ChemicalBook > CAS DataBase List > ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
- Product Name
- ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
- CAS No.
- 20461-99-8
- Chemical Name
- ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
- Synonyms
- 2-Carboethoxydithiolane;2-Carboethoxy-1,3-dithiolane;2-Ethoxycarbonyl-1,3-dithiolane;Ethyl 1,3-Ditholane-2-carboxylate;ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE;ETHYL GLYOXYLATE ETHYLENE THIOACETAL;Ethyl 1,3-dithiolane-2-carboxylate,99%;Ethyl 1,3-dithiolane-2-carboxylate, 98+%;Ethyl 1,3-dithiolane-2-carboxylate, GC 99%;Ethyl 1,3-dithiolane-2-carboxylate, 99% 5ML
- CBNumber
- CB2105967
- Molecular Formula
- C6H10O2S2
- Formula Weight
- 178.27
- MOL File
- 20461-99-8.mol
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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Property
- Boiling point:
- 85 °C/0.1 mmHg (lit.)
- Density
- 1.249 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.539(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- form
- Liquid
- color
- Clear light yellow
- Specific Gravity
- 1.249
- BRN
- 118157
- CAS DataBase Reference
- 20461-99-8(CAS DataBase Reference)
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- D2105
- Product name
- Ethyl 1,3-Dithiolane-2-carboxylate
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $67
- Updated
- 2024/03/01
TRC
- Product number
- E937118
- Product name
- Ethyl 1,3-Dithiolane-2-carboxylate
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
TRC
- Product number
- E937118
- Product name
- Ethyl 1,3-Dithiolane-2-carboxylate
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
Matrix Scientific
- Product number
- 098234
- Product name
- Ethyl 1,3-dithiolane-2-carboxylate
- Purity
- 95+%
- Packaging
- 1g
- Price
- $49
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CHM0029461
- Product name
- ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $897.92
- Updated
- 2021/12/16
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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Chemical Properties,Usage,Production
Chemical Properties
clear light yellow liquid
General Description
Ethyl 1,3-dithiolane-2-carboxylate is an α-keto acid equivalent. It participates in the conjugate additions to enones. It is a bulky equivalent of acetate undergoing syn-selective aldol reactions. Anion derived from ethyl 1,3-dithiolane-2-carboxylate participates as nucleophile during the total synthesis of the corynanthe alkaloid dihydrocorynantheol and the formal syntheses of the indole alkaloids tacamonine, rhynchophylline and hirsutine. It also participates in the conjugate addition of enolates to phenylglycinol-derived α,β-unsaturated δ-lactams.
Purification Methods
Dissolve the ester in CHCl3, wash it with aqueous K2CO3, twice with H2O, dry it over MgSO4, filter, evaporate and distil the residue in vacuo. [Hermann et al Tetrahedron Lett 2599 1973, Corey & Erickson J Org Chem 36 3553 1971]. [Beilstein 19/7 V 225.]
ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Preparation Products And Raw materials
Raw materials
Preparation Products
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ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23680
- Advantage
- 75
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View Lastest Price from ETHYL 1,3-DITHIOLANE-2-CARBOXYLATE manufacturers
Career Henan Chemical Co
- Product
- ethyl 1,3-dithiolane-2-carboxylate 20461-99-8
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- Min98% HPLC
- Supply Ability
- g/kg/ton
- Release date
- 2020-01-30
20461-99-8, ETHYL 1,3-DITHIOLANE-2-CARBOXYLATERelated Search:
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