3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER

Uses

Product Name: 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
CAS No.: 99548-54-6
Chemical Name: 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
Synonyms: METHYL 3-BROMO-2-METHYLBENZOATE;Methyl 3-Bromo-o-toluate;3-BroMo-o-toluic Acid Methyl Ester;3-BroMo-2-Methyl-benzoic acid Methy;Methyl 3-bromo-2-methylbenzoate 97%;3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-broMo-2-Methyl-, Methyl ester;Methyl 3-bromo-o-toluate, 2-Bromo-6-(methoxycarbonyl)toluene;Methyl 3-bromo-2-methylbenzoate , Methyl 3-bromo-2-methylbenzoate
CBNumber: CB7847693
Molecular Formula: C9H9BrO2
Formula Weight: 229.07
MOL File: 99548-54-6.mol

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3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Property

Melting point:: 29 °C
Boiling point:: 140°C/21mmHg(lit.)
Density: 1.433±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
solubility: Chloroform
form: Solid
color: White
InChI: InChI=1S/C9H9BrO2/c1-6-7(9(11)12-2)4-3-5-8(6)10/h3-5H,1-2H3
InChIKey: MKQQTCSBXHAYQL-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=CC(Br)=C1C

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2543
Product name: Methyl 3-Bromo-2-methylbenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $110
Updated: 2025/07/31

TCI Chemical

Product number: M2543
Product name: Methyl 3-Bromo-2-methylbenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $328
Updated: 2025/07/31

TRC

Product number: B685285
Product name: 3-Bromo-2-methylbenzoicAcidMethylEster
Packaging: 5G
Price: $1175
Updated: 2021/12/16

Oakwood

Product number: 233481
Product name: Methyl 3-Bromo-2-methylbenzoate
Purity: 98%
Packaging: 1g
Price: $10
Updated: 2021/12/16

ChemScene

Product number: CS-W005509
Product name: Methyl 3-Bromo-2-methylbenzoate
Purity: 99.87%
Packaging: 5g
Price: $22
Updated: 2021/12/16

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3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Uses

3-Bromo-2-methylbenzoic Acid Methyl Ester is a compound useful in organic synthesis.

Chemical Properties

White Solid

Synthesis

76006-33-2

74-88-4

99548-54-6

3-Bromo-2-methylbenzoic acid (16 g, 74.4 mmol) and iodomethane (21.2 g, 148.8 mmol) were reacted in DMF (160 mL) in the presence of sodium bicarbonate (12.5 g, 148.8 mmol). The reaction mixture was heated and stirred at 60 °C for 2 hours. After the reaction was completed, the mixture was cooled to room temperature and slowly poured into ice water (400 mL). The aqueous phase was extracted with ethyl acetate (4 x 100 mL) and the organic phases were combined. The organic phase was washed sequentially with water (3 x 100 mL) and saturated saline (100 mL) and then dried with anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give methyl 3-bromo-2-methylbenzoate (17.6 g, 100% yield) as an oil. The product was characterized by 1H NMR (CDCl3): δ 7.70 (t, J = 7.6 Hz, 2H), 7.08 (t, J = 7.9 Hz, 1H), 3.90 (s, 3H), 2.67 (s, 3H).

References

[1] Patent: US2003/96841, 2003, A1
[2] Patent: US2014/179667, 2014, A1. Location in patent: Paragraph 0802; 0803
[3] Patent: WO2008/65199, 2008, A1. Location in patent: Page/Page column 74

3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Suppliers

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View Lastest Price from 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co

Product: 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER 99548-54-6
Price: US $1.00/g
Min. Order: 1g
Purity: 99%
Supply Ability: 10000KGS
Release date: 2020-01-10

99548-54-6, 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTERRelated Search:

METHYL 2-BROMO-5-METHYLBENZOATE Ethyl 2-methyl-3-nitrobenzoate 4-AMINO-2-METHYLBENZOIC ACID ETHYL ESTER Methyl 2-Methyl-4-nitrobenzoate ETHYL 2-AMINO-5-METHYLBENZOATE Methyl 4-hydroxy-2-methylbenzoate 7-Chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylic Acid Ethyl Ester BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER METHYL 2-AMINO-5-METHYLBENZOATE AKOS BB-3093 Methyl-5-amino-2-chlorobenzoate Ethyl 3-bromo-4-methylbenzoate Methyl 5-Methyl-2-Nitrobenzoate 5-AMINO-2-METHYL-BENZOIC ACID METHYL ESTER ETHYL 3-METHYL-4-NITROBENZOATE METHYL 4-CHLORO-3-METHYLBENZOATE Methyl4-amino-2-methylbenzoate Ethyl 4-Bromo-3-methylbenzoate

3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER

METHYL 3-BROMO-2-METHYLBENZOATE

3-BroMo-o-toluic Acid Methyl Ester

Methyl 3-bromo-2-methylbenzoate 97%

Methyl 3-bromo-o-toluate, 2-Bromo-6-(methoxycarbonyl)toluene

3-BroMo-2-Methyl-benzoic acid Methy

Benzoic acid, 3-broMo-2-Methyl-, Methyl ester

Methyl 3-Bromo-o-toluate

Methyl 3-bromo-2-methylbenzoate , Methyl 3-bromo-2-methylbenzoate

99548-54-6

Aromatic Esters

Acids & Esters

Bromine Compounds

Aromatics

Miscellaneous Reagents