ChemicalBook > CAS DataBase List > Methyl 5-methoxy-2-nitrobenzoate

Methyl 5-methoxy-2-nitrobenzoate

Product Name: Methyl 5-methoxy-2-nitrobenzoate
CAS No.: 2327-45-9
Chemical Name: Methyl 5-methoxy-2-nitrobenzoate
Synonyms: 5-Methoxy-2-nitroMethylbenzoate;METHYL 5-METHOXY-2-NITROBENZOATE;Methyl5-methoxy-2-nitrobenzoate98%;Methyl 5-methoxy-2-nitrobenzoate 98%;5-Methoxy-2-nitro-benzoic acid methyl ester;Benzoic acid,5-Methoxy-2-nitro-, Methyl ester
CBNumber: CB2142605
Molecular Formula: C9H9NO5
Formula Weight: 211.17
MOL File: 2327-45-9.mol

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Methyl 5-methoxy-2-nitrobenzoate Property

Melting point:: 58-59 °C
Boiling point:: 196-198 °C(Press: 15-16 Torr)
Density: 1.294±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: crystals
color: Light lemon/yellow, granular

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Safety

Hazard Codes: Xi
Hazard Note: Irritant
HS Code: 2918300090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: M338748
Product name: Methyl5-Methoxy-2-nitrobenzoate
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Apolloscientific

Product number: OR7411
Product name: Methyl5-methoxy-2-nitrobenzoate
Purity: 98%
Packaging: 5g
Price: $98
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-1-77
Product name: Methyl 5-methoxy-2-nitrobenzoate
Packaging: 5G
Price: $108
Updated: 2021/12/16

Apolloscientific

Product number: OR7411
Product name: Methyl5-methoxy-2-nitrobenzoate
Purity: 98%
Packaging: 1g
Price: $32
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4654-1-77
Product name: Methyl 5-methoxy-2-nitrobenzoate
Packaging: 1g
Price: $36
Updated: 2021/12/16

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Methyl 5-methoxy-2-nitrobenzoate Chemical Properties,Usage,Production

Description

Methyl 5-methoxy-2-nitrobenzoate is an important organic intermediate, commonly used in organic synthesis. This compound can be synthesized from 5-Hydroxy-2-nitrobenzoic acid.

Synthesis

67-56-1

1882-69-5

2327-45-9

To a pressure-resistant reaction flask was added 5-methoxy-2-nitrobenzoic acid (3.98 g, 20.0 mmol) and anhydrous methanol (10 mL). Concentrated sulfuric acid (150 μL) was added slowly and dropwise. The reaction vial was sealed and the reaction was stirred at 85 °C for 4 days. Upon completion of the reaction, the mixture was cooled to room temperature and concentrated under reduced pressure to half the original volume. Ethyl acetate (25 mL) was added to dilute, and the organic phase was washed sequentially with water (25 mL), saturated aqueous sodium bicarbonate solution (2 × 25 mL), saturated saline (2 × 25 mL) and water (2 × 25 mL). The organic layer was dried over anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to afford methyl 5-methoxy-2-nitrobenzoate as a yellow oil (3.57 g, 87% yield). Its nuclear magnetic resonance hydrogen spectrum (1H NMR, 300 MHz, CDCl3) data were as follows: δ 8.04 (d, J = 8.8 Hz, 1H, H-6), 7.04 (d, J = 2.3 Hz, 1H, H-3), 7.00 (dd, J = 8.8, 2.8 Hz, 1H, H-4), 3.93 (s, 3H, OCH3), 3.91 (s. 3H, OCH3). The nuclear magnetic resonance carbon spectrum (13C NMR, 75 MHz, CDCl3) data were as follows: δ 166.7, 163.5, 140.2, 131.4, 126.8, 115.9, 114.2, 56.4, 53.5. The obtained data are in agreement with the literature reports.

References

[1] Synlett, 2016, vol. 27, # 8, p. 1237 - 1240
[2] Patent: WO2005/121152, 2005, A1. Location in patent: Page/Page column 30

Methyl 5-methoxy-2-nitrobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Methyl 5-methoxy-2-nitrobenzoate manufacturers

Career Henan Chemical Co

Product: METHYL 5-METHOXY-2-NITROBENZOATE 2327-45-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

2327-45-9, Methyl 5-methoxy-2-nitrobenzoateRelated Search:

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Benzoic acid,5-Methoxy-2-nitro-, Methyl ester

5-Methoxy-2-nitroMethylbenzoate

5-Methoxy-2-nitro-benzoic acid methyl ester

Methyl5-methoxy-2-nitrobenzoate98%

METHYL 5-METHOXY-2-NITROBENZOATE

Methyl 5-methoxy-2-nitrobenzoate 98%

2327-45-9

Acids & Esters

Anisoles, Alkyloxy Compounds & Phenylacetates

Nitro Compounds

blocks

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NitroCompounds

Aromatic Esters