Benzoyl cyanide

Product Name: Benzoyl cyanide
CAS No.: 613-90-1
Chemical Name: Benzoyl cyanide
Synonyms: Benzoyl nitrile;BENZOYL CYANIDE;Benzoylcyanide98%;Benzoylcyanide 98%;Phenylglyoxynitrile;Phenylglyoxonitrile;α-oxo-α-tolunitrile;Benzoyl cyanide,95%;Ritalin Impurity 11;Benzoyl Cyanide >
CBNumber: CB1716030
Molecular Formula: C8H5NO
Formula Weight: 131.13
MOL File: 613-90-1.mol

More

Less

Benzoyl cyanide Property

Melting point:: 28-31 °C(lit.)
Boiling point:: 206 °C(lit.)
Density: 1.106 g/mL at 25 °C(lit.)
refractive index: 1.4700 (estimate)
Flash point:: 184 °F
solubility: soluble in Methanol
form: powder to lump to clear liquid
color: White or Colorless to Light yellow
Water Solubility: slihtly soluble, decomposes
BRN: 1072101
CAS DataBase Reference: 613-90-1(CAS DataBase Reference)
NIST Chemistry Reference: Benzeneacetonitrile, «alpha»-oxo-(613-90-1)
EPA Substance Registry System: Benzeneacetonitrile, .alpha.-oxo- (613-90-1)

More

Less

Safety

Hazard Codes: T,N
Risk Statements: 25-50-34-24/25-20
Safety Statements: 36/37/39-45-61-29-26
RIDADR: UN 3439 6.1/PG 2
WGK Germany: 3
F: 10
HazardClass: 6.1(b)
PackingGroup: III
HS Code: 29269095

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H300Fatal if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 115959
Product name: Benzoyl cyanide
Purity: 98%
Packaging: 25g
Price: $111
Updated: 2023/06/20

Sigma-Aldrich

Product number: 115959
Product name: Benzoyl cyanide
Purity: 98%
Packaging: 100g
Price: $171
Updated: 2022/05/15

TCI Chemical

Product number: B0835
Product name: Benzoyl Cyanide
Purity: >98.0%(GC)
Packaging: 25g
Price: $68
Updated: 2024/03/01

TRC

Product number: B130375
Product name: Benzoyl cyanide
Packaging: 10g
Price: $75
Updated: 2021/12/16

TRC

Product number: B130375
Product name: Benzoyl cyanide
Packaging: 5g
Price: $60
Updated: 2021/12/16

More

Less

Benzoyl cyanide Chemical Properties,Usage,Production

Chemical Properties

yellow to brown low melting mass. Phenylglyoxylonitrile [613-90-1], benzoyl cyanide, Mr 131.13, mp 34℃, bp 206 – 208℃ (101.3 kPa), bp 96℃ (2 kPa), bp 82℃ (1.2 kPa), n26D 1.5303, can be used for selective reactions at the carbonyl and cyano groups. It is produced from the reaction of benzoyl chloride or benzoic anhydride with sodium cyanide (or hydrogen cyanide in the presence of alkali cyanide) in practically quantitative yield with copper (I) cyanide as catalyst. Benzoyl cyanide is used as an intermediate in the synthesis of plant protection agents.

Uses

Using benzoyl cyanide as an electrophile also gives selective acylation of the 3-position, as does levulinic acid in the presence of DCC.
Benzoyl cyanide is used to study the mechanism of reduction of benzoyl cyanide in acetonitrile, N,N-dimethylformamide and acetonitrile. It undergoes hydrolysis by Rhodococcus sp. CCZU10-1 to form benzoylformic acid. Reagent for selective acylation of amino compounds.

Preparation

Benzoyl cyanide is prepared by treatment of benzoyl chloride with sodium cyanide under phase-transfer catalytic conditions. This process is also used to convert 4-methyl, 4-methoxy, and 4-chlorobenzoyl chlorides into the corresponding benzoyl cyanides, and similarly cinnamoyl chloride into cinnamoyl cyanide (98%).

