Tribenoside

ChemicalBook > CAS DataBase List > Tribenoside

Product Name: Tribenoside
CAS No.: 10310-32-4
Chemical Name: Tribenoside
Synonyms: TBGF;Venex;Alven;21401-Ba;Glyvenol;Glyvenal;Glivenol;Tohcuron;Ba 21401;Flebosan
CBNumber: CB1842212
Molecular Formula: C29H34O6
Formula Weight: 478.58
MOL File: 10310-32-4.mol

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Tribenoside Property

alpha: D26 +8° (chloroform)
Boiling point:: bp1.2 270-280°
Density: 1.19±0.1 g/cm3(Predicted)
storage temp.: Sealed in dry,Store in freezer, under -20°C
solubility: Practically insoluble in water, very soluble in acetone, in methanol and in methylene chloride.
pka: 13.01±0.70(Predicted)
color: Pale Yellow to Light Yellow
InChIKey: ULLNJSBQMBKOJH-VIVFLBMVSA-N
CAS DataBase Reference: 10310-32-4

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Safety

Toxicity: LD50 oral in rat: > 20gm/kg

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: Y0000165
Product name: Tribenoside
Purity: European Pharmacopoeia (EP) Reference Standard
Packaging: y0000165
Price: $220
Updated: 2024/03/01

Usbiological

Product number: 293301
Product name: Ethyl 3,5,6-tri-O-benzyl-D-glucofuranoside
Packaging: 5g
Price: $382
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: O106695
Product name: Ethyl3-5-6-tri-O-benzyl-D-glucofuranoside
Packaging: 5G
Price: $395
Updated: 2021/12/16

Biosynth Carbosynth

Product number: ME02540
Product name: Ethyl 3,5,6-tri-O-benzyl-D-glucofuranoside
Packaging: 50g
Price: $425
Updated: 2021/12/16

Biosynth Carbosynth

Product number: ME02540
Product name: Ethyl 3,5,6-tri-O-benzyl-D-glucofuranoside
Packaging: 100g
Price: $750
Updated: 2021/12/16

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Tribenoside Chemical Properties,Usage,Production

Chemical Properties

Yellowish to pale yellow, clear, viscous liquid.

Originator

Glyvenol,Ciba,W. Germany,1967

Uses

Tribenoside is a vasoprotective drug. It’s used in the treatment of hemorrhoids as it has mild anti-inflammatory and wound healing properties.

Uses

Sclerosing agent.

Definition

ChEBI: (3R,4R,5R)-5-[(1R)-1,2-bis(phenylmethoxy)ethyl]-2-ethoxy-4-phenylmethoxy-3-oxolanol is a glycoside.

Manufacturing Process

4.9 g of 3,5,6-tribenzyl-1,2-isopropylidene glucofuranose are kept overnight at room temperature with 100 cc of N-ethanolic hydrochloric acid. Evaporation under vacuum at below 50°C is then carried out and the residue taken up in 150 cc of chloroform. The chloroform solution is thoroughly washed with sodium bicarbonate solution, dried with calcined sodium sulfate and evaporated under vacuum. The oily residue is then distilled under vacuum with a free flame. In this manner there is obtained the ethyl-3,5,6-tribenzyl_x0002_D-glucofuranoside of boiling point 270°C to 275°C under 1 mm pressure. The glucofuranose used as starting material is obtained as follows: 8.8 g of 1,2-isopropylidene-D-glucofuranose and 50.6 g of benzyl chloride are treated with a total of 28 g of potassium hydroxide in portions with cooling and stirring. The mixture is then stirred for 3 hours at 80°C to 90°C. Working up from chloroform solution and distillation at 250°C to 260°C under 0.1 mm pressure give 8.9 g of 1,2-isopropylidene-3,5,6-tribenzyl-D-glucofuranose.

Therapeutic Function

Topical venotonic

Hazard

Low toxicity by ingestion.

Contact allergens

This drug is used for the treatment, both topical and oral, of hemorrhoids. It leads to benzo?c acid, that is contained in Myroxylon pereirae as well, and could be the sensitizer.

Tribenoside Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Tribenoside manufacturers

shandong perfect biotechnology co.ltd

Product: Tribenoside 10310-32-4
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98% HPLC
Supply Ability: 1000kg
Release date: 2023-07-06

Hebei Yanxi Chemical Co., Ltd.

Product: Tribenoside 10310-32-4
Price: US $100.00/kgkg
Min. Order: 1kgkg
Purity: 0.99
Supply Ability: 100
Release date: 2023-09-20

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Tribenoside 10310-32-4
Price: US $0.00/G
Min. Order: 100G
Purity: 98%min
Supply Ability: 30kg/month
Release date: 2023-02-20

10310-32-4, TribenosideRelated Search:

Benzyltriethylammonium chloride Ethyl acetate Dextran Ethanol 4-Methoxyphenol Trinexapac-ethyl alpha-D-Methylglucoside 4-Methoxybenzyl cyanide Stevioside BETA-GLUCOSIDASE ISOXADIFEN-ETHYL 2-Ethoxyethanol p-Anisidine 4-Trifluoromethylbenzyl chloride Alkyl polyglucoside Ethoxyquin Guaiacol p-Anisaldehyde

Glivenol

Glucofuranoside, ethyl 3,5,6-tri-O-benzyl- (7CI)

Glucofuranoside, ethyl 3,5,6-tri-O-benzyl-, D- (8CI)

Glyvenal

Glyvenol

Hemocuron

TBGF

Tribenzoside

Venex

1-O-Ethyl-3-O,5-O,6-O-tribenzyl-D-glucofuranose

21401-Ba

Tohcuron

(3R,4R,5R)-4-(Benzyloxy)-5-((R)-1,2-bis(benzyloxy)ethyl)-2-ethoxytetrahydrofuran-3-ol

D-Glucofuranoside,ethyl 3,5,6-tris-O-(phenylMethyl)-

-1,2-bis(benzyloxy)

-2-ethoxytetrahydrofuran-3-ol

(3R,4R,5R)-5-[1,2-Bis(phenylmethoxy)ethyl]-2-ethoxy-4-(phenylmethoxy)oxolan-3-ol

ETHYL-3,5,6-TRI-O-BENZYL-D-GLUCOFURANOSIDE

Alven

Ba 21401

D-Glucofuranoside, ethyl 3,5,6-tris-O-(phenylmethyl)- (9CI)

Flebosan

TRIBENOSIDE

(3R,4R,5R)-4-(benzyloxy)-5-[(1R)-1,2-bis(benzyloxy)ethyl]-2-ethoxyoxolan-3-ol

Tribenoside (3R,4R,5R)-5-[1,2-Bis(phenylmethoxy)ethyl]-2-ethoxy-4-(phenylmethoxy)oxolan-3-ol

Tribenoside CRS

Tribenoside API

Tribenzyl glycoside

10310-32-4

C29H34O6