Methyl 2-(methylamino)benzoate

ChemicalBook > CAS DataBase List > Methyl 2-(methylamino)benzoate

Methyl 2-(methylamino)benzoate

Product Name: Methyl 2-(methylamino)benzoate
CAS No.: 85-91-6
Chemical Name: Methyl 2-(methylamino)benzoate
Synonyms: DIMETHYL ANTHRANILATE;METHYL N-METHYLANTHRANILATE;Methyl methanthranilate;Benzoic acid, 2-(methylamino)-, methyl ester;DIMETHYLANTHRANILAT;METHYL METHYLANTHRANILATE;2-Methylaminomethyl benzoate;Dimethylanthanilate;3-Amino-2-butenamide;FEMA 2718
CBNumber: CB1755530
Molecular Formula: C9H11NO2
Formula Weight: 165.19
MOL File: 85-91-6.mol

Less

Methyl 2-(methylamino)benzoate Property

Melting point:: 17-19 °C(lit.)
Boiling point:: 256 °C(lit.)
Density: 1.126 g/mL at 25 °C(lit.)
vapor pressure: 2.74Pa at 25℃
FEMA: 2718 | METHYL N-METHYLANTHRANILATE
refractive index: n20/D 1.579(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
solubility: Miscible in all proportions with ethanol 96%, DMSO and diethyl ether.
pka: 2.80±0.10(Predicted)
color: Colourless to Yellow
PH: 7-8 (H2O, 20℃)
Odor: at 100.00 %. fruity musty sweet neroli powdery phenolic wine
Odor Type: floral
Water Solubility: 329.792mg/L at 30℃
JECFA Number: 1545
BRN: 607217
LogP: 2.81-3.08 at 25℃
CAS DataBase Reference: 85-91-6(CAS DataBase Reference)
NIST Chemistry Reference: Benzoic acid,o-(methylamino)-, methyl ester(85-91-6)
EPA Substance Registry System: Methyl N-methyl anthranilate (85-91-6)

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36-36/37/39-22
WGK Germany: 1
RTECS: CB3500000
TSCA: Yes
HS Code: 2922498590
Hazardous Substances Data: 85-91-6(Hazardous Substances Data)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W271810
Product name: Dimethyl anthranilate
Purity: natural, ≥98%, FG
Packaging: 100g
Price: $175
Updated: 2024/03/01

Sigma-Aldrich

Product number: W271810
Product name: Dimethyl anthranilate
Purity: natural, ≥98%, FG
Packaging: 1kg
Price: $1050
Updated: 2024/03/01

Sigma-Aldrich

Product number: W271802
Product name: Dimethyl anthranilate
Purity: ≥97%, FG
Packaging: 1kg
Price: $203
Updated: 2024/03/01

Sigma-Aldrich

Product number: W271802
Product name: Dimethyl anthranilate
Purity: ≥97%, FG
Packaging: 5kg
Price: $541
Updated: 2024/03/01

Sigma-Aldrich

Product number: W271802
Product name: Dimethyl anthranilate
Purity: ≥97%, FG
Packaging: 100g
Price: $76.5
Updated: 2023/01/07

Less

Methyl 2-(methylamino)benzoate Chemical Properties,Usage,Production

Description

Methyl n-methylanthranilate has an orange and mandarin peel-like odor with a musty, grape-like flavor. It is somewhat more berry-like than grape. May be prepared by methylation of methyl anthranilate or esterification of N-methylanthranilic acid.

Chemical Properties

Methyl-n-methylanthranilate has an orange and mandarin peel-like odor and a musty, grape-like flavor; somewhat more berry-like than grape.

Chemical Properties

Methyl N-Methylanthranilate is the main component of petitgrain oils from mandarin leaves and is also found in mandarin oil. It is a pale yellow, fluorescent liquid with a delicate mandarin odor. The ester can be prepared by methylation ofmethyl anthranilate. It is used in soap and cosmetic perfumes as well as in aromas, particularly for mandarin flavors.

Occurrence

Reported found in mandarin essential oil and mandarin leaves essential oil (50 to 76.5%); also reported in the oil from bulbs of Kaempferia ethelae L., in orange petitgrain, and in the oil from hyacinth flowers. Also reported found in starfruit, orange peel oil and grapefruit juice.

Uses

It is used as a flavorant in a wide range of foods (particularly flour and sugar confections).

Uses

Methyl 2-(Methylamino)benzoate is one of many volatile components from mango cultivars.

