BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

Product Name: BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER
CAS No.: 99548-55-7
Chemical Name: BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER
Synonyms: 4-BROMO-2-METHYL-,METHYL ESTER;4-BroMo-2-Methyl-benzoic acid Methyl ester;Methyl 2-methyl-4-bromobenzoate;2- Methyl-4-broMo benzoic acidMethyl ester;BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER
CBNumber: CB32456776
Molecular Formula: C9H9BrO2
Formula Weight: 229.07
MOL File: 99548-55-7.mol

More

Less

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Property

Melting point:: 9 °C
Boiling point:: 273.6±20.0 °C(Predicted)
Density: 1.433±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
Appearance: Colorless to light yellow Liquid
InChI: InChI=1S/C9H9BrO2/c1-6-5-7(10)3-4-8(6)9(11)12-2/h3-5H,1-2H3
InChIKey: CYEXEOXALMJXDI-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(Br)C=C1C

More

Less

Safety

HS Code: 2916399090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

TCI Chemical

Product number: M3630
Product name: Methyl 4-Bromo-2-methylbenzoate
Purity: min. 98.0 %
Packaging: 5G
Price: $93
Updated: 2025/07/31

TCI Chemical

Product number: M3630
Product name: Methyl 4-Bromo-2-methylbenzoate
Purity: min. 98.0 %
Packaging: 25G
Price: $279
Updated: 2025/07/31

TRC

Product number: M295845
Product name: Methyl4-Bromo-2-methylbenzoate
Packaging: 1g
Price: $55
Updated: 2021/12/16

Apolloscientific

Product number: OR51873
Product name: Methyl4-bromo-2-methylbenzoate
Packaging: 1g
Price: $66
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2723-9-30
Product name: Methyl 4-bromo-2-methylbenzoate
Packaging: 1g
Price: $72
Updated: 2021/12/16

More

Less

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Uses

Methyl 4-Bromo-2-methylbenzoate can be used as an organic synthesis intermediate and a pharmaceutical intermediate.

Synthesis

68837-59-2

18107-18-1

99548-55-7

Step 1: To a mixed solution of 4-bromo-2-methylbenzoic acid (15.1 g, 0.070 mol) in tetrahydrofuran (180 mL) and methanol (45 mL) was slowly added dropwise (trimethylsilyl) diazomethane in 2.0 M hexane solution (42 mL, 0.084 mol) at 0 °C. The reaction mixture was gradually warmed to room temperature and stirred continuously for 1 hour. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure to afford methyl 4-bromo-2-methylbenzoate (16 g, 100% yield) as a yellow oil. The crude product could be used in the subsequent reaction without further purification. The product was characterized as follows: 1H NMR (400 MHz, CDCl3): δ 7.78 (d, 1H), 7.42 (s, 1H), 7.38 (d, 1H), 3.88 (s, 3H), 2.58 (s, 3H). Mass spectrum (EI): m/z 230 ([M+H]+, C9H9BrO2).

References

[1] Bioorganic and Medicinal Chemistry Letters, 2005, vol. 15, # 4, p. 999 - 1004
[2] Patent: WO2009/55077, 2009, A1. Location in patent: Page/Page column 430
[3] Journal of Medicinal Chemistry, 2014, vol. 57, # 6, p. 2334 - 2356
[4] Patent: US2009/69370, 2009, A1. Location in patent: Page/Page column 17-18
[5] Patent: WO2009/158369, 2009, A1. Location in patent: Page/Page column 38; 39

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER Suppliers

China 168 Germany 1 India 4 Ukraine 2 United Kingdom 2 United States 16 Global 193

Shanghai Troedsson Technology Co., LTD

Tel: 18117455885
Email: qihongchem@163.com
Country: China
ProdList: 9092
Advantage: 58

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44801
Advantage: 61

Shijiazhuang Sdyano Fine Chemical Co., Ltd.

Tel: 0311-89250318 031166536426
Fax: 4000311741
Email: master@sjzsdyn.com
Country: China
ProdList: 2809
Advantage: 65

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
Country: China
ProdList: 9976
Advantage: 60

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9310
Advantage: 66

Tetranov Biopharm

Tel: 13526569071
Email: sales@leadmedpharm.com
Country: China
ProdList: 7892
Advantage: 64

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: chenyj@titansci.com
Country: China
ProdList: 14101
Advantage: 59

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Fax: 021-50795055
Email: sales@accelachem.com
Country: China
ProdList: 11035
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42934
Advantage: 64

More

Less

View Lastest Price from BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER manufacturers

Qingdao RENAS Polymer Material Co., Ltd.

Product: methyl 4-bromo-2-methylbenzoate 99548-55-7
Price: US $0.00/kg
Min. Order: 20kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2025-04-11

Henan Fengda Chemical Co., Ltd

Product: BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER 99548-55-7
Price: US $5.00-0.10/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-09

Honest Joy Holdings Limited

Product: Methyl 4-bromo-2-methylbenzoate 99548-55-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100 tons
Release date: 2022-01-14

99548-55-7, BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTERRelated Search:

METHYL 2-AMINO-5-METHYLBENZOATE 7-Chloro-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylic Acid Ethyl Ester Methyl 4-hydroxy-2-methylbenzoate ETHYL 2-AMINO-5-METHYLBENZOATE Methyl 2-Methyl-4-nitrobenzoate 4-AMINO-2-METHYLBENZOIC ACID ETHYL ESTER Ethyl 2-methyl-3-nitrobenzoate METHYL 2-BROMO-5-METHYLBENZOATE AKOS BB-3093 Methyl-5-amino-2-chlorobenzoate Ethyl 3-bromo-4-methylbenzoate Methyl 5-Methyl-2-Nitrobenzoate 5-AMINO-2-METHYL-BENZOIC ACID METHYL ESTER ETHYL 3-METHYL-4-NITROBENZOATE METHYL 4-CHLORO-3-METHYLBENZOATE 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Methyl4-amino-2-methylbenzoate Ethyl 4-Bromo-3-methylbenzoate

Methyl 2-methyl-4-bromobenzoate

4-BroMo-2-Methyl-benzoic acid Methyl ester

BENZOIC ACID,4-BROMO-2-METHYL-,METHYL ESTER

2- Methyl-4-broMo benzoic acidMethyl ester

4-BROMO-2-METHYL-,METHYL ESTER

99548-55-7