Methyl 4-bromobenzoate

Product Name: Methyl 4-bromobenzoate
CAS No.: 619-42-1
Chemical Name: Methyl 4-bromobenzoate
Synonyms: METHYL P-BROMOBENZOATE;BRBSME;NSC 9392;RARECHEM AL BF 0075;Methyl 4-bromobenzoa;Methyl-4-brombenzoat;Methy14-bromobenzoate;METHYL 4-BROMOBENZOATE;Methyl 4-bromobenzoate,99%;Methyl 4-bromobenzoate 99%
CBNumber: CB2139717
Molecular Formula: C8H7BrO2
Formula Weight: 215.04
MOL File: 619-42-1.mol

More

Less

Methyl 4-bromobenzoate Property

Melting point:: 77-81 °C (lit.)
Boiling point:: 252.95°C (rough estimate)
Density: 1,689 g/cm³
refractive index: 1.5500 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Crystals or Crystalline Powder
color: White
Water Solubility: Insoluble in water.
Merck: 14,1408
BRN: 2045132
InChIKey: HANNIMAAZKBBRE-UHFFFAOYSA-N
CAS DataBase Reference: 619-42-1(CAS DataBase Reference)
NIST Chemistry Reference: 4-Bromobenzoic acid methyl ester(619-42-1)
EPA Substance Registry System: Benzoic acid, 4-bromo-, methyl ester (619-42-1)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-24/25
WGK Germany: 3
TSCA: Yes
HS Code: 29163990

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 407593
Product name: Methyl 4-bromobenzoate
Purity: 99%
Packaging: 10g
Price: $117
Updated: 2024/03/01

TCI Chemical

Product number: B0556
Product name: Methyl 4-Bromobenzoate
Purity: >98.0%(GC)
Packaging: 10g
Price: $50
Updated: 2024/03/01

TCI Chemical

Product number: B0556
Product name: Methyl 4-Bromobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $83
Updated: 2024/03/01

Alfa Aesar

Product number: A15517
Product name: Methyl 4-bromobenzoate, 98+%
Packaging: 5g
Price: $47.65
Updated: 2024/03/01

Alfa Aesar

Product number: A15517
Product name: Methyl 4-bromobenzoate, 98+%
Packaging: 25g
Price: $171
Updated: 2024/03/01

More

Less

Methyl 4-bromobenzoate Chemical Properties,Usage,Production

Chemical Properties

WHITE CRYSTALS OR CRYSTALLINE POWDER

Uses

Methyl 4-bromobenzoate is used as a starting material in the synthesis of three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine and methyl 4-tri-n-butylstannylbenzoate. It is also used to stimulate microbial dechlorination of polychlorinated biphenyls. Further, it is used in the preparation of stable radioiodinating reagent to label monoclonal antibodies for radiotherapy of cancer.

Uses

Methyl 4-bromobenzoate is a halogenated benzoate used as a reagent in organic synthesis. It can be used to stimulate microbial dechlorination of PCBs. By condensing methyl 4-bromobenzoate with 3-buten-1-ol, 4-(4-methylphenyl)butanal can be obtained.

Application

Methyl 4-bromobenzoate may be used in the following syntheses:

Methyl 4-(2-pyridyl)benzoate by cross coupling reaction with lithium 2-pyridyltriolborate.
Methyl 4-imidazo[1,2-a]pyridin-3-ylbenzoate by ligand-free Pd(OAc)2 catalyzed reaction with Imidazo[1,2-a]pyridine.
Methyl (E)-4-[3-(2-methoxycarbonylvinyl)-thiophen-2-yl]acrylate by reacting with methyl (E)-3-(thiophen-3-y)lacrylate.

General Description

Methyl 4-bromobenzoate is a para-substituted aryl bromide. Mol-ecules of methyl 4-bromobenzoate are almost planar. The compound is isostructural with methyl 4-iodo-benzoate. The Zeeman effect on the N.Q.R. (nuclear quadrupole resonance) of methyl 4-bromobenzoate on single crystals, has been investigated by the ′geometric method′.

Purification Methods

Crystallise the ester from MeOH. EtOH (m 81o, also 80.5o, 79.5o) or *C6H6/pet ether (m 78-79o). [Beilstein 9 H 352, 9 III 1405, 9 IV 1017.]