Definition

ChEBI: Methyl N-methylanthranilate is a methyl ester resulting from the formal condensation of the carboxy group of N-methylanthranilic acid with methanol. It has a role as a fungal metabolite, a plant metabolite and an animal metabolite. It is a benzoate ester, a methyl ester, a secondary amino compound and a substituted aniline. It is functionally related to a N-methylanthranilic acid.

Preparation

By methylation of methyl anthranilate or esterification of N-methylanthranillic acid.

Production Methods

Methyl N-methanthranilate is a component of mandarin and mandarin tree leaf essential oil. It is also found in oil from bulbs of Kaempferia ethelae L., hyacinth flowers, and orange petitgrain . It is synthesized by methylation of methyl anthranilate or esterification ofN-methylanthranilic acid.

Taste threshold values

Taste characteristics at 10 ppm: fruity grape skin, anthranilate-like with a woody and floral nuance

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 3373, 1984 DOI: 10.1021/jo00192a024

Toxicity evaluation

The acute oral LD₅₀ value in rats was reported as 3.7 ml/kg (Levenstein, 1974). The acute oral LD₅₀ in female rats was reported to be between 2.25 g/kg (no deaths) and 3.38 g/kg (100% deaths) (Gaunt, Sharratt, Grasso & Wright, 1970). The acute dermal LD₅₀ value in rabbits was reported as > 5 g/kg (Levenstein, 1974). The LC 50 for larvae of Tribolium destructor was found to be 0-1151 mg/cm3 (Vasechko, Kuznetsov, Smelyanets & Guznenok, 1970).

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.

Methyl 2-(methylamino)benzoate Preparation Products And Raw materials

Raw materials

Bis(methylthio)methane Methyl anthranilate Hydrogen peroxide Formaldehyde Nickel Acetic acid Iodomethane

Preparation Products

Less

Methyl 2-(methylamino)benzoate Suppliers

Americas 1 Australia 1 Belgium 1 China 178 Czech Republic 1 Europe 3 France 7 Germany 9 India 25 Italy 1 Japan 5 Mexico 1 Slovakia 1 South Africa 1 Spain 2 Switzerland 2 Ukraine 1 United Kingdom 17 United States 63 USA 1 Global 321

Jay Chemicals

Tel: 13732234254
Email: yogesh.dama@jaychemicals.co.in
Country: China
ProdList: 40
Advantage: 58

HUBEI CHANGYAO BIOTECHNOLOGY CO LTD

Tel: 17683887209
Email: 906856569@qq.com
Country: China
ProdList: 4559
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
Advantage: 61

Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18217
Advantage: 66

Adamas Reagent, Ltd.

Tel: 400-6009262 16621234537
Fax: 021-64823266
Email: zhangsn@titansci.com
Country: China
ProdList: 14113
Advantage: 59

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9816
Advantage: 59

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696;
Email: info@hanhongsci.com
Country: China
ProdList: 42982
Advantage: 64

jiliang chemicals

Tel: 21-62165282 15801962796;
Fax: 021 61153784
Email: bidingchem@163.com
Country: China
ProdList: 1165
Advantage: 60

Shandong Xiya Chemical Co., Ltd

Tel: 13355009207 13355009207
Fax: 0539-6365991
Email: 3007715519@qq.com
Country: China
ProdList: 18739
Advantage: 57

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12990
Advantage: 57

BEST-REAGENT

Tel: 400-1166-196 18981987031
Fax: 028-84555506 800101999
Email: cdhxsj@163.com
Country: China
ProdList: 11726
Advantage: 57

RYSS TECH LTD

Tel: 400-188-0725 +86 21 34310725 13611771617
Fax: +86 21 34311076
Country: China
ProdList: 2002
Advantage: 57

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14443
Advantage: 57

Maya High Purity Chemicals

Tel: +86 (573) 82222445 (0)18006601000 452520369
Fax: +86 (573) 82222643
Email: sales@maya-r.com
Country: China
ProdList: 11714
Advantage: 57

Shanghai Nuohey Chemical Co., Ltd.

Tel: 021-52212593 13761626812
Fax: +86 (21) 51062076
Email: sales@nuohey.com
Country: China
ProdList: 10690
Advantage: 60

Chengdu Ai Keda Chemical Technology Co., Ltd.

Tel: 4008-755-333 18080918076
Fax: 028-86757656
Email: 800078821@qq.com
Country: China
ProdList: 9725
Advantage: 55

Shanghai civi chemical technology co.,Ltd

Tel: 86-21-34053660
Fax: 86-21-34053661
Email: sale@labgogo.com
Country: China
ProdList: 9872
Advantage: 52

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66099280 17798518460
Fax: (1)02557626880
Email: cfzhang@aikonchem.com
Country: China
ProdList: 19918
Advantage: 55

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22519
Advantage: 55

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 400-6206333 18521732826;
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25015
Advantage: 65

TargetMol Chemicals Inc.

