TRIBUTYLBORANE

ChemicalBook > CAS DataBase List > TRIBUTYLBORANE

Product Name: TRIBUTYLBORANE
CAS No.: 122-56-5
Chemical Name: TRIBUTYLBORANE
Synonyms: Tributylboron;Boronbutoxide;TRIBUTYLBORANE;Tributylborine;tributyl-boran;Borane,tributyl-;TRI-N-BUTYLBORON;Borane, tributyl-;Tri-n-butylborane;tri-n-butylborane,
CBNumber: CB1725849
Molecular Formula: C12H27B
Formula Weight: 182.15
MOL File: 122-56-5.mol

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TRIBUTYLBORANE Property

Melting point:: -34 °C
Boiling point:: 109 °C20 mm Hg(lit.)
Density: 0.834 g/mL at 25 °C
refractive index: 1.4285
Flash point:: 1 °F
storage temp.: Flammables area
solubility: Benzene, Tetrahydrofuran
form: Solution
color: Clear colorless to light yellow
Water Solubility: Not miscible or difficult to mix with water.
Sensitive: Air Sensitive
Exposure limits: ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
InChIKey: CMHHITPYCHHOGT-UHFFFAOYSA-N
CAS DataBase Reference: 122-56-5
EPA Substance Registry System: Borane, tributyl- (122-56-5)

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Safety

Hazard Codes: F,Xn,C
Risk Statements: 17-34-40-36/37/38-20/21/22-11-22-19-37
Safety Statements: 7-23-26-36/37/39-43-45-16
RIDADR: UN 2845 4.2/PG 1
WGK Germany: 1
RTECS: ED1850000
TSCA: Yes
HazardClass: 4.2
PackingGroup: I
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H250Catches fire spontaneously if exposed to air

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 297976
Product name: Tributylborane solution
Purity: 1.0M in diethyl ether
Packaging: 100ml
Price: $229
Updated: 2023/01/07

Sigma-Aldrich

Product number: 179906
Product name: Tributylborane solution
Purity: 1.0 M in THF
Packaging: 100ml
Price: $154
Updated: 2022/05/15

Alfa Aesar

Product number: H32518
Product name: Tri-n-butylborane
Purity: 1M soln. in THF
Packaging: 100ml
Price: $140
Updated: 2021/12/16

Alfa Aesar

Product number: H32518
Product name: Tri-n-butylborane
Purity: 1M soln. in THF
Packaging: 500ml
Price: $373
Updated: 2021/12/16

Sigma-Aldrich

Product number: 298425
Product name: Tributylborane
Packaging: 50g
Price: $329
Updated: 2023/06/20

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TRIBUTYLBORANE Chemical Properties,Usage,Production

Chemical Properties

Colorless pyrophoric fluid. Insoluble in water; soluble in most organic solvents.

Uses

Petrochemical industry, organic reactions, catalyst.

Uses

Tributylborane is a reducing agent used in the controlled radical polymerization of alkyl acrylates.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 427, 1986 DOI: 10.1021/jo00354a002
Tetrahedron Letters, 26, p. 4311, 1985 DOI: 10.1016/S0040-4039(00)98721-5

Hazard

Flammable, dangerous fire risk, store and use in inert atmosphere, ignites spontaneously in air.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A very dangerous fire hazard when exposed to heat or flame; can ignite spontaneously. When heated to decomposition it emits acrid smoke and irritating fumes. See also BORANES.

TRIBUTYLBORANE Preparation Products And Raw materials

Raw materials

Preparation Products

DIBUTYLBORON TRIFLUOROMETHANESULFONATE

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View Lastest Price from TRIBUTYLBORANE manufacturers

Career Henan Chemical Co

Product: TRIBUTYLBORANE 122-56-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 200kgs
Release date: 2020-03-05

122-56-5, TRIBUTYLBORANERelated Search:

Tributyltin Hydride Boron trifluoride diethyl etherate 1,2,4-Trimethylbenzene Trifluoromethanesulfonic acid TRIPHENYLBORANE Trimethylaluminium TRIMETHYLBORON Triethylborane Tributyltin chloride Triethylaluminum Tributyl citrate Tributyl phosphate TRI-N-BUTYLALUMINUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE TRIBUTYLBORANE B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONANE LITHIUM HYDRIDO(9-BBN-NOPOL BENZYL ETHER ADDUCT) LITHIUM B-ISOPINOCAMPHEYL-9-BORABICYCLO[3.3.1]NONYL HYDRIDE

TRIBUTYLBORANE

Tributylboron

TRI-N-BUTYLBORON

Borane, tributyl-

Tributylborane, 1.0 M solution in THF, SpcSeal

Tributylborane solution 1.0 M in THF

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Borane,tributyl-

tributyl-boran

Tributylborine

Tri-n-butylborane

tri-n-butylborane,

tri-n-butylborane,tnbb

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Tributylborane solution

TRIBUTYLBORANE, 1.0M SOLUTION IN DIETHYL ETHER

TRIBUTYLBORANE, 1.0M SOLUTION IN TETRAHY DROFURAN

1.0Msolutionintetrahydrofuran

Tributylborane, 1M solution in THF

Tributylborane1M solution in THFAcroSeal§3

Tributylborane,98%

Tributylborane, 1M solution in THF, AcroSeal

Tri-n-butylborane, 1M soln. in THF

Tributylborane (1.0M in THF)

TIANFU CHEM-- TRIBUTYLBORANE

122-56-5

C12H27B

CH3CH233B

Boranes

Synthetic Reagents

Reduction

Boranes

Reduction

Synthetic Reagents