4-(bromomethyl)benzaldehyde

Product Name: 4-(bromomethyl)benzaldehyde
CAS No.: 51359-78-5
Chemical Name: 4-(bromomethyl)benzaldehyde
Synonyms: α-Bromo-p-Tolualdehyde;4-(BROMOMETHYL)BENZALDEHYDE;Benzaldehyde,4-(broMoMethyl)-;4-(Bromomethyl)benzaldehyde97%;4-(Bromomethyl)benzaldehyde 97%;4-Formylbenzyl bromide, alpha-Bromo-4-formyltoluene
CBNumber: CB1708152
Molecular Formula: C8H7BrO
Formula Weight: 199.04
MOL File: 51359-78-5.mol

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4-(bromomethyl)benzaldehyde Property

Melting point:: 99 °C
Boiling point:: 277.9±15.0 °C(Predicted)
Density: 1.524±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: crystalline powder
color: Pale lemon
CAS DataBase Reference: 51359-78-5

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Safety

Hazard Codes: C
Safety Statements: 24/25
Hazard Note: Corrosive
HS Code: 29142990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC

Product number: B694635
Product name: 4-(Bromomethyl)benzaldehyde
Packaging: 100mg
Price: $45
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB10749
Product name: 4-(Bromomethyl)benzaldehyde
Packaging: 100mg
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB10749
Product name: 4-(Bromomethyl)benzaldehyde
Packaging: 250mg
Price: $80
Updated: 2021/12/16

Apolloscientific

Product number: OR9193
Product name: 4-(Bromomethyl)benzaldehyde
Purity: 97%
Packaging: 1g
Price: $87
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB10749
Product name: 4-(Bromomethyl)benzaldehyde
Packaging: 500mg
Price: $130
Updated: 2021/12/16

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4-(bromomethyl)benzaldehyde Chemical Properties,Usage,Production

Synthesis

4-(bromomethyl) benzonitrile (1 g, 5.1 mmol) was dissolved in 10 mL of dry toluene and cooled at 0 oC and a portion of 1.08 M DIBALH in hexane (2 equiv.) was added dropwise under nitrogen atmosphere. The solution was stirred for 1 h at 0 oC. The reaction mixture was first diluted with chloroform (15 mL) followed by 34 mL of 10% HCl, and the solution was stirred at room temperature for another 1 h. The organic layer separated was washed with distilled water and dried over anhydrous Na2SO4. The solvent was almost completely removed from the filtrate under reduced pressure, and the residue was washed with ice-cold n-hexane and dried at 50 oC under vacuum to afford 4-(bromomethyl)benzaldehyde. Yield: 70%; 1 H NMR (300 MHz, CDCl3, TMS): δ = 10.02 (s, 1H), 7.86 (m, 2H), 7.57 (m, 2H), 4.52 (s, 2H) ppm[1].

References

[1] Sandeep, Anjamkudy et al. “Supercoiled fibres of self-sorted donor–acceptor stacks: a turn-off/turn-on platform for sensing volatile aromatic compounds?.” Chemical Science 7 (2016): 4460–4467.

4-(bromomethyl)benzaldehyde Preparation Products And Raw materials

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View Lastest Price from 4-(bromomethyl)benzaldehyde manufacturers

henan kanbei chemical co.,ltd

Product: 4-bromomethylbenzaldehyde 51359-78-5
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-09-19

Career Henan Chemical Co

Product: 4-(BROMOMETHYL)BENZALDEHYDE 51359-78-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kg
Release date: 2019-12-26

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51359-78-5

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Phenyls & Phenyl-Het

Methyl Halides

Phenyls & Phenyl-Het