Tel: 021-33632979 15002134094
Fax: 021-33632979
Email: marketing@targetmol.com
Country: China
ProdList: 7934
Advantage: 58

Shanghai Hao Yun Chemical Science Co.,Ltd.

Tel: 021-68367562 15002147577;
Fax: 021-68369562
Email: sales@haoyunchem.com
Country: China
ProdList: 490
Advantage: 55

Shanghai JONLN Reagent Co., Ltd.

Tel: 400-0066400 13621662912
Fax: 021-55660885
Email: 422131432@qq.com
Country: China
ProdList: 9986
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-1647117 15221909166
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41438
Advantage: 60

ChemStrong Scientific Co.,Ltd

Tel: 0755-0755-66853366 13670046396
Fax: 0755-28363542
Email: sales@chem-strong.com
Country: China
ProdList: 17982
Advantage: 56

Shanghai CanSpecsci Instrument Co., Ltd.

Tel: 400-6087598 15021221957
Fax: 4006087598-8012
Email: order@canspecsci.com
Country: China
ProdList: 2071
Advantage: 56

Shanghai Macklin Biochemical Co.,Ltd.

Tel: 15221275939 15221275939
Fax: 021-50706099
Email: shenlinxing@macklin.cn
Country: China
ProdList: 15878
Advantage: 55

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

Shanghai Synchem Pharma Co., ltd

Tel: 021-61984905-1 18016477331
Email: synchempharma@aliyun.com
Country: China
ProdList: 6454
Advantage: 55

Zhengzhou Alfachem Co., Ltd.

Tel: 0371-53765687 18937137882
Fax: QQ:2885373884
Email: 2853979813@qq.com
Country: China
ProdList: 7996
Advantage: 55

Nanjing Vital Chemical Co., Ltd.

Tel: 025-87193546 18652950785
Fax: 025-87193546
Email: chemweiao@163.com
Country: China
ProdList: 9030
Advantage: 60

Shanghai Xilong Biochemical Technology Co., Ltd.

Tel: 021-52907766-8042
Fax: 021-52906523
Country: China
ProdList: 9947
Advantage: 58

Shenzhen Simeiquan Biotechnology Co. Ltd

Tel: 18126413629 0755-23311925 2355327053
Fax: 0755-23311925
Email: abel@ycgmp.com
Country: China
ProdList: 5115
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131981
Advantage: 58

Shenzhen Sendi Biological Technology Co., Ltd.

Tel: 18124570582 TEL：0755-23574479 2355327139
Fax: 0755-23229476 QQ: 2355327139
Email: siliao02@yccreate.com
Country: China
ProdList: 6120
Advantage: 58

Guangzhou Kafen Biotech Co.,Ltd

Tel: 18029243487 2355327168
Fax: 020-31121510
Email: gy@yccreate.com
Country: China
ProdList: 4753
Advantage: 55

Shanghai Witofly Chemical Co. ,Ltd.

Tel: 021-021-50630626 18964684208
Email: sales@witofly.com
Country: China
ProdList: 1150
Advantage: 55

Taian Jiaye Biotechnology Co.Ltd

Tel: 13127280945
Email: 285424065@qq.com
Country: China
ProdList: 9980
Advantage: 55

Dalian lichuang Chemical Co., Ltd

Tel: 0411-0411-00000000 13644282108
Fax: -
Email: 3500508746@qq.com
Country: China
ProdList: 2844
Advantage: 55

Chengdu Push Bio-Technology Co., Ltd.

Tel: 028-85370565-229 18080489829
Email: 3004654993@qq.com
Country: China
ProdList: 9174
Advantage: 60

9ding chemical ( Shanghai) Limited

Tel: 021-021-52271985 17721149837
Fax: +86 (21) 52271987
Email: sales@9dingchem.com
Country: China
ProdList: 19806
Advantage: 60

Zhuhai JiaYi Biological Technology Co., Ltd.

Tel: 18578209868 2355327026
Fax: 18578209868 QQ：2355327026
Email: steroidbest@hotmail.com
Country: China
ProdList: 6504
Advantage: 58

Capot Chemical Co.,Ltd.

Tel: 571-85586718 +8613336195806
Fax: +86-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 29797
Advantage: 60

Shanghai Standard Technology Co.,Ltd.

Tel: 021-57127007-6622 15618937986
Fax: +86 (21) 5132-0077
Email: zhaok@nature-standard.com
Country: China
ProdList: 3920
Advantage: 58

Conier Chem & Pharma Limited

Tel: 13368167990
Email: sales@conier.com
Country: China
ProdList: 2809
Advantage: 58

Wuhan FengyaoTonghui Chemical Products Co., Ltd.

