Methyl 5-Methyl-2-Nitrobenzoate
- Product Name
- Methyl 5-Methyl-2-Nitrobenzoate
- CAS No.
- 20587-30-8
- Chemical Name
- Methyl 5-Methyl-2-Nitrobenzoate
- Synonyms
- Methyl 6-nitro-m-toluate;5-Methyl-2-Nitrobenzoate Methyl;Methyl 5-Methyl-2-Nitrobenzoate;6-Nitro-m-toluic Acid Methyl Ester;Methyl 5-Methyl-2-nitrobenzoate >5-Methyl-2-nitrobenzoic acid methyl ester;Benzoic acid, 5-methyl-2-nitro-, methyl ester;5-methyl-2-nitrobenzoic acid methyl ester 90%;2-(Ethoxycarbonyl)-4-methylnitrobenzene, 3-(Ethoxycarbonyl)-4-nitrotoluene;2-(Methoxycarbonyl)-4-methylnitrobenzene, 3-(Methoxycarbonyl)-4-nitrotoluene
- CBNumber
- CB51564263
- Molecular Formula
- C9H9NO4
- Formula Weight
- 195.17
- MOL File
- 20587-30-8.mol
Methyl 5-Methyl-2-Nitrobenzoate Property
- Melting point:
- 77-79℃
- Boiling point:
- 305.1±22.0 °C(Predicted)
- Density
- 1.255
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- powder to crystal
- color
- White to Almost white
- InChIKey
- KFOICDVZQKFCGM-UHFFFAOYSA-N
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- S914665
- Product name
- METHYL 5-METHYL-2-NITROBENZOATE
- Purity
- Aldrich<sup>CPR</sup>
- Packaging
- 1 unit
- Price
- $113
- Updated
- 2025/07/31
- Product number
- S914665
- Product name
- METHYL 5-METHYL-2-NITROBENZOATE
- Purity
- Aldrich
- Packaging
- 250mg
- Price
- $110
- Updated
- 2024/03/01
- Product number
- M2544
- Product name
- Methyl 5-Methyl-2-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $36
- Updated
- 2025/07/31
- Product number
- M2544
- Product name
- Methyl 5-Methyl-2-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $119
- Updated
- 2025/07/31
- Product number
- B451623
- Product name
- METHYL 5-METHYL-2-NITROBENZOATE
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
Methyl 5-Methyl-2-Nitrobenzoate Chemical Properties,Usage,Production
Synthesis
67-56-1
3113-72-2
20587-30-8
5-Methyl-2-nitrobenzoic acid (8 g, 44.198 mmol) was dissolved in methanol (80 mL) and the solution was cooled to 0°C. Sulfuric acid (5 mL) was added slowly and dropwise with stirring. Subsequently, the reaction mixture was heated to 90 °C and stirred continuously at this temperature for 16 hours. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent 50% ethyl acetate/hexane). After completion of the reaction, excess methanol was removed by distillation under reduced pressure. The residue was poured into water (150 mL) and extracted with ethyl acetate (150 mL x 2). The organic phases were combined and washed sequentially with saturated sodium bicarbonate solution (50 mL x 2) and brine (20 mL). The organic layer was dried over anhydrous sodium sulfate, filtered and concentrated to afford methyl 5-methyl-2-nitrobenzoate (yield: 8 g, 93%). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 7.86-7.84 (d, 1H, J = 8Hz), 7.48 (s, 1H), 7.40-7.38 (d, 1H, J = 8Hz), 3.91 (s, 3H), 3.47 (s, 3H).
References
[1] Journal of Heterocyclic Chemistry, 1984, vol. 21, p. 1807 - 1816
[2] Patent: WO2015/38417, 2015, A1. Location in patent: Paragraph 151
[3] Bulletin of the Korean Chemical Society, 2011, vol. 32, # 12, p. 4309 - 4315
[4] Bioorganic and Medicinal Chemistry, 2006, vol. 14, # 7, p. 2209 - 2224
[5] Chemische Berichte, 1909, vol. 42, p. 433
Methyl 5-Methyl-2-Nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Methyl 5-Methyl-2-Nitrobenzoate manufacturers
- Product
- methyl 5-methyl-2-nitrobenzoate 20587-30-8
- Price
- US $0.00/kg
- Min. Order
- 10kg
- Purity
- 99%
- Supply Ability
- 10 tons
- Release date
- 2025-05-12
- Product
- Methyl 5-Methyl-2-Nitrobenzoate 20587-30-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100KG
- Release date
- 2020-01-03