METHYL 2-BROMO-4-METHYLBENZOATE
- Product Name
- METHYL 2-BROMO-4-METHYLBENZOATE
- CAS No.
- 87808-49-9
- Chemical Name
- METHYL 2-BROMO-4-METHYLBENZOATE
- Synonyms
- RARECHEM AL BF 0916;2-bromo-4-methylbenzoate;Methyl2-Bromo-4-Methylbenzoat;METHYL 2-BROMO-4-METHYLBENZOATE;Methyl2-bromo-4-methylbenzoate,98%;Benzoic acid, 2-bromo-4-methyl-, methyl ester
- CBNumber
- CB3473892
- Molecular Formula
- C9H9BrO2
- Formula Weight
- 229.07
- MOL File
- 87808-49-9.mol
METHYL 2-BROMO-4-METHYLBENZOATE Property
- Boiling point:
- 161-164 °C(Press: 32 Torr)
- Density
- 1.433±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- form
- Solid
- Appearance
- Colorless to off-white Solid-liquid mixture
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 075331
- Product name
- Methyl 2-bromo-4-methylbenzoate
- Packaging
- 25.00g
- Price
- $46
- Updated
- 2026/05/18
- Product number
- 075331
- Product name
- Methyl 2-bromo-4-methylbenzoate
- Packaging
- 100.00g
- Price
- $133
- Updated
- 2026/05/18
- Product number
- 075331
- Product name
- Methyl 2-bromo-4-methylbenzoate
- Packaging
- 500.00g
- Price
- $667
- Updated
- 2026/05/18
- Product number
- M51893
- Product name
- Methyl 2-bromo-4-methylbenzoate
- Purity
- 98%
- Packaging
- 1g
- Price
- $24
- Updated
- 2026/05/06
- Product number
- M51893
- Product name
- Methyl 2-bromo-4-methylbenzoate
- Purity
- 98%
- Packaging
- 5g
- Price
- $28
- Updated
- 2026/05/06
METHYL 2-BROMO-4-METHYLBENZOATE Chemical Properties,Usage,Production
Chemical Properties
off-white powder
Synthesis
67-56-1
7697-27-0
87808-49-9
The general procedure for the synthesis of methyl 2-bromo-4-methylbenzoate from methanol and 2-bromo-4-methylbenzoic acid was as follows: concentrated sulfuric acid (4 mL) was slowly added to an anhydrous methanol (200 mL) solution of 2-bromo-4-methylbenzoic acid (10.0 g, 46.5 mmol). The reaction mixture was heated to reflux for 18 hours. After completion of the reaction, it was cooled to room temperature and the reaction mixture was concentrated. The residue was partitioned between water and ethyl acetate for extraction. After separating the organic and aqueous layers, the aqueous layer was then extracted with ethyl acetate (3 x 100 mL). All organic extracts were combined and washed sequentially with saturated sodium bicarbonate solution (2 x 50 mL) and brine, followed by drying with anhydrous magnesium sulfate. After filtration to remove the desiccant, the filtrate was concentrated to afford methyl 2-bromo-4-methylbenzoate (10.50 g, 99% yield), the product was a light amber colored oil. Mass spectrometry (MS) analysis showed m/z of 229.2 (M+H+).
References
[1] Patent: WO2008/124575, 2008, A1. Location in patent: Page/Page column 144
[2] Patent: WO2014/8197, 2014, A1. Location in patent: Page/Page column 163
[3] Patent: WO2015/95767, 2015, A1. Location in patent: Page/Page column 178
[4] Antimicrobial Agents and Chemotherapy, 2016, vol. 60, # 7, p. 3980 - 3987
[5] Patent: US2005/70584, 2005, A1. Location in patent: Page/Page column 23; 24
METHYL 2-BROMO-4-METHYLBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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