Tel: 027-87466105 15377573527
Email: 2678564200@qq.com
Country: China
ProdList: 17997
Advantage: 58

Less

View Lastest Price from Methyl 2-(methylamino)benzoate manufacturers

Hebei Duling International Trade Co. LTD

Product: Methyl 2-(methylamino)benzoate 85-91-6
Price: US $30.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2023-03-17

Hebei Guanlang Biotechnology Co., Ltd.

Product: Methyl 2-(methylamino)benzoate 85-91-6
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2023-03-02

Hebei Mojin Biotechnology Co., Ltd

Product: Methyl 2-(methylamino)benzoate 85-91-6
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-08-30

85-91-6, Methyl 2-(methylamino)benzoateRelated Search:

Aniline-2-sulfonic acid Methyl 4-methylbenzoate Emamectin benzoate Denatonium Benzoate Anhydrous Methyl 4-cyanobenzoate Methyl acrylate Methyl salicylate Methanol o-Anisidine Methyl 4-(bromomethyl)benzoate Sodium benzoate Methyl anthranilate 2-Carbomethoxybenzenesulfonamide Methyl 3-(bromomethyl)benzoate 4-Aminobenzoic acid Methyl 4-aminobenzoate Kresoxim-methyl METSULFURON METHYL

METHYL 2-(N-METHYLAMINO)BENZOATE

METHYL 2-METHYLAMINOBENZOATE

METHYL O-(METHYLAMINO)BENZOATE

METHYL N-METHYLANTHRANILATE

METHYL METHYLANTHRANILATE

FEMA 2718

DIMETHYL ANTHRANILATE

2-METHYLAMINOBENZOIC ACID METHYL ESTER

N-METHYLANTHRANILIC ACID METHYL ESTER

N-METHYL-2-AMINOBENZOIC ACID METHYL ESTER

2-Methylaminomethyl benzoate

2-Methylaminomethylbenzoate

Anthranilic acid, N-methyl-, methyl ester

Methyl 2-methylaminobenzoate, tech.

DIMETHYLANTHRANILAT

Methyl-N-methylanthranilat

2-(methylamino)-benzoicacimethylester

DIMETHYL ANTHRANILATE, NATURAL

DIMETHYL ANTHRANILATE, SYNTHETIC

(CH3NH)C6H4CO2CH3

Dimethyl anthranilate ,98%

Dimethyl anthranilate,Methyl N-methylanthranilate

Methyl N-methylanthranilate, 2-(Methoxycarbonyl)-N-methylaniline

3-Amino-2-butenamide

b-Aminocrotonamide

2-Methylaminobenzoic acid methyl

o-(Methylamino)benzoic acid methyl ester

N-Methyl-2-aminobenzoic Acid Methyl Ester N-Methylanthranilic Acid Methyl Ester Methyl N-Methyl-2-aminobenzoate

METHYL-N-METHYL ANTHRANILATE FOR SYNTHES

5-(2-oxo-1,3,3a,4,6,6a-hexahydrothieno[3,4-d]imidazol-4-yl)pentanoic acid (13-methyl-17-oxo-7,8,9,11,12,14,15,16-octahydro-6H-cyclopenta[a]phenanthren-3-yl) ester

Benzoic acid, 2-(methylamino)-, methyl ester

Benzoicacid,2-(methylamino)-,methylester

Me N-methylanthranilate

Methyl benzoate, 2-methylamino

Methyl methanthranilate

Methyl methylaminobenzoate

Methyl m-methylanthranilate

Methyl N-methyl-o-anthranilate

methylmethanthranilate

N-Methyl methyl anthranilate

n-methylanthranilicacid,methyl

n-methyl-anthranilicacimethylester

N-Methylanthranilic acid methyl ester~Methyl 2-methylaminobenzoate

DIMETHYL ANTHRANILATE 97+%

DIMETHYL ANTHRANILATE 98+% NATURAL &

Dimethylanthanilate

N-Methylanthranilic Acid Methyl Ester Methyl N-Methylanthranilate N-Methyl-2-aminobenzoic Acid Methyl Ester methyl 2-(methylamino)benzoate

MethylN-Methylanthranilate&gt

Methyl N-Methyl-2-aminobenzoate

Methyl 2-(methylamino)benzoate USP/EP/BP

Dimethyl Anthranilate 6878001

85-91-6

2CH3NHC6H4CO2CH3

CH3NHC6H4COOCH3

C9H11O2N

Organic Building Blocks

Esters

C8 to C9