Methyl 4-bromobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Methyl 4-bromobenzoate Suppliers

Americas 1 Belgium 3 Canada 1 China 298 Cyprus 1 Europe 3 Germany 10 India 37 Japan 3 Slovakia 1 Switzerland 3 United Kingdom 18 United States 47 USA 1 Global 427

Shanghai TongYuan Chemical Co., Ltd.

Tel: 021-021-69182866 13701855675
Fax: 021-69182022
Email: tongyuanchem@126.com
Country: China
ProdList: 4331
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: 029-81124267 15229202216
Fax: 029-88380327
Email: 1073@dideu.com
Country: China
ProdList: 10011
Advantage: 58

Shandong Dexin Fine Chemical Co. LTD

Tel: 18353358123 18353358123
Email: 839877395@qq.com
Country: China
ProdList: 150
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94838
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
Fax: +86 351 7031519
Email: sales@RHFChem.com
Country: China
ProdList: 2341
Advantage: 56

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

ShangHai DEMO Chemical Co.,Ltd

Tel: 400-021-7337 2355568890
Fax: 0086-21-50182339
Email: sales@demochem.com
Country: China
ProdList: 2572
Advantage: 57

BeiJing Hwrk Chemicals Limted

Tel: 0757-86329057 18501085097
Fax: 010-89508210
Email: sales3.gd@hwrkchemical.com
Country: China
ProdList: 7583
Advantage: 55

More

Less

View Lastest Price from Methyl 4-bromobenzoate manufacturers

Henan Fengda Chemical Co., Ltd

Product: Methyl 4-bromobenzoate 619-42-1
Price: US $5.00-0.10/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-09

Hebei Duling International Trade Co. LTD

Product: Methyl 4-bromobenzoate 619-42-1
Price: US $26.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000kg
Release date: 2022-12-30

Hebei Guanlang Biotechnology Co., Ltd.

Product: Methyl 4-bromobenzoate 619-42-1
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2022-10-26

619-42-1, Methyl 4-bromobenzoateRelated Search:

4-Bromobenzoic acid 4-Aminobenzoic acid Bensulfuron methyl Thiophanate-methyl Methyl bromoacetate Methyl benzoate Methyl acetate METHYL THIOPHENE-2-CARBOXYLATE Methyl 2-bromo-2-methylpropionate Methylparaben Kresoxim-methyl Methyl 4-cyanobenzoate Benzoic acid Methyl acrylate Methyl 4-(bromomethyl)benzoate 4-Bromomethylbenzoic acid 4-Nitrophenylacetic acid 4-Nitrophenyl chloroformate

RARECHEM AL BF 0075

BRBSME

METHYL P-BROMOBENZOATE

METHYL 4-BROMOBENZOATE

4-BROMOBENZOIC ACID METHYL ESTER

4-bromo-benzoicacimethylester

Benzoic acid, 4-bromo-, methyl ester

Benzoic acid, p-bromo-, methyl ester

Benzoicacid,4-bromo-,methylester

p-Bromobenzoic acid, methyl ester

1-BROMO-4-(METHOXYCARBONYL)BENZENE

Methyl 4-bromobenzoate, 98+%

Methyl 4-bromobenzoate,99%

Methyl 4-bromobenzoa

4-Methoxycarbonyl-1-broMobenzene

4-Methoxycarbonylphenyl BroMide

NSC 9392

ThebroMo benzoic acidMethyl ester

The broMine benzoic acid Methyl ester

Methyl 4-bromobenzoate 99%

Methyl 4-Bromobenzoate &gt

Methyl 4-bromobenzoate, 99%, for synthesis

Methyl-4-brombenzoat

High purity CAS 619-42-1 Methyl 4-bromobenzoate in stock

Methy14-bromobenzoate

619-42-1

BrC6H4CO2CH3

Alphabetic

Esters

Organic Building Blocks

META - METH

Carbonyl Compounds

C8 to C9

Analytical Chromatography Product Catalog

Analytical Standards

Building Blocks

Pyridines

C8 to C9

Carbonyl Compounds

Esters

Aromatic Esters

Acids & Esters

Bromine Compounds

bc0001