Definition

ChEBI: Benzoyl cyanide is an alpha-ketonitrile and an aromatic ketone. It is functionally related to a benzoic acid.

Synthesis Reference(s)

Synthetic Communications, 15, p. 849, 1985 DOI: 10.1080/00397918508063881

General Description

Benzoyl cyanide is used to study the mechanism of reduction of benzoyl cyanide in acetonitrile, N,N-dimethylformamide and acetonitrile. It undergoes hydrolysis by Rhodococcus sp. CCZU10-1 to form benzoylformic acid.

Benzoyl cyanide Preparation Products And Raw materials

Raw materials

Copper(I) Cyanide Benzoyl chloride

Preparation Products

Benzoylformic acid Methyl benzoylformate

More

Less

Benzoyl cyanide Suppliers

Americas 1 Belgium 2 Canada 1 China 156 Czech Republic 2 Europe 3 Germany 4 India 13 Japan 3 Switzerland 1 The Netherlands 1 United Kingdom 14 United States 37 Global 238

Ark Pharm, Inc.

Tel: 847-367-3680
Fax: 847-367-3681
Email: sales@arkpharminc.com
Country: United States
ProdList: 1670
Advantage: 56

Aladdin Scientific

Tel
Email: tp@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Alfa Chemistry

Tel
Email: info@alfa-chemistry.com
Country: United States
ProdList: 2344
Advantage: 58

Aston Chemical

Tel: 13000000000
Email: sales@astonchem.com
Country: United States
ProdList: 1634
Advantage: 58

Crescent Chemical Company

Tel: --
Fax: --
Email: fran@creschem.com
Country: United States
ProdList: 1441
Advantage: 58

2A Biotech USA

Tel: --
Fax: --
Email: info@2abiotech.com
Country: United States
ProdList: 1785
Advantage: 58

MilliporeSigma (Sigma-Aldrich Corp.)

Tel: --
Fax: --
Email: @sial.com
Country: United States
ProdList: 5414
Advantage: 58

eNovation Chemicals LLC

Tel: --
Fax: --
Email: ales@eNovationChem.com
Country: United States
ProdList: 1673
Advantage: 58

Alichem Inc.

Tel: --
Fax: --
Email: sales@alichem.com
Country: United States
ProdList: 6167
Advantage: 58

Fluorochem Ltd.

Tel: --
Fax: --
Email: enquiries@fluorochem.co.uk
Country: United States
ProdList: 4583
Advantage: 58

TCI America, Inc. (Tokyo Chemical Industry Co., Ltd.)

Tel: --
Fax: --
Email: .Crew@tcichemicals.com
Country: United States
ProdList: 3164
Advantage: 58

Redox Scientific

Tel: --
Fax: --
Email: info@redoxsci.com
Country: United States
ProdList: 2380
Advantage: 58

OX CHEM

Tel: --
Fax: --
Email: sales@ox-chem.com
Country: United States
ProdList: 759
Advantage: 50

Spectrum Chemical Mfg. Corp.

Tel: --
Fax: --
Email: marketing@spectrumchemical.com
Country: United States
ProdList: 3113
Advantage: 60

BroadPharm. Inc.

Tel: --
Fax: --
Email: sales@broadpharm.com
Country: United States
ProdList: 891
Advantage: 50

Oakwood Products, Inc.

Tel: --
Fax: --
Email: sales@oakwoodchemical.com
Country: United States
ProdList: 6193
Advantage: 74

Advance Scientific & Chemical

Tel: --
Fax: --
Email: sales@advance-scientific.com
Country: United States
ProdList: 6419
Advantage: 71

AK Scientific, Inc.

Tel: --
Fax: --
Email: sales@aksci.com
Country: United States
ProdList: 6347
Advantage: 65

VWR International, LLC.

Tel: --
Fax: --
Email: @sargentwelch.com
Country: United States
ProdList: 6262
Advantage: 58

United States Biological

Tel: --
Fax: --
Email: chemicals@usbio.net
Country: United States
ProdList: 6214
Advantage: 80

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Alfa Chemistry

Tel: --
Fax: --
Email: info@Alfa-Chemistry.com
Country: United States
ProdList: 6814
Advantage: 0

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6962
Advantage: 56

Waterstone Technology, LLC

Tel: --
Fax: --
Email: sales@waterstonetech.com
Country: United States
ProdList: 6786
Advantage: 30

Ryan Scientific, Inc.

