steady state) and heated to 120 °C at 1 bar pressure for for several minutes. Upon completion of the reaction, the target product was isolated and purified by column chromatography using ethyl acetate-hexane gradient elution.
References
[1] Synlett, 2014, vol. 25, # 17, p. 2485 - 2487
[2] Patent: WO2016/89062, 2016, A2. Location in patent: Page/Page column 38; 39
[3] Patent: US2005/70584, 2005, A1. Location in patent: Page/Page column 24
[4] Patent: WO2008/124575, 2008, A1. Location in patent: Page/Page column 144
[5] Patent: WO2017/156165, 2017, A1. Location in patent: Paragraph 00504; 00505
METHYL-2-BROMO-4-BROMOMETHYLBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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