Uses
ChemicalBook > CAS DataBase List > 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER

3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER

Uses
Product Name
3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
CAS No.
99548-54-6
Chemical Name
3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
Synonyms
METHYL 3-BROMO-2-METHYLBENZOATE;Methyl 3-Bromo-o-toluate;3-BroMo-o-toluic Acid Methyl Ester;3-BroMo-2-Methyl-benzoic acid Methy;Methyl 3-bromo-2-methylbenzoate 97%;3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER;Benzoic acid, 3-broMo-2-Methyl-, Methyl ester;Methyl 3-bromo-o-toluate, 2-Bromo-6-(methoxycarbonyl)toluene;Methyl 3-bromo-2-methylbenzoate , Methyl 3-bromo-2-methylbenzoate
CBNumber
CB7847693
Molecular Formula
C9H9BrO2
Formula Weight
229.07
MOL File
99548-54-6.mol
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3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Property

Melting point:
29 °C
Boiling point:
140°C/21mmHg(lit.)
Density 
1.433±0.06 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform
form 
Solid
color 
White
InChI
InChI=1S/C9H9BrO2/c1-6-7(9(11)12-2)4-3-5-8(6)10/h3-5H,1-2H3
InChIKey
MKQQTCSBXHAYQL-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC(Br)=C1C
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2543
Product name
Methyl 3-Bromo-2-methylbenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$110
Updated
2025/07/31
TCI Chemical
Product number
M2543
Product name
Methyl 3-Bromo-2-methylbenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$328
Updated
2025/07/31
TRC
Product number
B685285
Product name
3-Bromo-2-methylbenzoicAcidMethylEster
Packaging
5G
Price
$1175
Updated
2021/12/16
Oakwood
Product number
233481
Product name
Methyl 3-Bromo-2-methylbenzoate
Purity
98%
Packaging
1g
Price
$10
Updated
2021/12/16
ChemScene
Product number
CS-W005509
Product name
Methyl 3-Bromo-2-methylbenzoate
Purity
99.87%
Packaging
5g
Price
$22
Updated
2021/12/16
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3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Chemical Properties,Usage,Production

Uses

3-Bromo-2-methylbenzoic Acid Methyl Ester is a compound useful in organic synthesis.

Chemical Properties

White Solid

Synthesis

76006-33-2

74-88-4

99548-54-6

3-Bromo-2-methylbenzoic acid (16 g, 74.4 mmol) and iodomethane (21.2 g, 148.8 mmol) were reacted in DMF (160 mL) in the presence of sodium bicarbonate (12.5 g, 148.8 mmol). The reaction mixture was heated and stirred at 60 °C for 2 hours. After the reaction was completed, the mixture was cooled to room temperature and slowly poured into ice water (400 mL). The aqueous phase was extracted with ethyl acetate (4 x 100 mL) and the organic phases were combined. The organic phase was washed sequentially with water (3 x 100 mL) and saturated saline (100 mL) and then dried with anhydrous magnesium sulfate. The solvent was removed by concentration under reduced pressure to give methyl 3-bromo-2-methylbenzoate (17.6 g, 100% yield) as an oil. The product was characterized by 1H NMR (CDCl3): δ 7.70 (t, J = 7.6 Hz, 2H), 7.08 (t, J = 7.9 Hz, 1H), 3.90 (s, 3H), 2.67 (s, 3H).

References

[1] Patent: US2003/96841, 2003, A1
[2] Patent: US2014/179667, 2014, A1. Location in patent: Paragraph 0802; 0803
[3] Patent: WO2008/65199, 2008, A1. Location in patent: Page/Page column 74

3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER Suppliers

Americas 1 Canada 1 China 144 Europe 1 India 8 Japan 1 United Kingdom 5 United States 16 Global 177
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23671
Advantage
75
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View Lastest Price from 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER manufacturers

Career Henan Chemical Co
Product
3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER 99548-54-6
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
10000KGS
Release date
2020-01-10

99548-54-6, 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTERRelated Search:

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  • 3-BROMO-2-METHYL-BENZOIC ACID METHYL ESTER
  • METHYL 3-BROMO-2-METHYLBENZOATE
  • 3-BroMo-o-toluic Acid Methyl Ester
  • Methyl 3-bromo-2-methylbenzoate 97%
  • Methyl 3-bromo-o-toluate, 2-Bromo-6-(methoxycarbonyl)toluene
  • 3-BroMo-2-Methyl-benzoic acid Methy
  • Benzoic acid, 3-broMo-2-Methyl-, Methyl ester
  • Methyl 3-Bromo-o-toluate
  • Methyl 3-bromo-2-methylbenzoate , Methyl 3-bromo-2-methylbenzoate
  • 99548-54-6
  • Aromatic Esters
  • Acids & Esters
  • Bromine Compounds
  • Aromatics
  • Miscellaneous Reagents