ChemicalBook > CAS DataBase List > TRIBUTYLBORANE

TRIBUTYLBORANE

Product Name
TRIBUTYLBORANE
CAS No.
122-56-5
Chemical Name
TRIBUTYLBORANE
Synonyms
Tributylboron;Boronbutoxide;TRIBUTYLBORANE;Tributylborine;tributyl-boran;Borane,tributyl-;TRI-N-BUTYLBORON;Borane, tributyl-;Tri-n-butylborane;tri-n-butylborane,
CBNumber
CB1725849
Molecular Formula
C12H27B
Formula Weight
182.15
MOL File
122-56-5.mol
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TRIBUTYLBORANE Property

Melting point:
-34 °C
Boiling point:
109 °C20 mm Hg(lit.)
Density 
0.834 g/mL at 25 °C
refractive index 
1.4285
Flash point:
1 °F
storage temp. 
Flammables area
solubility 
Benzene, Tetrahydrofuran
form 
Solution
color 
Clear colorless to light yellow
Water Solubility 
Not miscible or difficult to mix with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
InChIKey
CMHHITPYCHHOGT-UHFFFAOYSA-N
CAS DataBase Reference
122-56-5
EPA Substance Registry System
Borane, tributyl- (122-56-5)
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Safety

Hazard Codes 
F,Xn,C
Risk Statements 
17-34-40-36/37/38-20/21/22-11-22-19-37
Safety Statements 
7-23-26-36/37/39-43-45-16
RIDADR 
UN 2845 4.2/PG 1
WGK Germany 
1
RTECS 
ED1850000
TSCA 
Yes
HazardClass 
4.2
PackingGroup 
I
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H250Catches fire spontaneously if exposed to air

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
297976
Product name
Tributylborane solution
Purity
1.0M in diethyl ether
Packaging
100ml
Price
$229
Updated
2023/01/07
Sigma-Aldrich
Product number
179906
Product name
Tributylborane solution
Purity
1.0 M in THF
Packaging
100ml
Price
$154
Updated
2022/05/15
Alfa Aesar
Product number
H32518
Product name
Tri-n-butylborane
Purity
1M soln. in THF
Packaging
100ml
Price
$140
Updated
2021/12/16
Alfa Aesar
Product number
H32518
Product name
Tri-n-butylborane
Purity
1M soln. in THF
Packaging
500ml
Price
$373
Updated
2021/12/16
Sigma-Aldrich
Product number
298425
Product name
Tributylborane
Packaging
50g
Price
$329
Updated
2023/06/20
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TRIBUTYLBORANE Chemical Properties,Usage,Production

Chemical Properties

Colorless pyrophoric fluid. Insoluble in water; soluble in most organic solvents.

Uses

Petrochemical industry, organic reactions, catalyst.

Uses

Tributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 427, 1986 DOI: 10.1021/jo00354a002
Tetrahedron Letters, 26, p. 4311, 1985 DOI: 10.1016/S0040-4039(00)98721-5

Hazard

Flammable, dangerous fire risk, store and use in inert atmosphere, ignites spontaneously in air.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame; can ignite spontaneously. When heated to decomposition it emits acrid smoke and irritating fumes. See also BORANES.

TRIBUTYLBORANE Preparation Products And Raw materials

Raw materials

Preparation Products

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TRIBUTYLBORANE Suppliers

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View Lastest Price from TRIBUTYLBORANE manufacturers

Career Henan Chemical Co
Product
TRIBUTYLBORANE 122-56-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kgs
Release date
2020-03-05

122-56-5, TRIBUTYLBORANERelated Search:


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