2-Bromo-9,9-diphenylfluorene
Uses- Product Name
- 2-Bromo-9,9-diphenylfluorene
- CAS No.
- 474918-32-6
- Chemical Name
- 2-Bromo-9,9-diphenylfluorene
- Synonyms
- 2-BroMo-9,9-diphenyl-9H-fluorene;PC221;2--9,9--;2-BroMo-9,9-di;2-Bromo-9,9-diphenyl;2-bromo-9,9-diphenylfluorene;2-Bromo-9,5-diphenylfluorene;2-Dibromo-9,9-diphenylfluorene;2-bromo-9,9-diphenyl-fluororene;2-Bromo-9,9-diphenylfluorene >
- CBNumber
- CB1855115
- Molecular Formula
- C25H17Br
- Formula Weight
- 397.31
- MOL File
- 474918-32-6.mol
2-Bromo-9,9-diphenylfluorene Property
- Melting point:
- 217.0 to 221.0 °C
- Boiling point:
- 480.5±24.0 °C(Predicted)
- Density
- 1.363±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Toluene
- form
- powder to crystal
- color
- White to Almost white
- CAS DataBase Reference
- 474918-32-6
Safety
- HS Code
- 2903998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B4450
- Product name
- 2-Bromo-9,9-diphenylfluorene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $36
- Updated
- 2024/03/01
- Product number
- B4450
- Product name
- 2-Bromo-9,9-diphenylfluorene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $111
- Updated
- 2024/03/01
- Product number
- B685623
- Product name
- 2-Bromo-9,9-Diphenylfluorene
- Packaging
- 500mg
- Price
- $110
- Updated
- 2021/12/16
- Product number
- X4129
- Product name
- 2-Bromo-9,9-diphenylfluorene
- Packaging
- 25g
- Price
- $283
- Updated
- 2021/12/16
- Product number
- 094950
- Product name
- 2-Bromo-9,9-diphenyl-9H-fluorene
- Purity
- 95+%
- Packaging
- 1g
- Price
- $331
- Updated
- 2021/12/16
2-Bromo-9,9-diphenylfluorene Chemical Properties,Usage,Production
Uses
2-Bromo-9,9-dimethylfluorene is a fluorene derivative which shows π-electron conjugation. It has a high fluorescent and high electron delocalization. It can be used as a non-linear optical (NLO) material. 2-bromo-9, 9-diphenylfluorene can be synthesized by using 2-bromofluorene and iodomethane as the major reactants. It can be majorly used in organic electronic based applications.
Description
2-bromo-9, 9-diphenylfluorene appears as an off-white solid. It belongs to the fluorene group compound. It is a kind of OLED (organic light-emitting diodes) intermediate. It can be used for the production of 9, 9-diphenylfluorene-capped oligothiophenes which can be used as active materials such as filed-effect transistors and light-emitting diodes.
Chemical Properties
off-white powder
Synthesis
10 g (30 mmol) of 2-bromo-9-phenyl-9H-fluoren-9-ol was dissolved in 60
ml of benzene, and 2.4 ml (45 mmol) of concentrated sulfuric acid
diluted with a small amount of benzene was added to the solution. The
mixture was stirred for 5 hours at 80?? C, and after evaporating the
benzene, 1 N sodium hydroxide solution was added to the remaining
solution to a pH of around 7. The mixture was extracted 3 times with
ethyl acetate (40 ml). The collected organic layer was dried with
magnesium sulfate, and the residue obtained by evaporating the solvent
was separated and purified by silica gel column chromatography. 6 g of
Intermediate N (yield: 50%).
References
(2015). Synthesis method of 2-bromo-9, 9-diphenylfluorene, Google Patents.
Wong, Ken-Tsung, et al. "Synthesis and properties of novel thiophene-based conjugated homologues: 9, 9-diphenylfluorene-capped oligothiophenes."Organic letters 4.25 (2002): 4439-4442.
2-Bromo-9,9-diphenylfluorene Preparation Products And Raw materials
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View Lastest Price from 2-Bromo-9,9-diphenylfluorene manufacturers
- Product
- 2-Dibromo-9,9-Diphenylfluorene; 2-Bromo-9,9-diphenylfluorene; 474918-32-6
- Price
- US $6.00-0.60/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-18
- Product
- 2-Bromo-9,9-diphenyl-9H-fluorene 474918-32-6
- Price
- US $39.00-327.00/g
- Min. Order
- 5g
- Purity
- 0.99
- Supply Ability
- 25kg
- Release date
- 2023-12-14
- Product
- 9H-Fluorene, 2-bromo-9,9-diphenyl- 474918-32-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-17