CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID

Product Name: CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
CAS No.: 111955-05-6
Chemical Name: CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID
Synonyms: Cis-2-Carbomethoxycyclohexane-1-Carbox;2-carbomethoxycyclohexane-1-carboxylic acid;cis-2-Carbomethoxycyclohexanecarboxylic acid;2-methoxycarbonylcyclohexane-1-carboxylic acid;2-methoxycarbonyl-1-cyclohexanecarboxylic acid;CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID;cis-2-methoxycarbonylcyclohexanecarboxylic acid;rel-1-Methyl (1R,2S)-1,2-cyclohexanedicarboxylate;(1R,2S)-2-(Methoxycarbonyl)cyclohexanecarboxylic acid;(+/-)CIS-2-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID
CBNumber: CB1760765
Molecular Formula: C9H14O4
Formula Weight: 186.21
MOL File: 111955-05-6.mol

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CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Property

Melting point:: 68-69 °C
Boiling point:: 82 °C(Press: 0.5 Torr)
Density: 1.191±0.06 g/cm3(Predicted)
storage temp.: Store at room temperature
pka: 4.45±0.44(Predicted)
form: solid
Appearance: White to off-white Solid

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B415263
Product name: Cis-2-carbomethoxycyclohexane-1-carboxylicacid
Packaging: 25mg
Price: $45
Updated: 2021/12/16

TRC

Product number: B415263
Product name: Cis-2-carbomethoxycyclohexane-1-carboxylicacid
Packaging: 250mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 086447
Product name: cis-2-Carbomethoxycyclohexane-1-carboxylic acid
Purity: 97%
Packaging: 1g
Price: $59
Updated: 2021/12/16

Matrix Scientific

Product number: 086447
Product name: cis-2-Carbomethoxycyclohexane-1-carboxylic acid
Purity: 97%
Packaging: 5g
Price: $188
Updated: 2021/12/16

Rieke Metals

Product number: 18503
Product name: Cis-2-Carbomethoxycyclohexane-1-carboxylicacid
Purity: 97%
Packaging: 1g
Price: $225
Updated: 2021/12/16

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CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Chemical Properties,Usage,Production

Synthesis

67-56-1

13149-00-3

2484-60-8

The cis-1,2-cyclohexanedicarboxylic anhydride (7.0 g, 45.5 mmol) was dissolved in methanol (2 mL, 49.5 mmol) and the reaction was stirred at 100 °C for 1 hour. Upon completion of the reaction, the solvent was removed by evaporation to afford trans-2-(methoxycarbonyl)cyclohexanecarboxylic acid (8.46 g, 45.5 mmol, 100% yield) as a white solid, which could be used in subsequent steps without further purification. The melting point of the product is 67-69 °C. Infrared spectrum (KBr): ν 3060, 1710, 1670 cm-1. 1H NMR (400 MHz, CDCl3): δ 7.54 (s, 1H), 3.68 (s, 3H), 2.89-2.81 (m, 2H), 2.09-1.96 (m, 2H), 1.83-1.72 (m, 2H), 1.61-1.36 （13C NMR (100 MHz, CDCl3): δ 179.76, 174.06, 51.71, 42.48, 42.33, 26.25, 25.95, 23.74, 23.62. High-resolution mass spectrometry (ESI): Calculated value of C9H13O4 [M-H]- 185.0792, measured value of 185.0790. 185.0790.

References

[1] Letters in Organic Chemistry, 2018, vol. 15, # 5, p. 404 - 411
[2] Journal of Organic Chemistry, 2008, vol. 73, # 6, p. 2454 - 2457
[3] Organic and Biomolecular Chemistry, 2011, vol. 9, # 22, p. 7929 - 7940
[4] Patent: US2014/288314, 2014, A1. Location in patent: Paragraph 197; 198
[5] Chirality, 2015, vol. 27, # 10, p. 693 - 699

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID Suppliers

China 44 India 1 United Kingdom 1 United States 7 Global 53

Aladdin Scientific

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Matrix Scientific

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Rieke Metals, Inc.

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ASDI Incorporated

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View Lastest Price from CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID manufacturers

Career Henan Chemica Co

Product: CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID 111955-05-6
Price: US $6.05/ASSAYS
Min. Order: 200g
Purity: 95.0%-99.0%
Supply Ability: 100kg
Release date: 2020-11-05

111955-05-6, CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACIDRelated Search:

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID CIS-DIETHYL BICYCLO[2.2.1]HEPTANE-2,3-DICARBOXYLATE Cicloxolone (1S,2R)-Cyclohexane-1,2-dicarboxylic acid diethyl ester Monoacryloyloxyethy Hexahydrophthalate (MAHP) Dimethyl cyclohexane-1,2-dicarboxylate

1,2-Cyclohexanedicarboxylic acid, 1-methyl ester, (1R,2S)-rel-

(1R,2S)-2-(Methoxycarbonyl)cyclohexanecarboxylic acid

2-carbomethoxycyclohexane-1-carboxylic acid

2-methoxycarbonyl-1-cyclohexanecarboxylic acid

2-methoxycarbonylcyclohexane-1-carboxylic acid

(1S,2R)-2-(methoxycarbonyl)cyclohexane-1-carboxylic acid

(1R,2S)-2-methoxycarbonylcyclohexane-1-carboxylic acid

CIS-2-CARBOMETHOXYCYCLOHEXANE-1-CARBOXYLIC ACID

cis-2-Carbomethoxycyclohexanecarboxylic acid

(+/-)CIS-2-(METHOXYCARBONYL)CYCLOHEXANECARBOXYLIC ACID

Cis-2-Carbomethoxycyclohexane-1-Carbox

rel-1-Methyl (1R,2S)-1,2-cyclohexanedicarboxylate

cis-2-methoxycarbonylcyclohexanecarboxylic acid

111955-05-6

Carboxylic acid