Methyl 2-Methyl-4-nitrobenzoate
- Product Name
- Methyl 2-Methyl-4-nitrobenzoate
- CAS No.
- 62621-09-4
- Chemical Name
- Methyl 2-Methyl-4-nitrobenzoate
- Synonyms
- Benzoic acid, 2-Methyl-4-nitro-, Methyl ester;Methyl 4-Nitro-o-toluate;Methyl 4-Nitro-2-Methylbenzoate;Methyl 2-Methyl-4-nitrobenzoate;Methyl2-Methyl-4-nitrobenzoate>4-Nitro-o-toluic Acid Methyl Ester;_x005f\rMethyl 2-Methyl-4-nitrobenzoate;2-Methyl-4-nitrobenzoic acid methyl ester;2-Pyridinecarboxylicacid,7-(trifluoromethyl)-
- CBNumber
- CB21513745
- Molecular Formula
- C9H9NO4
- Formula Weight
- 195.17
- MOL File
- 62621-09-4.mol
Methyl 2-Methyl-4-nitrobenzoate Property
- Melting point:
- 74.0 to 78.0 °C
- Boiling point:
- 315.4±30.0 °C(Predicted)
- Density
- 1?+-.0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- form
- powder to crystal
- color
- White to Light yellow
- InChI
- InChI=1S/C9H9NO4/c1-6-5-7(10(12)13)3-4-8(6)9(11)14-2/h3-5H,1-2H3
- InChIKey
- JJHCLPDHYBSSHC-UHFFFAOYSA-N
- SMILES
- C(OC)(=O)C1=CC=C([N+]([O-])=O)C=C1C
Safety
- HS Code
- 2916399090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M2545
- Product name
- Methyl 2-Methyl-4-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $65
- Updated
- 2025/07/31
- Product number
- M2545
- Product name
- Methyl 2-Methyl-4-nitrobenzoate
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $259
- Updated
- 2025/07/31
- Product number
- 083334
- Product name
- Methyl 2-methyl-4-nitrobenzoate
- Purity
- 97%
- Packaging
- 5g
- Price
- $240
- Updated
- 2021/12/16
- Product number
- 4754-1-0G
- Product name
- Methyl 4-nitro-2-methylbenzoate
- Packaging
- 100g
- Price
- $250
- Updated
- 2021/12/16
- Product number
- 4754-1-0G
- Product name
- Methyl 4-nitro-2-methylbenzoate
- Packaging
- 25g
- Price
- $75
- Updated
- 2021/12/16
Methyl 2-Methyl-4-nitrobenzoate Chemical Properties,Usage,Production
Uses
methyl 2-methyl-4-nitrobenzoate is a useful research chemical.
Synthesis
67-56-1
1975-51-5
62621-09-4
General procedure for the synthesis of methyl 2-methyl-4-nitrobenzoate from methanol and 2-methyl-4-nitrobenzoic acid: 1. SOCl? was added slowly and dropwise to a methanolic solution of 2-methyl-4-nitrobenzoic acid (3 g, 16.5 mmol). 2. the reaction mixture was stirred continuously at 70 °C for 18 hours. 3. After completion of the reaction, the solvent was removed by evaporation and the residue was diluted with ether. 4. The ether phase was washed sequentially with water and 1N NaOH solution. 5. 5. The organic phase was dried with anhydrous Na?SO?, filtered and the solvent was evaporated to give methyl 2-methyl-4-nitrobenzoate as a dark yellow solid (3.25 g, quantitative yield). NMR data: 1H NMR (300 MHz, CDCl?) δ: 7.95 (m, 3H), 3.86 (s, 3H), 2.59 (s, 3H).
References
[1] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 942 - 945
[2] Bioorganic and Medicinal Chemistry Letters, 2008, vol. 18, # 3, p. 946 - 949
[3] Patent: WO2009/47240, 2009, A1. Location in patent: Page/Page column 28
[4] Journal of Medicinal Chemistry, 1999, vol. 42, # 18, p. 3510 - 3519
[5] Patent: CN103804358, 2016, B. Location in patent: Paragraph 0117
Methyl 2-Methyl-4-nitrobenzoate Preparation Products And Raw materials
Raw materials
Preparation Products
Methyl 2-Methyl-4-nitrobenzoate Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from Methyl 2-Methyl-4-nitrobenzoate manufacturers
- Product
- Methyl 2-Methyl-4-nitrobenzoate 62621-09-4
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kgs
- Release date
- 2020-02-14