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TRIBUTYLBORANE

Product Name
TRIBUTYLBORANE
CAS No.
122-56-5
Chemical Name
TRIBUTYLBORANE
Synonyms
Tributylboron;Boronbutoxide;TRIBUTYLBORANE;Tributylborine;tributyl-boran;Borane,tributyl-;TRI-N-BUTYLBORON;Borane, tributyl-;Tri-n-butylborane;tri-n-butylborane,
CBNumber
CB1725849
Molecular Formula
C12H27B
Formula Weight
182.15
MOL File
122-56-5.mol
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TRIBUTYLBORANE Property

Melting point:
-34 °C
Boiling point:
109 °C20 mm Hg(lit.)
Density 
0.834 g/mL at 25 °C
refractive index 
1.4285
Flash point:
1 °F
storage temp. 
Flammables area
solubility 
Benzene, Tetrahydrofuran
form 
Solution
color 
Clear colorless to light yellow
Water Solubility 
Not miscible or difficult to mix with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
InChIKey
CMHHITPYCHHOGT-UHFFFAOYSA-N
CAS DataBase Reference
122-56-5
EPA Substance Registry System
Borane, tributyl- (122-56-5)
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Safety

Hazard Codes 
F,Xn,C
Risk Statements 
17-34-40-36/37/38-20/21/22-11-22-19-37
Safety Statements 
7-23-26-36/37/39-43-45-16
RIDADR 
UN 2845 4.2/PG 1
WGK Germany 
1
RTECS 
ED1850000
TSCA 
Yes
HazardClass 
4.2
PackingGroup 
I
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H250Catches fire spontaneously if exposed to air

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
297976
Product name
Tributylborane solution
Purity
1.0M in diethyl ether
Packaging
100ml
Price
$229
Updated
2023/01/07
Sigma-Aldrich
Product number
179906
Product name
Tributylborane solution
Purity
1.0 M in THF
Packaging
100ml
Price
$154
Updated
2022/05/15
Alfa Aesar
Product number
H32518
Product name
Tri-n-butylborane
Purity
1M soln. in THF
Packaging
100ml
Price
$140
Updated
2021/12/16
Alfa Aesar
Product number
H32518
Product name
Tri-n-butylborane
Purity
1M soln. in THF
Packaging
500ml
Price
$373
Updated
2021/12/16
Sigma-Aldrich
Product number
298425
Product name
Tributylborane
Packaging
50g
Price
$329
Updated
2023/06/20
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TRIBUTYLBORANE Chemical Properties,Usage,Production

Chemical Properties

Colorless pyrophoric fluid. Insoluble in water; soluble in most organic solvents.

Uses

Petrochemical industry, organic reactions, catalyst.

Uses

Tributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 427, 1986 DOI: 10.1021/jo00354a002
Tetrahedron Letters, 26, p. 4311, 1985 DOI: 10.1016/S0040-4039(00)98721-5

Hazard

Flammable, dangerous fire risk, store and use in inert atmosphere, ignites spontaneously in air.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame; can ignite spontaneously. When heated to decomposition it emits acrid smoke and irritating fumes. See also BORANES.

TRIBUTYLBORANE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIBUTYLBORANE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12990
Advantage
57
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
TIANJIN SPRING PHARMA SCIENCE CO., LTD.
Tel
0086-22-60330256
Fax
0086-22-60330256
Country
China
ProdList
83
Advantage
58
Wuxi Zhongkun Biochemical Technology Co., Ltd.
Tel
0510-85629785 18013409632
Fax
051085625359
Email
sales@reading-chemicals.com
Country
China
ProdList
15185
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Infinity SCI
Tel
400-400-1062016 17800804092
Email
admin@infsci.com
Country
China
ProdList
719
Advantage
55
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View Lastest Price from TRIBUTYLBORANE manufacturers

Career Henan Chemical Co
Product
TRIBUTYLBORANE 122-56-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kgs
Release date
2020-03-05

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