ChemicalBook > CAS DataBase List > 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate

Product Name
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
CAS No.
35193-63-6
Chemical Name
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
Synonyms
BNDHP;(R)-(-)-BNP ACID;(R)-(-)-BPA;(R)-(-)-BNPA;(S)-(+)-BPA;(S)-(+)-BNPA;(S)-(+)-BNP ACID;Einecs 252-425-8;1,1'-Biphthyl-2,2'-diyl hydrogenphosphate;1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
CBNumber
CB2107330
Molecular Formula
C20H13O4P
Formula Weight
348.29
MOL File
35193-63-6.mol
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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Property

Melting point:
≥300 °C
Boiling point:
619.5±38.0 °C(Predicted)
Density 
1.49±0.1 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
1.14±0.20(Predicted)
form 
Solid
color 
White to Yellow to Orange
optical activity
Consistent with structure
Water Solubility 
Extremely low soluble in water.
InChI
InChI=1S/C20H13O4P/c21-25(22)23-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)24-25/h1-12H,(H,21,22)
InChIKey
JEHUZVBIUCAMRZ-UHFFFAOYSA-N
SMILES
O1C2=CC=C3C(=C2C2=C4C(C=CC=C4)=CC=C2OP1(=O)O)C=CC=C3
CAS DataBase Reference
35193-63-6(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39-22
WGK Germany 
3
RTECS 
RZ2475100
F 
10-23
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
292966
Product name
1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Purity
95%
Packaging
5g
Price
$96.44
Updated
2025/07/31
TCI Chemical
Product number
B2130
Product name
(+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
Purity
>98.0%(HPLC)(T)
Packaging
5g
Price
$72
Updated
2025/07/31
TCI Chemical
Product number
B2130
Product name
(+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
Purity
>98.0%(HPLC)(T)
Packaging
25g
Price
$259
Updated
2025/07/31
Biosynth Carbosynth
Product number
FB05481
Product name
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate
Packaging
5G
Price
$105
Updated
2021/12/16
ChemScene
Product number
CS-0031445
Product name
1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate
Purity
99.88%
Packaging
100g
Price
$170
Updated
2021/12/16
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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powde

Uses

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate Suppliers

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View Lastest Price from 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-63-6
Price
US $0.10/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
1000 tons
Release date
2025-09-11
Hebei Chuanghai Biotechnology Co., Ltd
Product
1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 35193-63-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-18
XINXIANG RUNYU MATERIAL CO., LTD.
Product
1,1'-Binaphthyl-2,2'-diylhydrogenphosphate 35193-63-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%+
Supply Ability
250kg
Release date
2024-11-19

35193-63-6, 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphateRelated Search:

naphthidine Iron oxide black Clindamycin phosphate SULPHOSUCCINIC ACID ESTER Zinc oxide NITRIC OXIDE Magnesium oxide (S)-(-)-1,1'-Bi-2-naphthol ETHYLENE OXIDE 1,1'-Bi-2-naphthol Iron oxide Rutile (Diethoxymethyl)diphenylphosphine oxide Water treatment agent POE NITROUS OXIDE (S)-(+)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate, min. 98%,(S)-(+)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE,S-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE (R)-(-)-1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate 1,1'-BINAPHTHYL

  • (+/-)-1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
  • 1,1'-BINAPHTHYL-2,2'-DIYL HYDROGENPHOSPHATE
  • (+/-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
  • 2-HYDROXY-2LAMBDA5-DINAPHTHO[2,1-D:1,2-F][1,3,2]DIOXAPHOSPHEPIN-2-ONE
  • 4-Hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin 4-oxide
  • (R)-(-)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
  • (R)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOSPHEPIN-4-OXID
  • (R)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
  • R(-)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
  • (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL-PHOSPHATE
  • (R)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
  • (S)-(+)-2,2'-DIHYDROXY-1,1'-BINAPHTHYL HYDROGENPHOSPHATE
  • (S)-(+)-1,1'-BINAPHTHELENE-2,2'-DIYL-PHOSPHATE
  • S(+)-1,1'-BI-2-NAPHTHYL-2,2'-DIYL HYDROGEN PHOSPHATE
  • (S)-(-)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
  • S(+)-1,1'-BINAPHTHALENE-2,2'-DIYL HYDROGEN PHOSPHATE
  • (R)-(-)-BPA
  • (R)-(-)-BNP ACID
  • (R)-(-)-BNPA
  • (S)-4-HYDROXYDINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-OXIDE
  • (S)-4-HYDROXY DINAPHTHO[2,1-D:1',2'-F][1,3,2]-DIOXAPHOPHEPIN-4-OXID
  • (S)-(+)-BPA
  • (S)-(+)-BNPA
  • (S)-(+)-BNP ACID
  • (+/-)-1,1-ALPHA'-BINAPHTHYL-2,2-ALPHA'-DIYL HYDROGENPHOSPHATE
  • (+/-)-1,1''-BINAPHTHYL-2,2''-DIYL HYDROGENPHOSPHATE 99%
  • Einecs 252-425-8
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 4-hydroxy-, 4-oxide
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ol 4-oxide, BNDHP
  • BNDHP
  • 1,1-Binaphthyl-2,2-diyl hydrogenphosphate≥ 99% (HPLC)
  • 1,1'-Biphthyl-2,2'-diyl hydrogenphosphate
  • rac-1,1'-Binaphthyl-2,2'-diyl-hydrogenphosphate
  • (+/-)-1,1′-Binaphtyl-2,2′-diyl hydrogenphosphate
  • (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate &gt
  • 1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, 99%,
  • (±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
  • 4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • (±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
  • 1,1′-Binaphthyl-2,2′-diyl hydrogenphosphate, CAS 35193-63-6
  • (+/-)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
  • 4-Hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
  • 1,1'-Binaphthyl-2,2'-diyl hydrogenphosphate - [B94047]
  • 35193-63-6
  • C20H13O4P
  • for Resolution of Bases
  • e.e. / Absolute Conefiguration Determination (NMR)
  • Optical Resolution
  • Enantiomer Excess & Absolute Conefiguration Determination
  • Chiral Resolution Reagents
  • Catalysis and Inorganic Chemistry
  • Asymmetric Synthesis
  • Phosphorus Catalysts
  • Phosphorus Compounds
  • Chiral Resolving Reagents
  • Achiral Phosphine
  • Aryl Phosphine
  • Phosphorus Catalysts