ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE

Product Name: ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
CAS No.: 20461-99-8
Chemical Name: ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
Synonyms: 2-Carboethoxydithiolane;2-Carboethoxy-1,3-dithiolane;2-Ethoxycarbonyl-1,3-dithiolane;Ethyl 1,3-Ditholane-2-carboxylate;ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE;ETHYL GLYOXYLATE ETHYLENE THIOACETAL;Ethyl 1,3-dithiolane-2-carboxylate,99%;Ethyl 1,3-dithiolane-2-carboxylate, 98+%;Ethyl 1,3-dithiolane-2-carboxylate, GC 99%;Ethyl 1,3-dithiolane-2-carboxylate, 99% 5ML
CBNumber: CB2105967
Molecular Formula: C6H10O2S2
Formula Weight: 178.27
MOL File: 20461-99-8.mol

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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Property

Boiling point:: 85 °C/0.1 mmHg (lit.)
Density: 1.249 g/mL at 25 °C (lit.)
refractive index: n20/D 1.539(lit.)
Flash point:: >230 °F
storage temp.: 2-8°C
form: Liquid
color: Clear light yellow
Specific Gravity: 1.249
BRN: 118157
CAS DataBase Reference: 20461-99-8(CAS DataBase Reference)

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Safety

Safety Statements: 23-24/25
RIDADR: 3334
WGK Germany: 3
F: 8-9
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TCI Chemical

Product number: D2105
Product name: Ethyl 1,3-Dithiolane-2-carboxylate
Purity: >97.0%(GC)
Packaging: 5g
Price: $67
Updated: 2024/03/01

TRC

Product number: E937118
Product name: Ethyl 1,3-Dithiolane-2-carboxylate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: E937118
Product name: Ethyl 1,3-Dithiolane-2-carboxylate
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Matrix Scientific

Product number: 098234
Product name: Ethyl 1,3-dithiolane-2-carboxylate
Purity: 95+%
Packaging: 1g
Price: $49
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0029461
Product name: ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
Purity: 95.00%
Packaging: 5G
Price: $897.92
Updated: 2021/12/16

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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Chemical Properties,Usage,Production

Chemical Properties

clear light yellow liquid

General Description

Ethyl 1,3-dithiolane-2-carboxylate is an α-keto acid equivalent. It participates in the conjugate additions to enones. It is a bulky equivalent of acetate undergoing syn-selective aldol reactions. Anion derived from ethyl 1,3-dithiolane-2-carboxylate participates as nucleophile during the total synthesis of the corynanthe alkaloid dihydrocorynantheol and the formal syntheses of the indole alkaloids tacamonine, rhynchophylline and hirsutine. It also participates in the conjugate addition of enolates to phenylglycinol-derived α,β-unsaturated δ-lactams.

Purification Methods

Dissolve the ester in CHCl3, wash it with aqueous K2CO3, twice with H2O, dry it over MgSO4, filter, evaporate and distil the residue in vacuo. [Hermann et al Tetrahedron Lett 2599 1973, Corey & Erickson J Org Chem 36 3553 1971]. [Beilstein 19/7 V 225.]

ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Ethanol 1,2-Ethanedithiol ETHYL DIBROMOACETATE Potassium

Preparation Products

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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Suppliers

Americas 1 Belgium 1 China 43 Europe 2 Germany 2 India 2 Japan 3 Switzerland 2 United Kingdom 4 United States 10 Global 70

J & K SCIENTIFIC LTD.

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View Lastest Price from ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE manufacturers

Career Henan Chemical Co

Product: ethyl 1,3-dithiolane-2-carboxylate 20461-99-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: Min98% HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-30

20461-99-8, ETHYL 1,3-DITHIOLANE-2-CARBOXYLATERelated Search:

2-METHYL-1,3-DITHIOLANE Methyl thioglycolate ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE METHYL (METHYLTHIO)ACETATE 1,2-Ethanedithiol ETHYL THIOGLYCOLATE 1,3-DITHIOLANE Bis(methylthio)methane Mercaptoacetic acid 2-methoxyethanethiol (METHYLTHIO)ACETIC ACID (ETHYLTHIO)ACETIC ACID Ethyl 2-hydroxyethyl sulfide ETHYL (METHYLTHIO)ACETATE 1-(methylthio)ethanethiol

ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE

ETHYL GLYOXYLATE ETHYLENE THIOACETAL

GLYOXYLIC ACID ETHYL ESTER ETHYLENE MERCAPTAL

2-Carboethoxy-1,3-dithiolane~1,3-Dithiolane-2-carboxylicacidethylester~2-Ethoxycarbonyl-1,3-dithiolane~Ethylglyoxyla

1,3-DITHIOLANE-2-CARBOXYLIC ACID ETHYL ESTER

2-Carboethoxy-1,3-dithiolane

2-Carboethoxydithiolane

Ethyl 1,3-dithiolane-2-carboxylate, GC 99%

1,3-DITHIOLANE-2-CARBOXYLIC ACID ETHYL ESTER 95+%

Ethyl 1,3-dithiolane-2-carboxylate, 98+%

Ethyl 1,3-dithiolane-2-carboxylate,99%

2-Ethoxycarbonyl-1,3-dithiolane

Ethyl Glyoxylate Dimethylene Dithioacetal

Ethyl 1,3-dithiolane-2-carboxylate, 99% 5ML

Ethyl 1,3-Ditholane-2-carboxylate

20461-99-8

C6H10O2S2

Sulfur Compounds (for Synthesis)

Building Blocks

Others

S-Containing

Heterocyclic Building Blocks

Sulfur Compounds (for Synthesis)

Synthetic Organic Chemistry

Heterocyclic Compounds