Tel: --
Fax: --
Email: ryan.reichlyn@ryansci.com
Country: United States
ProdList: 6439
Advantage: 60

Pfaltz & Bauer, Inc.

Tel: --
Fax: --
Email: sales@pfaltzandbauer.com
Country: United States
ProdList: 6828
Advantage: 72

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

2A PharmaChem USA

Tel: --
Fax: --
Email: sales@2apharmachem.com
Country: United States
ProdList: 6137
Advantage: 39

City Chemical LLC

Tel: --
Fax: --
Email: sales@citychemical.com
Country: United States
ProdList: 6708
Advantage: 72

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

APAC Pharmaceutical, LLC

Tel: --
Fax: --
Email: sales@apacpharma.com
Country: United States
ProdList: 6322
Advantage: 38

Aceto Corporation

Tel: --
Fax: --
Email: contact@aceto.com
Country: United States
ProdList: 2619
Advantage: 75

MP Biomedicals, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 6561
Advantage: 81

City Chemicals Corporation

Tel: --
Fax: --
Country: United States
ProdList: 6460
Advantage: 72

More

Less

View Lastest Price from Benzoyl cyanide manufacturers

Nanjing jinheyou Trading Co., Ltd.

Product: Benzoyl cyanide 613-90-1
Price: US $0.00/g
Min. Order: 1g
Purity: 95%min
Supply Ability: 20kg/month
Release date: 2019-11-19

Career Henan Chemical Co

Product: Benzoyl cyanide 613-90-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2019-08-29

613-90-1, Benzoyl cyanideRelated Search:

Benzoyl peroxide Benzonitrile Copper(I) Cyanide Diethylstilbestrol 4-Nitrobenzonitrile Benzamide p-Tolunitrile Chlorantraniliprole Ethyl benzoylacetate Benzoyl isothiocyanate Methyl benzoylformate Dibenzoylmethane HYDROGEN CYANIDE Dibenzoyltartaric acid POTASSIUM CYANIDE OXO-4-TRIFLUOROMETHYL-PHENYL)-ACETONITRILE 2-METHYLBENZOYL CYANIDE Benzoyl cyanide oxime~Phenylglyoxylonitrile oxime

BENZOYL CYANIDE

PHENYLGLYOXYLONITRILE

alpha-oxophenylacetonitrile

Benzoyl cyanide, 95% 25GR

Benzeneacetonitrile,a-oxo-

Benzoyl nitrile

Glyoxylonitrile, phenyl-

Oxo(phenyl)acetonitrile

Oxo-phenyl-acetonitrile

Phenylglyoxonitrile

Phenylglyoxynitrile

α-Oxobenzeneacetonitrile

alpha-oxo-benzeneacetonitril

alpha-Oxobenzeneacetonitrile

alpha-Tolunitrile, alpha-oxo-

Benzeneacetonitrile,alpha-oxo-

α-keto-α-tolunitrile

α-oxo-α-tolunitrile

a-Oxobenzeneacetonitrile

Phenylglyoxalic acid nitrile

2-Oxo-2-phenylethanenitrile

Benzoylformic acid nitrile

Phenylglyoxylnitrile

Benzoyl cyanide,95%

Benzoyl cyanidePhenylglyoxylonitrile

2-oxo-2-Phenylacetonitrile

Benzoylcyanide98%

Benzoylcyanide 98%

alpta-Oxophenylacetonitrile

Ritalin Impurity 11

Benzoyl Cyanide &gt

Benzeneacetonitrile, α-oxo-

[Mohrs SaL,Ammonium iron(ii)Sulphate,Ferrous Ammonium Sulphate]

613-90-1

C6H5COCN

Nitrogen Compounds

Organic Building Blocks

Cyanides/Nitriles

C8 to C9

Building Blocks