Methyl 2-Methyl-4-nitrobenzoate

Product Name: Methyl 2-Methyl-4-nitrobenzoate
CAS No.: 62621-09-4
Chemical Name: Methyl 2-Methyl-4-nitrobenzoate
Synonyms: Benzoic acid, 2-Methyl-4-nitro-, Methyl ester;Methyl 4-Nitro-o-toluate;Methyl 4-Nitro-2-Methylbenzoate;Methyl 2-Methyl-4-nitrobenzoate;Methyl2-Methyl-4-nitrobenzoate>4-Nitro-o-toluic Acid Methyl Ester;_x005f\rMethyl 2-Methyl-4-nitrobenzoate;2-Methyl-4-nitrobenzoic acid methyl ester;2-Pyridinecarboxylicacid,7-(trifluoromethyl)-
CBNumber: CB21513745
Molecular Formula: C9H9NO4
Formula Weight: 195.17
MOL File: 62621-09-4.mol

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Methyl 2-Methyl-4-nitrobenzoate Property

Melting point:: 74.0 to 78.0 °C
Boiling point:: 315.4±30.0 °C(Predicted)
Density: 1?+-.0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
solubility: soluble in Methanol
form: powder to crystal
color: White to Light yellow
InChI: InChI=1S/C9H9NO4/c1-6-5-7(10(12)13)3-4-8(6)9(11)14-2/h3-5H,1-2H3
InChIKey: JJHCLPDHYBSSHC-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C([N+]([O-])=O)C=C1C

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Safety

HS Code: 2916399090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical

Product number: M2545
Product name: Methyl 2-Methyl-4-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 5g
Price: $65
Updated: 2025/07/31

TCI Chemical

Product number: M2545
Product name: Methyl 2-Methyl-4-nitrobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $259
Updated: 2025/07/31

SynQuest Laboratories

Product number: 4754-1-0G
Product name: Methyl 4-nitro-2-methylbenzoate
Packaging: 5G
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4754-1-0G
Product name: Methyl 4-nitro-2-methylbenzoate
Packaging: 25g
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 083334
Product name: Methyl 2-methyl-4-nitrobenzoate
Purity: 97%
Packaging: 1g
Price: $82
Updated: 2021/12/16

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Methyl 2-Methyl-4-nitrobenzoate Chemical Properties,Usage,Production

Uses

methyl 2-methyl-4-nitrobenzoate is a useful research chemical.

Synthesis

67-56-1

1975-51-5

62621-09-4

General procedure for the synthesis of methyl 2-methyl-4-nitrobenzoate from methanol and 2-methyl-4-nitrobenzoic acid: 1. SOCl? was added slowly and dropwise to a methanolic solution of 2-methyl-4-nitrobenzoic acid (3 g, 16.5 mmol). 2. the reaction mixture was stirred continuously at 70 °C for 18 hours. 3. After completion of the reaction, the solvent was removed by evaporation and the residue was diluted with ether. 4. The ether phase was washed sequentially with water and 1N NaOH solution. 5. 5. The organic phase was dried with anhydrous Na?SO?, filtered and the solvent was evaporated to give methyl 2-methyl-4-nitrobenzoate as a dark yellow solid (3.25 g, quantitative yield). NMR data: 1H NMR (300 MHz, CDCl?) δ: 7.95 (m, 3H), 3.86 (s, 3H), 2.59 (s, 3H).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 942 - 945
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 946 - 949
[3] Patent: WO2009/47240, 2009, A1. Location in patent: Page/Page column 28
[4] Journal of Medicinal Chemistry, 1999, vol. 42, # 18, p. 3510 - 3519
[5] Patent: CN103804358, 2016, B. Location in patent: Paragraph 0117

Methyl 2-Methyl-4-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl 2-Methyl-4-nitrobenzoate Suppliers

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View Lastest Price from Methyl 2-Methyl-4-nitrobenzoate manufacturers

Career Henan Chemical Co

Product: Methyl 2-Methyl-4-nitrobenzoate 62621-09-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kgs
Release date: 2020-02-14

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Methyl 2-Methyl-4-nitrobenzoate

Benzoic acid, 2-Methyl-4-nitro-, Methyl ester

Methyl 4-Nitro-2-Methylbenzoate

2-Methyl-4-nitrobenzoic acid methyl ester

_x005f\rMethyl 2-Methyl-4-nitrobenzoate

Methyl2-Methyl-4-nitrobenzoate&gt

4-Nitro-o-toluic Acid Methyl Ester

Methyl 4-Nitro-o-toluate

2-Pyridinecarboxylicacid,7-(trifluoromethyl)-

62621-09-4

Esters

Phenyls & Phenyl-Het