METHYL 2-AMINO-5-METHYLBENZOATE
- Product Name
- METHYL 2-AMINO-5-METHYLBENZOATE
- CAS No.
- 18595-16-9
- Chemical Name
- METHYL 2-AMINO-5-METHYLBENZOATE
- Synonyms
- NSC 3109;SunaroMe UVA;Methyl 6-Amino-m-toluate;o-(Methoxycarbonyl)aniline;Methyl 5-methylanthranilate;METHYL 2-AMINO-5-METHYLBENZOATE;[2-(Methoxycarbonyl)phenyl]aMine;Methyl2-Amino-5-methylbenzoate>6-Amino-m-toluic Acid Methyl Ester;5-Methylanthranilic Acid Methyl Ester
- CBNumber
- CB3454611
- Molecular Formula
- C9H11NO2
- Formula Weight
- 165.19
- MOL File
- 18595-16-9.mol
METHYL 2-AMINO-5-METHYLBENZOATE Property
- Melting point:
- 54-56°C
- Density
- 1.132
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Dichloromethane, Ethyl Acetate, Methanol
- form
- Solid
- color
- Yellow to Brown
Safety
- HS Code
- 2922498590
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- M2541
- Product name
- Methyl 2-Amino-5-methylbenzoate
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $66
- Updated
- 2025/07/31
- Product number
- M2541
- Product name
- Methyl 2-Amino-5-methylbenzoate
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $224
- Updated
- 2025/07/31
- Product number
- 083304
- Product name
- Methyl 2-amino-5-methylbenzoate
- Purity
- 97%
- Packaging
- 1g
- Price
- $267
- Updated
- 2021/12/16
- Product number
- J94832
- Product name
- Methyl 2-Amino-5-methylbenzoate
- Packaging
- 5g
- Price
- $35
- Updated
- 2021/12/16
- Product number
- Z4332
- Product name
- Methyl 2-Amino-5-methylbenzoate
- Packaging
- 100g
- Price
- $440
- Updated
- 2021/12/16
METHYL 2-AMINO-5-METHYLBENZOATE Chemical Properties,Usage,Production
Chemical Properties
METHYL 2-AMINO-5-METHYLBENZOATE is yellow Solid
Uses
METHYL 2-AMINO-5-METHYLBENZOATE is a useful synthetic intermediate
Uses
A useful synthetic intermediate.
Synthesis
20587-30-8
18595-16-9
Methyl 5-methyl-2-nitrobenzoate (8 g, 41.025 mmol) was used as a raw material in a solvent mixture of methanol (80 mL) and water (10 mL), and cooled to 0 °C. Subsequently, zinc powder (13.33 g, 205.128 mmol) and NH4Cl (17.6 g, 328.2 mmol) were added sequentially. The reaction mixture was stirred at room temperature for 12 h. The reaction progress was monitored by TLC (unfolding agent: 20% ethyl acetate/hexane). After completion of the reaction, the mixture was filtered and the filtrate was evaporated to give the crude product. The crude product was alkalized with saturated NaHCO3 solution and extracted with dichloromethane (2 x 20 mL). The organic layers were combined, dried with Na2SO4, filtered and the solvent was evaporated to give the target compound methyl 2-amino-5-methylbenzoate (yield: 4 g, 60%).1H NMR (400 MHz, CDCl3) data were as follows: δ 7.65 (s, 1H), 7.25 (s, 1H), 7.10-7.07 (q, 1H, J=8Hz), 6.58 (d, 1H), 3.86 (s, 3H), 2.22 (s, 3H).
References
[1] Patent: WO2015/38417, 2015, A1. Location in patent: Paragraph 151; 152
[2] Journal of the Chemical Society, 1930, p. 1513,1516
[3] Bioorganic and Medicinal Chemistry Letters, 2009, vol. 19, # 15, p. 4416 - 4420
[4] Patent: EP1475368, 2004, A1. Location in patent: Page 57
METHYL 2-AMINO-5-METHYLBENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from METHYL 2-AMINO-5-METHYLBENZOATE manufacturers
- Product
- METHYL 2-AMINO-5-METHYLBENZOATE 18595-16-9
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-09
- Product
- METHYL 2-AMINO-5-METHYLBENZOATE 18595-16-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-12